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Theoretical and Applied Climatology - Although atmospheric humidity influences environmental and agricultural conditions, thereby influencing plant growth, human health, and air pollution, efforts...  相似文献   
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In the hydrologic analysis of extreme events such as precipitation or floods, the data can generally be divided into two types: partial duration series and annual maximum series. Partial duration series analysis is a robust method to analyze hydrologic extremes, but the adaptive choice of an optimal threshold is challenging. The main goal of this paper was to determine the best method for choosing optimal thresholds. Ten semi-parametric tail index estimators were applied to find the optimal threshold of a 24-h duration precipitation period using data from the Korean Meteorological Administration. The mean square errors of the 10 estimators were calculated to determine the optimal threshold using a semi-parametric bootstrap method. A modified generalized Jackknife estimator determined the best performance in this study among the 10 estimators evaluated with regard to estimating the mean square error of the shape estimator for the generalized Pareto distribution.  相似文献   
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The adsorption of cadmium (Cd) and zinc (Zn) with similar chemical properties is examined onto three soil samples: one is alkaline and the others are acidic. The distribution coefficient (K d) and the Freundlich constant (K F) for Zn are slightly higher than those for Cd, implying that the adsorption affinity of Zn is a little greater and less mobile. However, Cd and Zn usually show comparable results in the kinetic, isotherm, and envelope experiments. The adsorption of the heavy metals is relatively rapid and the reaction is almost completed within 15 min. The kinetics for both Cd and Zn are very well explained by the parabolic diffusion model. The maximum adsorption of the heavy metals is obtained at high pH, high temperature, and low ionic strength. The adsorption capacity on the alkaline soil is more significantly affected by the temperature as compared to the acidic soil. It is found that the adsorption affinity of the two heavy metals is mainly affected by the soil properties, such as pH, pHPZC, organic matter, and total carbon. It is also confirmed that the chemical properties of the heavy metals are important factors in their adsorption onto soil. The adsorption isotherms of Cd and Zn are well described in both Freundlich and Langmuir models at the usual pH (soil pH). Under acidic and alkaline pHs, however, only the Freundlich model describes the adsorption of both heavy metals satisfactorily.  相似文献   
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