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1.
Beaver dam analogues (BDAs) are a cost-effective stream restoration approach that leverages the recognized environmental benefits of natural beaver dams on channel stability and local hydrology. Although natural beaver dams are known to exert considerable influence on the hydrologic conditions of a stream system by mediating geomorphic processes, nutrient cycling, and groundwater–surface water interactions, the impacts of beaver-derived restoration methods on groundwater–surface water exchange are poorly characterized. To address this deficit, we monitored hyporheic exchange fluxes and streambed porewater biogeochemistry across a sequence of BDAs installed along a central Wyoming stream during the summer of 2019. Streambed fluxes were quantified by heat tracing methods and vertical hydraulic gradients. Biogeochemical activity was evaluated using major ion porewater chemistry and principal component analysis. Vertical fluxes of approximately 1.0 m/day were observed around the BDAs, as was the development of spatially heterogeneous zones of nitrate production, groundwater upwelling, and anaerobic reduction. Strong contrasts in hyporheic zone processes were observed across BDAs of differing sizes. This suggests that structures may function with size-dependent behaviour, only altering groundwater–surface water interactions after a threshold hydraulic step height is exceeded. Patterns of hyporheic exchange and biogeochemical cycling around the studied BDAs resemble those around natural beaver dams, suggesting that BDAs may provide comparable benefits to channel complexity and near-stream function over a 1-year period.  相似文献   
2.
Local glaciers and ice caps (GICs) comprise only ~5.4% of the total ice volume, but account for ~14–20% of the current ice loss in Greenland. The glacial history of GICs is not well constrained, however, and little is known about how they reacted to Holocene climate changes. Specifically, in North Greenland, there is limited knowledge about past GIC fluctuations and whether they survived the Holocene Thermal Maximum (HTM, ~8 to 5 ka). In this study, we use proglacial lake records to constrain the ice‐marginal fluctuations of three local ice caps in North Greenland including Flade Isblink, the largest ice cap in Greenland. Additionally, we have radiocarbon dated reworked marine molluscs in Little Ice Age (LIA) moraines adjacent to the Flade Isblink, which reveal when the ice cap was smaller than present. We found that outlet glaciers from Flade Isblink retreated inland of their present extent from ~9.4 to 0.2 cal. ka BP. The proglacial lake records, however, demonstrate that the lakes continued to receive glacial meltwater throughout the entire Holocene. This implies that GICs in Finderup Land survived the HTM. Our results are consistent with other observations from North Greenland but differ from locations in southern Greenland where all records show that the local ice caps at low and intermediate elevations disappeared completely during the HTM. We explain the north–south gradient in glacier response as a result of sensitivity to increased temperature and precipitation. While the increased temperatures during the HTM led to a complete melting of GICs in southern Greenland, GICs remained in North Greenland probably because the melting was counterbalanced by increased precipitation due to a reduction in Arctic sea‐ice extent and/or increased poleward moisture transport.  相似文献   
3.
We present H2CO observations of young protostar candidates in the Serpens Cloud Core. We find evidence for dense molecular gas in the cores of these objects that is warmer than the surrounding dust. The strong emission and gas properties support the premise that many of these sources may be very young protostars.  相似文献   
4.
This paper reports a preliminary investigation of CO2 sequestration and seal integrity at Teapot Dome oil field, Wyoming, USA, with the objective of predicting the potential risk of CO2 leakage along reservoir-bounding faults. CO2 injection into reservoirs creates anomalously high pore pressure at the top of the reservoir that could potentially hydraulically fracture the caprock or trigger slip on reservoir-bounding faults. The Tensleep Formation, a Pennsylvanian age eolian sandstone is evaluated as the target horizon for a pilot CO2 EOR-carbon storage experiment, in a three-way closure trap against a bounding fault, termed the S1 fault. A preliminary geomechanical model of the Tensleep Formation has been developed to evaluate the potential for CO2 injection inducing slip on the S1 fault and thus threatening seal integrity. Uncertainties in the stress tensor and fault geometry have been incorporated into the analysis using Monte Carlo simulation. The authors find that even the most pessimistic risk scenario would require ∼10 MPa of excess pressure to cause the S1 fault to reactivate and provide a potential leakage pathway. This would correspond to a CO2 column height of ∼1,500 m, whereas the structural closure of the Tensleep Formation in the pilot injection area does not exceed 100 m. It is therefore apparent that CO2 injection is not likely to compromise the S1 fault stability. Better constraint of the least principal stress is needed to establish a more reliable estimate of the maximum reservoir pressure required to hydrofracture the caprock.  相似文献   
5.
The Mo stable isotope system is being applied to study changes in ocean redox. Such applications implicitly assume that Mo isotope fractionation in aqueous systems is relatively insensitive to frequently changing environmental variables such as temperature (T) and ionic strength (I). A major driver of fractionation is the adsorption of Mo to Mn oxyhydroxide surfaces [Barling J. and Anbar A. D. (2004) Molybdenum isotope fractionation during adsorption by manganese oxides. Earth Planet. Sci. Lett.217(3-4), 315-329]. Here, we report the results of experiments that determine the extent to which Mo isotope fractionation during adsorption of Mo to the Mn oxyhydroxide mineral birnessite is sensitive to T and I. The results are compared to new predictions from quantum chemical computations. We measured fractionation from 1 to 50 °C at I = 0.1 m and found that Δ97/95Modissolved-adsorbed varies from 1.9‰ to 1.6‰ over this temperature range. Experiments were also performed at 25 °C in synthetic seawater (I = 0.7); fractionation at this condition was the same within analytical error as in low ionic strength experiments. These findings confirm that the Mo isotope fractionation during adsorption to Mn oxyhydroxides is relatively insensitive to variations and T and I over environmentally relevant ranges. To relate these findings to potential mechanisms of Mo isotope fractionation, we also report results for density functional theory computations of the fractionation between and various possible structures of molybdic acid as a function of temperature. Because no plausible species fractionates from with a magnitude matching the experiments, we are left with three possibilities to explain the fractionation: (1) solvation effects on the vibrational frequencies of aqueous species considered thus far are significant, such that our calculations in vacuo yield inaccurate fractionations; (2) a trace aqueous species not yet considered fractionates from and then adsorbs to birnessite; or (3) a surface complex not present in solution forms on birnessite in which Mo is not tetrahedrally coordinated. Our findings help validate assumptions underlying paleoceanographic applications of the Mo isotope system and also lead us closer to understanding the mechanism of isotope fractionation during adsorption of Mo to Mn oxyhydroxides.  相似文献   
6.
A large number of papers and technical reports are available on the technically important problem of structural elements executing transverse vibrations and carrying concentrated masses. In general it is assumed that the attachment is perfectly rigid. On the other hand, a rather limited amount of published work is available when the mass is elastically connected to the structure. The system then exhibits a more complex behavior than in the case of rigid attachment. The present study deals with the solution of the title problem using the well-known normal mode, sinusoidal eigenfunction expansions.  相似文献   
7.
Water column concentrations of total suspended solids (TSS), particulate organic carbon (POC) and particulate nitrogen (PN) were measured at three different depths in four different locations bracketing the estuarine turbidity maximum (ETM) along the main channel of a temperate riverine estuary (Winyah Bay, South Carolina, USA). Measurements were carried out over full tidal cycle (over 24 h). Salinity, temperature, current magnitude and direction were also monitored at the same time throughout the water column. Tidally averaged net fluxes of salt, TSS, POC and PN were calculated by combining the current measurements with the concentration data. Under the extreme low river discharge conditions that characterized the study period, net landward fluxes of salt were measured in the lower part of the study area, suggesting that the landward transport through the main channel of the estuary was probably balanced by export out through the sides. In contrast, the net fluxes of salt in the upper reaches of the study area were near zero, indicating a closed salt balance in this part of the estuary. In contrast to salt, the net fluxes of TSS, POC and PN in the deeper parts of the water column were consistently landward at all four sites in Winyah Bay indicating the non-conservative behavior of particulate components and their active transport up the estuary in the region around the ETM.The carbon contents (%POC), carbon:nitrogen ratios (org[C:N]a) and stable carbon isotopic compositions (δ13CPOC) of the suspended particles varied significantly with depth, location and tidal stage. Tidally averaged compositions showed a significant increase up the estuary in the %POC and org[C:N]a values of suspended particles consistent with the preferential landward transport of carbon-rich particles with higher vascular plant debris content. The combination of tidal resuspension and flood-dominated flow appeared to be responsible for the hydrodynamic sorting of particles along the estuary that resulted in denser, organic-poor particles being transported landward less efficiently. The elemental and isotopic compositions indicated that vascular C3 plants and estuarine algae were the major sources of the particulate organic matter of all the samples, without any significant contributions from salt marsh C4 vegetation (Spartina alterniflora) and/or marine phytoplankton.  相似文献   
8.
This paper deals with the determination of an approximate fundamental frequency equation for a rectangular plate with two edges (y = 0, b) elastically restrained against rotation while the edges x=0, a are free but internal supports parallel to the free edges are present in the structural system. The algorithmic procedure can be easily implemented on a micro computer or even a hand, programmable calculator.Good engineering agreement with experimental results is shown to exist in the case of a plate with edges y=0,b rigidly clamped.  相似文献   
9.
Long-term exposure of animals to sub-lethal doses of toxicants such as benzene (B) and dimethylnaphthalene (DMN) may result in subtle changes in their physiology and biochemistry. In crustaceans such changes include decreased rate of limb regeneration, extended time to molt and decreased growth increment at molt.1,2 These processes depend upon an adequate supply of stored nutrients in the tissues and appropriate release of neuroendocrine substances from the central nervous system.3,4 We are examining the effects of sub-lethal doses of B and DMN on osmotic and ionic regulation and on nutrient storage in the blue crab, Callinectes sapidus, and the green crab, Carcinus maenas. Disturbances in these physiological processes may reflect alterations in neuroendocrine functions brought about by the presence of toxicants. We find that exposure of C. maenas to B or DMN, followed by transfer to a dilute medium, results in impaired osmoregulatory capacity, while addition of these compounds to a dilute medium to which the animal is already acclimated does not affect their regulatory ability. Storage of carbohydrate in the midgut gland (hepatopancreas) is decreased by B or DMN, while the accessory storage tissues (gill, muscle) are not significantly affected.  相似文献   
10.
The present paper, of a tutorial nature, solves two different thermoelastic problems using a unified approach: (a) thermoelastic stresses and deflections in thin, rectangular plates with edges elastically restrained against rotation when small-deflection theory is used and stress resultants in the middle plane of the plates are neglected; and (b) thermoelastic plane stress situations in rectangular plates with stress-free edges subjected to a two-dimensional temperature distribution.The first problem is attacked using polynomial coordinate functions which identically satisfy the governing boundary conditions, and the Ritz method is used to determine the plate response. When the flexibility coefficients approach zero (clamped edge conditions) the calculated results practically coincide with the exact solution for the test case treated in this paper. On the other hand this degenerate solution turns out to be a very convenient approximation for obtaining a solution to Airy's problem described in the second place and which is also solved in a straightforward manner using a variational approach.  相似文献   
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