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The Physico-Chemical Properties of a Subducted Slab from Garnet Zonation Patterns (Sesia Zone, Western Alps) 总被引：3，自引：0，他引：3
KONRAD-SCHMOLKE MATTHIAS; BABIST JOCHEN; HANDY MARK R.; O'BRIEN PATRICK J. 《Journal of Petrology》2006,47(11):2123-2148
Garnets in continentally derived high-pressure (HP) rocks ofthe Sesia Zone (Western Alps) exhibit three different chemicalzonation patterns, depending on sample locality. Comparisonof observed garnet zonation patterns with thermodynamicallymodelled patterns shows that the different patterns are causedby differences in the water content of the subducted protolithsduring prograde metamorphism. Zonation patterns of garnets inwater-saturated host rocks show typical prograde chemical zonationswith steadily increasing pyrope content and increasing XMg,together with bell-shaped spessartine patterns. In contrast,garnets in water-undersaturated rocks have more complex zonationpatterns with a characteristic decrease in pyrope and XMg betweencore and inner rim. In some cases, garnets show an abrupt compositionalchange in core-to-rim profiles, possibly due to water-undersaturationprior to HP metamorphism. Garnets from both water-saturatedand water-undersaturated rocks show signs of intervening growthinterruptions and core resorption. This growth interruptionresults from bulk-rock depletion caused by fractional garnetcrystallization. The water content during burial influences significantly thephysical properties of the subducted rocks. Due to enhancedgarnet crystallization, water-undersaturated rocks, i.e. thoselacking a free fluid phase, become denser than their water-saturatedequivalents, facilitating the subduction of continental material.Although water-bearing phases such as phengite and epidote arestable up to eclogite-facies conditions in these rocks, dehydrationreactions during subduction are lacking in water-undersaturatedrocks up to the transition to the eclogite facies, due to thethermodynamic stability of such hydrous phases at high P–Tconditions. Our calculations show that garnet zonation patternsstrongly depend on the mineral parageneses stable during garnetgrowth and that certain co-genetic mineral assemblages causedistinct garnet zonation patterns. This observation enablesinterpretation of complex garnet growth zonation patterns interms of garnet-forming reactions and water content during HPmetamorphism, as well determination of detailed P–T paths. KEY WORDS: dehydration; high-pressure metamorphism; Sesia Zone; subduction; thermodynamic modelling 相似文献
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By M. WIEGNER J. GASTEIGER K. KANDLER B. WEINZIERL K. RASP M. ESSELBORN V. FREUDENTHALER B. HEESE C. TOLEDANO M. TESCHE D. ALTHAUSEN 《Tellus. Series B, Chemical and physical meteorology》2009,61(1):180-194
In the framework of the Saharan Mineral Dust Experiment (SAMUM) for the first time the spectral dependence of particle linear depolarization ratios was measured by combining four lidar systems. In this paper these measurements are compared with results from scattering theory based on the T-matrix method. For this purpose, in situ measurements—size distribution, shape distribution and refractive index—were used as input parameters; particle shape was approximated by spheroids. A sensitivity study showed that lidar-related parameters—lidar ratio S p and linear depolarization ratio δ p —are very sensitive to changes of all parameters. The simulated values of the δ p are in the range of 20% and 31% and thus in the range of the measurements. The spectral dependence is weak, so that it could not be resolved by the measurements. Calculated lidar ratios based on the measured microphysics and considering equivalent radii up to 7.5 μm show a range of possible values between 29 and 50 sr at λ= 532 nm . Larger S p might be possible if the real part of the refractive index is small and the imaginary part is large. A strict validation was however not possible as too many microphysical parameters influence S p and δ p that could not be measured with the required accuracy. 相似文献
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ANDREI A. ANDREEV GUIDO GROSSE LUTZ SCHIRRMEISTER SVETLANA A. KUZMINA ELENA YU. NOVENKO ANATOLY A. BOBROV PAVEL E. TARASOV BORIS P. ILYASHUK TATIANA V. KUZNETSOVA MATTHIAS KRBETSCHEK HANNO MEYER VIKTOR V. KUNITSKY 《Boreas: An International Journal of Quaternary Research》2004,33(4):319-348
Palaeoenvironmental records from permafrost sequences complemented by infrared stimulated luminescence (IRSL) and [Formula: See Text]Th/U dates from Bol'shoy Lyakhovsky Island (73°20'N, 141°30'E) document the environmental history in the region for at least the past 200 ka. Pollen spectra and insect fauna indicate that relatively wet grass-sedge tundra habitats dominated during an interstadial c. 200-170 ka BP. Summers were rather warm and wet, while stable isotopes reflect severe winter conditions. The pollen spectra reflect sparser grass-sedge vegetation during a Taz (Late Saalian) stage, c. 170-130 ka BP, with environmental conditions much more severe compared with the previous interstadial. Open Poaceae and Artemisia plant associations dominated vegetation at the beginning of the Kazantsevo (Eemian) c. 130 ka BP. Some shrubs (Alnus fruticosa, Salix, Betula nana) grew in more protected and wetter places as well. The climate was relatively warm during this time, resulting in the melting of Saalian ice wedges. Later, during the interglacial optimum, shrub tundra with Alnus fruticosa and Betula nana s.l. dominated vegetation. Climate was relatively wet and warm. Quantitative pollen-based climate reconstruction suggests that mean July temperatures were 4-5°C higher than the present during the optimum of the Eemian, while late Eemian records indicate significant climate deterioration. 相似文献
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STEFAN LAUTERBACH ACHIM BRAUER NILS ANDERSEN DAN L. DANIELOPOL PETER DULSKI MATTHIAS HÜLS KRYSTYNA MILECKA TADEUSZ NAMIOTKO BIRGIT PLESSEN ULRICH VON GRAFENSTEIN DECLAKES PARTICIPANTS 《Boreas: An International Journal of Quaternary Research》2011,40(1):57-72
Lauterbach, S., Brauer, A., Andersen, N., Danielopol, D. L., Dulski, P., Hüls, M., Milecka, K., Namiotko, T., Plessen, B., von Grafenstein, U. & DecLakes participants 2010: Multi‐proxy evidence for early to mid‐Holocene environmental and climatic changes in northeastern Poland. Boreas, 10.1111/j.1502‐3885.2010.00159.x. ISSN 0300‐9483. We investigated the sedimentary record of Lake Hańcza (northeastern Poland) using a multi‐proxy approach, focusing on early to mid‐Holocene climatic and environmental changes. AMS 14C dating of terrestrial macrofossils and sedimentation rate estimates from occasional varve thickness measurements were used to establish a chronology. The onset of the Holocene at c. 11 600 cal. a BP is marked by the decline of Lateglacial shrub vegetation and a shift from clastic‐detrital deposition to an autochthonous sedimentation dominated by biochemical calcite precipitation. Between 10 000 and 9000 cal. a BP, a further environmental and climatic improvement is indicated by the spread of deciduous forests, an increase in lake organic matter and a 1.7‰ rise in the oxygen isotope ratios of both endogenic calcite and ostracod valves. Rising δ18O values were probably caused by a combination of hydrological and climatic factors. The persistence of relatively cold and dry climate conditions in northeastern Poland during the first one and a half millennia of the Holocene could be related to a regional eastern European atmospheric circulation pattern. Prevailing anticyclonic circulation linked to a high‐pressure cell above the retreating Scandinavian Ice Sheet might have blocked the influence of warm and moist Westerlies and attenuated the early Holocene climatic amelioration in the Lake Hańcza region until the final decay of the ice sheet. 相似文献
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By BERND HEINOLD INA TEGEN MICHAEL ESSELBORN KONRAD KANDLER PETER KNIPPERTZ DETLEF MÜLLER ALEXANDER SCHLADITZ MATTHIAS TESCHE BERNADETT WEINZIERL ALBERT ANSMANN DIETRICH ALTHAUSEN BENOIT LAURENT REAS MASSLING THOMAS MÜLLER REAS PETZOLD KERSTIN SCHEPANSKI ALFRED WIEDENSOHLER 《Tellus. Series B, Chemical and physical meteorology》2009,61(1):307-324
The regional dust model system LM-MUSCAT-DES was developed in the framework of the SAMUM project. Using the unique comprehensive data set of near-source dust properties during the 2006 SAMUM field campaign, the performance of the model system is evaluated for two time periods in May and June 2006. Dust optical thicknesses, number size distributions and the position of the maximum dust extinction in the vertical profiles agree well with the observations. However, the spatio-temporal evolution of the dust plumes is not always reproduced due to inaccuracies in the dust source placement by the model. While simulated winds and dust distributions are well matched for dust events caused by dry synoptic-scale dynamics, they are often misrepresented when dust emissions are caused by moist convection or influenced by small-scale topography that is not resolved by the model. In contrast to long-range dust transport, in the vicinity of source regions the model performance strongly depends on the correct prediction of the exact location of sources. Insufficiently resolved vertical grid spacing causes the absence of inversions in the model vertical profiles and likely explains the absence of the observed sharply defined dust layers. 相似文献
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By N. KAADEN A. MASSLING A. SCHLADITZ T. MÜLLER K. KANDLER L. SCHÜTZ B. WEINZIERL A. PETZOLD M. TESCHE S. LEINERT C. DEUTSCHER M. EBERT S. WEINBRUCH A. WIEDENSOHLER 《Tellus. Series B, Chemical and physical meteorology》2009,61(1):51-63
The Saharan Mineral Dust Experiment (SAMUM) was conducted in May and June 2006 in Tinfou, Morocco. A H-TDMA system and a H-DMA-APS system were used to obtain hygroscopic properties of mineral dust particles at 85% RH. Dynamic shape factors of 1.11, 1.19 and 1.25 were determined for the volume equivalent diameters 720, 840 and 960 nm, respectively.
During a dust event, the hydrophobic number fraction of 250 and 350 nm particles increased significantly from 30 and 65% to 53 and 75%, respectively, indicating that mineral dust particles can be as small as 200 nm in diameter. Log-normal functions for mineral dust number size distributions were obtained from total particle number size distributions and fractions of hydrophobic particles. The geometric mean diameter for Saharan dust particles was 715 nm during the dust event and 570 nm for the Saharan background aerosol.
Measurements of hygroscopic growth showed that the Saharan aerosol consists of an anthropogenic fraction (predominantly non natural sulphate and carbonaceous particles) and of mineral dust particles. Hygroscopic growth and hysteresis curve measurements of the 'more' hygroscopic particle fraction indicated ammonium sulphate as a main component of the anthropogenic aerosol. Particles larger than 720 nm in diameter were completely hydrophobic meaning that mineral dust particles are not hygroscopic. 相似文献
During a dust event, the hydrophobic number fraction of 250 and 350 nm particles increased significantly from 30 and 65% to 53 and 75%, respectively, indicating that mineral dust particles can be as small as 200 nm in diameter. Log-normal functions for mineral dust number size distributions were obtained from total particle number size distributions and fractions of hydrophobic particles. The geometric mean diameter for Saharan dust particles was 715 nm during the dust event and 570 nm for the Saharan background aerosol.
Measurements of hygroscopic growth showed that the Saharan aerosol consists of an anthropogenic fraction (predominantly non natural sulphate and carbonaceous particles) and of mineral dust particles. Hygroscopic growth and hysteresis curve measurements of the 'more' hygroscopic particle fraction indicated ammonium sulphate as a main component of the anthropogenic aerosol. Particles larger than 720 nm in diameter were completely hydrophobic meaning that mineral dust particles are not hygroscopic. 相似文献