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Thirty borehole temperature–depth profiles in the central and southern Urals, Russia were scrutinized for evidence of ground surface temperature histories. We explored two inversion schemes: a simple ramp inversion in which solutions are parameterized in terms of an onset time and magnitude of change and a more sophisticated functional space inverse algorithm in which the functional form of the solution is left unspecified. To enhance and potentially identify latitudinal differences in the ground surface temperature signal, we subdivided the data into three groups based on geographic proximity and simultaneously inverted the borehole temperature–depth logs. The simultaneous inversions highlighted 13 temperature–depth logs that could not both fit a common ground surface temperature history and a priori models within reasonable bounds. Our results confirm that this is an effective way to reduce site-specific noise from an ensemble of boreholes. Each inversion scheme gives comparable results indicating locally variable warming on the order of 1°C starting between 1800 and 1900 AD. Similarly surface air temperature records from 12 nearby meteorological stations exhibit locally variable warming also on the order of 1°C of warming during the 20th century. To explore the degree to which borehole temperatures and surface air temperature (SAT) time series are responding to the same signal, we average the SAT data into the same three groups and used these averages as a forcing function at the Earth's surface to generate synthetic transient temperature profiles. Root mean square (RMS) misfits between these synthetic temperature profiles and averaged temperature–depth profiles are low, suggesting that first-order curvature in borehole temperatures and variations in SAT records are correlated.  相似文献   
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Summary In the Middle Miocene claystones containing fossil micro-organic matter and overlying the brown-coal seams in the Jii quarry of the Sokolov Brown-Coal Basin, a strongly magnetic layer was found and subjected to detailed palaeomagnetic investigations. The principal carrier of magnetism in this bed (called Kocián's bed) is the ferrimagnetic mineralization of greigite or greigitesmythite showing pronounced metastable properties. This mineralization must be treated with caution during laboratory tests aimed at deriving palaeomagnetic directions. In Kocián's bed, about two metres thick, two zones of palaeomagnetic field transition were identified. The high degree of demagnetization achieved by using thermal stepwise procedures and a MAVACS apparatus enabled the origin of the self-reversal of remanence to be defined after heating to 360°C. The process of chemo-remanent magnetization of the authigenic greigite-(smythite) mineralization fossilizing the palaeomagnetic field was relatively fast; the transition of the palaeomagnetic field is recorded in layers not exceeding a thickness of 2 × 10–2 m.Presented at 2nd conference on New Trends in Geomagnetism, Castle of Bechyn, Czechoslovakia, September 24–29, 1990.  相似文献   
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Volcanism throughout the Luzon arc is associated with eastwardsubduction of the South China Sea floor along the Manila Trench.The southern section of the arc, the focus of this study, extendsfrom the Lingayen-Dingalan fault to the small islands just southof Luzon. Two segments appear to exist along this section ofthe arc the northern Bataan and southern Mindoro segments whichare separated by the Macolod Corridor. The volcanic rocks have typical arc phenocryst mineralogies:olivine, clinopyroxene, plagioclase, and titanomagnetite inthe most mafic rocks and clinopyroxene, plagioclase, orthopyroxene,titanomagnetite, ? amphibole in the more felsic samples. Complexzoning, sieve textures, and decoupling of incompatible traceelements suggest that processes such as assimilation have takenplace. The rocks from the study area range from basalts to rhyolitesand show typical calc-alkaline features. The rocks of the MacolodCorridor and Mindoro segment are particularly enriched in largeion lithophile elements (LILE), light rare earth elements (LREE),and radiogenic Sr compared with the Bataan segment. The datafall within the mantle array on Sr-Nd isotopic diagrams andgrade toward higher Sr and lower Nd isotopic values from northto south. A likely source for the volcanics of this study is either amid-ocean ridge basalt (MORB)-type mantle that undergoes higherdegrees of partial melting than regions involved in MORB generationor a previously depleted source. We suggest that the high fieldstrength element (HFSE) anomalies have been derived throughdifferential element partitioning during fluid transport fromthe subducted lithosphere to the mantle wedge. Continental crustal material seems to play a significant roleparticularly in the Macolod Corridor and the Mindoro segment,based on the high LILE, La/Sm ratios, radiogenic Sr isotopes,and 18O values. The Macolod Corridor and the Mindoro segmenthave undergone source contamination by crustal material fromthe North Palawan-Mindoro crustal block either during the collisionof this block with the Manila Trench or by subduction of sedimentsrich in this crustal material. A similar component has alsobeen detected in the Bataan segment but in minor amounts. Thetrace element and isotopic differences between the northernand southern sections of the arc are interpreted in terms ofvariable composition (i. e., variable amounts of a crustal componentintroduced from the Palawan-Mindoro crustal terrain) of themetasomatic fluids released into the source.  相似文献   
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Unconsolidated sand, gravel and clay deposits near Beihai and in the Leizhou Peninsula in southern China form an unconfined aquifer, aquitard and a confined aquifer. Water and soil samples were collected from the two aquifers in the coastal Beihai area for the determination of chemical compositions, minerals and soluble ions. Hydrogeochemical modeling of three flow paths through the aquitard are carried out using PHREEQC to determine water–rock interactions along the flow paths. The results indicate that the dissolution of anorthite, fluorite, halite, rhodochrosite and CO2, and precipitation of potash feldspar and kaolinite may be occurring when groundwater leaks through the aquitard from the unconfined aquifer to the confined aquifer. Cation exchanges between Na and Ca can also happen along the flow paths.  相似文献   
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Summary The Aguablanca Ni-Cu-(PGE) magmatic sulphide deposit is associated with a magmatic breccia located in the northern part of the Aguablanca gabbro (SW, Iberia). Three types of ores are present: semi-massive, disseminated, and chalcopyrite-rich veined ore. The principal ore minerals are pyrrhotite, pentlandite and chalcopyrite. A relatively abundant platinum-group mineral (PGM) assemblage is present and includes merenskyite, melonite, michenerite, moncheite and sperrylite. Moreover, concentrations of base and precious metals and micro-PIXE analyses were obtained for the three ore-types. The mineralogy and the mantle-normalised chalcophile element profiles strongly suggest that semi-massive ore represents mss crystallisation, whereas the disseminated ore represents an unfractionated sulphide liquid and the chalcopyrite-rich veined ore a Cu-rich sulphide liquid. Palladium-bearing minerals occur commonly enclosed within sulphides, indicating a magmatic origin rather than hydrothermal. The occurrences and the composition of these minerals suggest that Pd was initially dissolved in the sulphides and subsequently exsolved at low temperatures to form bismutotellurides. Negative Pt and Au anomalies in the mantle-normalised chalcophile element profiles, a lack of Cu-S correlation and textural observations (such as sperrylite losing its euhedral shape when in contact with altered minerals) suggest partial remobilisation of Pt, Au and Cu by postmagmatic hydrothermal fluids after the sulphide crystallisation. Authors’ addresses: R. Pi?a, L. Ortega, R. Lunar, Departamento de Cristalografía y Mineralogía, Facultad de Geología, Universidad Complutense de Madrid, ES-28040 Madrid, Spain; F. Gervilla, Facultad de Ciencias, Instituto Andaluz de Ciencias de la Tierra, Universidad de Granada-CSIC, Avda. Fuentenueva, s/n, ES-18002 Granada, Spain  相似文献   
8.
Diel patterns in the chlorophyll a specific absorption coefficient of surface picoplankton, a*pico (γ) (m2·[mg chlorophyll a]−1), were studied at 7 stations under daily cycle of in situ light condition in the western subarctic Pacific and Japan Sea. All the data were normalized by dividing the anomaly with daily averaged a*pico (γ). Opposite diel patterns were observed for the normalized a*pico (443) and a*pico (675) with maximum toward dawn or dusk and minimum toward midday at 4 stations under low-irradiance (LI) conditions and vice versa at 3 stations under high-irradiance (HI) conditions. The absorption efficiency factors at red absorption peak, Q a (675), were determined by reconstruction with intracellular chlorophyll a concentration and cell diameter. The normalized Q a (675) also showed diel pattern with maximum toward midday and minimum toward dawn or dusk under LI. The diel pattern in a*pico (675) and Q a (675) were primarily caused by changes in intracellular chlorophyll a concentration due to photoadaptation under LI. The diel pattern in a*pico (443) was influenced by pigmentation, as recognized by blue to red ratio [a*pico (443)/a*pico (675)] under HI. This study proposed that the opposite diel pattern in a*pico (γ) might occur for a wide range of algal species. The results presented here have important consequences for the interpretation of diel variations in optical properties observed in the open ocean.  相似文献   
9.
The measurements of the vertical transport of CO2 were carried out over the Sea of Japan using the specially designed pier of Kyoto University on September 20 to 22, 2000. CO2 fluxes were measured by the eddy correlation and aerodynamic techniques. Both techniques showed comparable CO2 fluxes during sea breeze conditions: −0.001 to −0.08 mg m−2s−1 with the mean of −0.05 mg m−2s−1. This means that the measuring site satisfies the fetch requirement for meteorological observations under sea breeze conditions. Moreover, the eddy diffusivity coefficient used in the aerodynamic technique is found to be consistent with the coefficient used in the eddy correlation technique. The present result leads us to conclude that the aerodynamic technique may be applicable to underway CO2 flux measurements over the ocean and may be used in place of the bulk technique. The important point is the need to maintain a measuring accuracy of CO2 concentration difference of the order of 0.1 ppmv on the research vessels or the buoys.  相似文献   
10.
To evaluate the contribution of biogeochemical processes to the oceanic carbon cycle and to calculate the ratio of calcium carbonate to organic carbon downward export, we have incorporated biological and alkalinity pumps in the yoked high-latitude exchange/interior diffusion-advection (YOLDA) model. The biogeochemical processes are represented by four parameters. The values of the parameters are tuned so that the model can reproduce the observed phosphate and alkalinity distributions in each oceanic region. The sensitivity of the model to the biogeochemical parameters shows that biological production rates in the euphotic zone and decomposition depths of particulate matters significantly influence horizontal and vertical distributions of biogeochemical substances. The modeled vertical fluxes of particulate organic phosphorus and calcium carbonate are converted to vertical carbon fluxes by the biological pump and the alkalinity pump, respectively. The downward carbon flux from the surface layer to the deep layer in the entire region is estimated to be 3.36 PgC/yr, which consists of 2.93 PgC/yr from the biological pump and 0.43 PgC/yr from the alkalinity pump, which is consistent with previous studies. The modeled rain ratio is higher with depth and higher in the Pacific and Indian Oceans than in the Atlantic Ocean. The global rain ratio at the surface layer is calculated to be 0.14 to 0.15. This value lies between the lower and higher ends of the previous estimates, which range widely from 0.05 to 0.25. This study indicates that the rain ratio is unlikely to be higher than 0.15, at least in the surface waters.  相似文献   
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