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1.
Daniel P. Glavin Jason P. Dworkin Andrew Aubrey Oliver Botta James H. Doty Zita Martins Jeffrey L. Bada 《Meteoritics & planetary science》2006,41(6):889-902
Abstract— Amino acid analyses of the Antarctic CM2 chondrites Allan Hills (ALH) 83100 and Lewis Cliff (LEW) 90500 using liquid chromatography‐time of flight‐mass spectrometry (LC‐ToF‐MS) coupled with UV fluorescence detection revealed that these carbonaceous meteorites contain a suite of indigenous amino acids not present in Antarctic ice. Several amino acids were detected in ALH 83100, including glycine, alanine, β‐alanine, γ‐amino‐n‐butyric acid (γ‐ABA), and α‐aminoisobutyric acid (AIB) with concentrations ranging from 250 to 340 parts per billion (ppb). In contrast to ALH 83100, the CM2 meteorites LEW 90500 and Murchison had a much higher total abundance of these amino acids (440–3200 ppb). In addition, ALH 83100 was found to have lower abundances of the α‐dialkyl amino acids AIB and isovaline than LEW 90500 and Murchison. There are three possible explanations for the depleted amino acid content in ALH 83100: 1) amino acid leaching from ALH 83100 during exposure to Antarctic ice meltwater, 2) a higher degree of aqueous alteration on the ALH 83100 parent body, or 3) ALH 83100 originated on a chemically distinct parent body from the other two CM2 meteorites. The high relative abundance of ?‐amino‐n‐caproic acid (EACA) in the ALH 83100 meteorite as well as the Antarctic ice indicates that Nylon‐6 contamination from the Antarctic sample storage bags may have occurred during collection. 相似文献
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Bruno Lanson Matthew A. Marcus Sirine Fakra Frdric Panfili Nicolas Geoffroy Alain Manceau 《Geochimica et cosmochimica acta》2008,72(10):2478-2490
It is now well established that a number of terrestrial and aquatic microorganisms have the capacity to oxidize and precipitate Mn as phyllomanganate. However, this biomineralization has never been shown to occur in plant tissues, nor has the structure of a natural Mn(IV) biooxide been characterized in detail. We show that the graminaceous plant Festuca rubra (red fescue) produces a Zn-rich phyllomanganate with constant Zn:Mn and Ca:Mn atomic ratios (0.46 and 0.38, respectively) when grown on a contaminated sediment. This new phase is so far the Zn-richest manganate known to form in nature (chalcophanite has a Zn:Mn ratio of 0.33) and has no synthetic equivalent. Visual examination of root fragments under a microscope shows black precipitates about ten to several tens of microns in size, and their imaging with backscattered and secondary electrons demonstrates that they are located in the root epidermis. In situ measurements by Mn and Zn K-edge extended X-ray absorption fine structure (EXAFS) spectroscopy and X-ray diffraction (XRD) with a micro-focused beam can be quantitatively described by a single-phase model consisting of Mn(IV) octahedral layers with 22% vacant sites capped with tetrahedral and octahedral Zn in proportions of 3:1. The layer charge deficit is also partly balanced by interlayer Mn and Ca. Diffracting crystallites have a domain radius of 33 Å in the ab plane and contain only 1.2 layers (8.6 Å) on average. Since this biogenic Mn oxide consists mostly of isolated layers, basal 00l reflections are essentially absent despite its lamellar structure. Individual Mn layers are probably held together in the Mn–Zn precipitates by stabilizing organic molecules. Zinc biomineralization by plants likely is a defense mechanism against toxicity induced by excess concentrations of this metal in the rhizosphere. 相似文献
5.
Ronald Amundson Stephanie Ewing Brad Sutter Oliver Chadwick Michelle Walvoord 《Geochimica et cosmochimica acta》2008,72(15):3845-3864
Early (>3 Gy) wetter climate conditions on Mars have been proposed, and it is thus likely that pedogenic processes have occurred there at some point in the past. Soil and rock chemistry of the Martian landing sites were evaluated to test the hypothesis that in situ aqueous alteration and downward movement of solutes have been among the processes that have transformed these portions of the Mars regolith. A geochemical mass balance shows that Martian soils at three landing sites have lost significant quantities of major rock-forming elements and have gained elements that are likely present as soluble ions. The loss of elements is interpreted to have occurred during an earlier stage(s) of weathering that may have been accompanied by the downward transport of weathering products, and the salts are interpreted to be emplaced later in a drier Mars history. Chemical differences exist among the sites, indicating regional differences in soil composition. Shallow soil profile excavations at Gusev crater are consistent with late stage downward migration of salts, implying the presence of small amounts of liquid water even in relatively recent Martian history. While the mechanisms for chemical weathering and salt additions on Mars remain unclear, the soil chemistry appears to record a decline in leaching efficiency. A deep sedimentary exposure at Endurance crater contains complex depth profiles of SO4, Cl, and Br, trends generally consistent with downward aqueous transport accompanied by drying. While no model for the origin of Martian soils can be fully constrained with the currently available data, a pedogenic origin is consistent with observed Martian geology and geochemistry, and provides a testable hypothesis that can be evaluated with present and future data from the Mars surface. 相似文献
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Uwe?LangrockEmail author Ruediger?Stein Marcus?Lipinski Hans-Jürgen?Brumsack 《Geo-Marine Letters》2003,23(1):34-42
The late Volgian (early "Boreal" Berriasian) sapropels of the Hekkingen Formation of the central Barents Sea show total organic carbon (TOC) contents from 3 to 36 wt%. The relationship between TOC content and sedimentation rate (SR), and the high Mo/Al ratios indicate deposition under oxygen-free bottom-water conditions, and suggest that preservation under anoxic conditions has largely contributed to the high accumulation of organic carbon. Hydrogen index values obtained from Rock-Eval pyrolysis are exceptionally high, and the organic matter is characterized by well-preserved type II kerogen. However, the occurrence of spores, freshwater algae, coal fragments, and charred land-plant remains strongly suggests proximity to land. Short-term oscillations, probably reflecting Milankovitch-type cyclicity, are superimposed on the long-term trend of constantly changing depositional conditions during most of the late Volgian. Progressively smaller amounts of terrestrial organic matter and larger amounts of marine organic matter upwards in the core section may have been caused by a continuous sea-level rise. 相似文献
8.
Although its use is widespread in several other scientific disciplines, the theory of tensor invariants is only marginally
adopted in gravity field modeling. We aim to close this gap by developing and applying the invariants approach for geopotential
recovery. Gravitational tensor invariants are deduced from products of second-order derivatives of the gravitational potential.
The benefit of the method presented arises from its independence of the gradiometer instrument’s orientation in space. Thus,
we refrain from the classical methods for satellite gravity gradiometry analysis, i.e., in terms of individual gravity gradients,
in favor of the alternative invariants approach. The invariants approach requires a tailored processing strategy. Firstly,
the non-linear functionals with regard to the potential series expansion in spherical harmonics necessitates the linearization
and iterative solution of the resulting least-squares problem. From the computational point of view, efficient linearization
by means of perturbation theory has been adopted. It only requires the computation of reference gravity gradients. Secondly,
the deduced pseudo-observations are composed of all the gravitational tensor elements, all of which require a comparable level
of accuracy. Additionally, implementation of the invariants method for large data sets is a challenging task. We show the
fundamentals of tensor invariants theory adapted to satellite gradiometry. With regard to the GOCE (Gravity field and steady-state
Ocean Circulation Explorer) satellite gradiometry mission, we demonstrate that the iterative parameter estimation process
converges within only two iterations. Additionally, for the GOCE configuration, we show the invariants approach to be insensitive
to the synthesis of unobserved gravity gradients. 相似文献
9.
Efficient GOCE satellite gravity field recovery based on least-squares using QR decomposition 总被引:3,自引:0,他引:3
We develop and apply an efficient strategy for Earth gravity field recovery from satellite gravity gradiometry data. Our approach
is based upon the Paige-Saunders iterative least-squares method using QR decomposition (LSQR). We modify the original algorithm
for space-geodetic applications: firstly, we investigate how convergence can be accelerated by means of both subspace and
block-diagonal preconditioning. The efficiency of the latter dominates if the design matrix exhibits block-dominant structure.
Secondly, we address Tikhonov-Phillips regularization in general. Thirdly, we demonstrate an effective implementation of the
algorithm in a high-performance computing environment. In this context, an important issue is to avoid the twofold computation
of the design matrix in each iteration. The computational platform is a 64-processor shared-memory supercomputer. The runtime
results prove the successful parallelization of the LSQR solver. The numerical examples are chosen in view of the forthcoming
satellite mission GOCE (Gravity field and steady-state Ocean Circulation Explorer). The closed-loop scenario covers 1 month
of simulated data with 5 s sampling. We focus exclusively on the analysis of radial components of satellite accelerations
and gravity gradients. Our extensions to the basic algorithm enable the method to be competitive with well-established inversion
strategies in satellite geodesy, such as conjugate gradient methods or the brute-force approach. In its current development
stage, the LSQR method appears ready to deal with real-data applications. 相似文献
10.
The dynamics and thermodynamics of large ash flows 总被引:6,自引:6,他引:0
Ash flow deposits, containing up to 1000 km3 of material, have been produced by some of the largest volcanic eruptions known. Ash flows propagate several tens of kilometres
from their source vents, produce extensive blankets of ash and are able to surmount topographic barriers hundreds of metres
high. We present and test a new model of the motion of such flows as they propagate over a near horizontal surface from a
collapsing fountain above a volcanic vent. The model predicts that for a given eruption rate, either a slow (10–100 m/s) and
deep (1000–3000 m) subcritical flow or a fast (100–200 m/s) and shallow (500–1000 m) supercritical flow may develop. Subcritical
ash flows propagate with a nearly constant volume flux, whereas supercritical flows entrain air and become progressively more
voluminous. The run-out distance of such ash flows is controlled largely by the mass of air mixed into the collapsing fountain,
the degree of fragmentation and the associated rate of loss of material into an underlying concentrated depositional system,
and the mass eruption rate. However, in supercritical flows, the continued entrainment of air exerts a further important control
on the flow evolution. Model predictions show that the run-out distance decreases with the mass of air entrained into the
flow. Also, the mass of ash which may ascend from the flow into a buoyant coignimbrite cloud increases as more air is entrained
into the flow. As a result, supercritical ash flows typically have shorter runout distances and more ash is elutriated into
the associated coignimbrite eruption columns. We also show that one-dimensional, channellized ash flows typically propagate
further than their radially spreading counterparts.
As a Plinian eruption proceeds, the erupted mass flux often increases, leading to column collapse and the formation of pumiceous
ash flows. Near the critical conditions for eruption column collapse, the flows are shed from high fountains which entrain
large quantities of air per unit mass. Our model suggests that this will lead to relatively short ash flows with much of the
erupted material being elutriated into the coignimbrite column. However, if the mass flux subseqently increases, then less
air per unit mass is entrained into the collapsing fountain, and progressively larger flows, which propagate further from
the vent, will develop.
Our model is consistent with observations of a number of pyroclastic flow deposits, including the 1912 eruption of Katmai
and the 1991 eruption of Pinatubo. The model suggests that many extensive flow sheets were emplaced from eruptions with mass
fluxes of 109–1010 kg/s over periods of 103–105 s, and that some indicators of flow "mobility" may need to be reinterpreted. Furthermore, in accordance with observations,
the model predicts that the coignimbrite eruption columns produced from such ash flows rose between 20 and 40 km.
Received: 25 August 1995 / Accepted: 3 April 1996 相似文献