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1.
The development of the future atmospheric chemical composition is investigated with respect to NO y and O3 by means of the off‐line coupled dynamic‐chemical general circulation model ECHAM3/CHEM. Two time slice experiments have been performed for the years 1992 and 2015, which include changes in sea surface temperatures, greenhouse gas concentrations, emissions of CFCs, NO x and other species, i.e., the 2015 simulation accounts for changes in chemically relevant emissions and for a climate change and its impact on air chemistry. The 2015 simulation clearly shows a global increase in ozone except for large areas of the lower stratosphere, where no significant changes or even decreases in the ozone concentration are found. For a better understanding of the importance of (A) emissions like NO x and CFCs, (B) future changes of air temperature and water vapour concentration, and (C) other dynamical parameters, like precipitation and changes in the circulation, diabatic circulation, stratosphere‐troposphere‐exchange, the simulation of the future atmosphere has been performed stepwise. This method requires a climate‐chemistry model without interactive coupling of chemical species. Model results show that the direct effect of emissions (A) plays a major rôle for the composition of the future atmosphere, but they also clearly show that climate change (B and C) has a significant impact and strongly reduces the NO y and ozone concentration in the lower stratosphere.  相似文献   
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An excellent section in the Welzow-Süd open-cast lignite mine in Lower Lusatia, eastern Germany, provided a rare opportunity to study a small (5 m deep), buried subglacial meltwater channel of Saalian age. The channel is steep-sided and distinctly U-shaped. It is separated from undeformed outwash deposits in which it is incised by a sharp erosional contact and it is filled with meltwater sand and till. The till was possibly squeezed into the channel from the adjacent ice/bed interface. Directly beneath the channel, there is a partly truncated diapir of clayey silt, evidencing sediment intrusion into the channel from below. During channel formation, the pressure gradient was oriented from the surrounding sediments into the channel, so that the channel served as a drainage conduit for groundwater from the adjacent subglacial aquifer. The substratum consists largely of sandy aquifers with a total thickness of about 100 m, separated by two aquitards. Channel formation was initiated when hydraulic transmissivity of the bed did not suffice to evacuate all the subglacial meltwater as groundwater flow. As the Welzow-Süd channel belongs to a dense network of subglacial channels in eastern Germany, temporary ice-sheet instability in this region prior to channel formation seems possible.  相似文献   
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Compiled data from published and unpublished sources on copepod grazing of the large-sized copepods in the Barents Sea give wide ranges in grazing rates. Approximate average values indicate daily rations of 7–18% for copepodite stages V and VI and considerably higher values for the earliest copepodite stages. It is demonstrated that individual variability in gut fullness of copepods from a given locality is typically very high and not closely related to variable food abundance or depth of occurrence. There is no diel feeding rhythm during the summer, and even when relating copepod grazing to a number of biotic and abiotic factors through stepwise linear regression analysis, much of the variability remains unexplained. It is suggested that feeding behaviour, food quality and feeding history of the copepods all play important roles as factors which regulate copepod grazing. Model simulations on the phytoplankton succession, using literature data on laboratory-determined growth characteristics for solitary cells and colonies of the prymnesiophyte Phaeocystis pouchetii and large diatoms, indicate that the extent of the mixed layer and selective grazing by zooplankton are important factors that may explain the occurrence of dense blooms of P. pouchetii colonies, frequently observed during the spring.  相似文献   
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Diatom ooze and diatomaceous mudstone overlie terrigenous mudstone beds at Leg 19 Deep Sea Drilling Project sites. The diatomaceous units are 300-725 m thick but most commonly are about 600 m. Diagenesis of diatom frustules follows a predictable series of physical and chemical changes that are related primarily to temperature (depth of burial and local geothermal gradient). During the first 300-400 m of burial frustules are fragmented and undergo mild dissolution. By 600 m dissolution of opal-A (biogenic silica) is widespread. Silica reprecipitates abundantly as inorganic opal-A between 600 and 700 m sub-bottom depth. Inorganic opal-A is rapidly transformed by crystal growth to opal-CT. The result is formation of silica cemented mudstone and porcelanite beds. A regional acoustic reflector (called the bottom-simulating reflector, or BSR) occurs near 600 m depth in the sections. This acoustic event marks the upper surface where silicification (cementation) is active. In Bering Sea deposits, opal-A is transformed to opal-CT at temperatures between 35° and 50°C. This temperature range corresponds to a sub-bottom depth of about 600 m and is the area where silicification is most active. Thus, the BSR represents an isothermal surface; the temperature it records is that required to transform opal-A to opal-CT. Deposition of at least 500 m of diatomaceous sediment was required before the temperature at the base of the diatomaceous section was appropriate (35°-50°C) for silica diagenesis to occur. Accordingly, silica diagenesis did not begin until Pleistocene time. Once silicification began, in response to sediment accumulation during the Quaternary, the diagenetic front (the BSR) moved upsection in pace with the upward migrating thermal boundary. X-ray diffractograms and SEM photographs show three silica phases, biogenic opal-A, inorganic opal-A’, and opal-CT. These have crystallite sizes of 11-16 A, 20-27 A, and 40-81 A, respectively, normal to 101. The d(101) reflection of opal-CT decreases with depth of burial at DSDP Site 192. This occurs by solid-state ordering and requires at least 700 m of burial. Most clinoptilolite in Leg 19 cores forms from the diagenesis of siliceous debris rather than from the alteration of volcanic debris as is commonly reported.  相似文献   
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The volcanic history of Santo Antão, NW Cape Verde Islands,includes the eruption of basanite–phonolite series magmasbetween 7·5 and 0·3 Ma and (melilite) nephelinite–phonoliteseries magmas from 0·7 to 0·1 Ma. The most primitivevolcanic rocks are olivine ± clinopyroxene-phyric, whereasthe more evolved rocks have phenocrysts of clinopyroxene ±Fe–Tioxide ± kaersutite ± haüyne ± titanite± sanidine; plagioclase occurs in some intermediate rocks.The analysed samples span a range of 19–0·03% MgO;the most primitive have 37–46% SiO2, 2·5–7%TiO2 and are enriched 50–200 x primitive mantle in highlyincompatible elements; the basanitic series is less enrichedthan the nephelinitic series. Geochemical trends in each seriescan be modelled by fractional crystallization of phenocrystassemblages from basanitic and nephelinitic parental magmas.There is little evidence for mineral–melt disequilibrium,and thus magma mixing is not of major importance in controllingbulk-rock compositions. Mantle melting processes are modelledusing fractionation-corrected magma compositions; the modelssuggest 1–4% partial melting of a heterogeneous mantleperidotite source at depths of 90–125 km. Incompatibleelement enrichment among the most primitive magma types is typicalof HIMU OIB. The Sr, Nd and Pb isotopic compositions of theSanto Antão volcanic sequence and geochemical characterchange systematically with time. The older volcanic rocks (7·5–2Ma) vary between two main mantle source components, one of whichis a young HIMU type with 206Pb/204Pb = 19·88, 7/4 =–5, 8/4 0, 87Sr/86Sr = 0·7033 and 143Nd/144Nd= 0·51288, whereas the other has somewhat less radiogenicSr and Pb and more radiogenic Nd. The intermediate age volcanicrocks (2–0·3 Ma) show a change of sources to two-componentmixing between a carbonatite-related young HIMU-type source(206Pb/204Pb = 19·93, 7/4 = –5, 8/4 = –38,87Sr/86Sr = 0·70304) and a DM-like source. A more incompatibleelement-enriched component with 7/4 > 0 (old HIMU type) isprominent in the young volcanic rocks (0·3–0·1Ma). The EM1 component that is important in the southern CapeVerde Islands appears to have played no role in the petrogenesisof the Santo Antão magmas. The primary magmas are arguedto be derived by partial melting in the Cape Verde mantle plume;temporal changes in composition are suggested to reflect layeringin the plume conduit. KEY WORDS: radiogenic isotopes; geochemistry; mantle melting; Cape Verde  相似文献   
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Distribution and life history of krill from the Barents Sea   总被引:2,自引:0,他引:2  
Krill from the Barents Sea were studied on six cruises from 1985 to 1989. Thysanoessa inermis and T. longicaudata were the dominant species, while T. raschii and Meganyctiphanes norvegica were rarer in the studied areas. The two dominant species T. inermis and T. longicaudata are mainly found in the Atlantic. Water and they do not to a large extent penetrate into Arctic water masses in the northern Barents Sea. M. norvegica is a more strict boreal species that does not occur as extensively in the Barents Sea as do the Thysanoessa species. The mean population abundance ranged from 1 to 61 individuals m−2 for T. inermis and from 2 to 52 ind. M−2 for T. longicaudata . The mean dry weight biomass of these two species ranged from 14 to 616 and from 19 to 105 mg−2. Length frequency distributions indicate a life span of just over two years for T. inermis and T. longicaudata . Growth took place from about April to autumn with no apparent growth during winter. Maturation and spawning seem to occur after two years for T. inermis and one year for T. longicaudata . Main spawning occurred from May to June coinciding with the spring phytoplankton bloom. Captive spawners of T. inermis (total length 17-22 mm) shed 30-110 eggs per female in a single batch.  相似文献   
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The Cambro-Ordovician Cap Enragé Formation is interpreted as a deep submarine channel complex of conglomerates, pebbly sandstones and massive sandstones. The formation is up to 270 m thick, and crops out in a coastal belt 50 km long. In general terms, it has previously been interpreted as a deep sea channel deposit, with the channel about 300 m deep, at least 10 km wide and trending south-westward, parallel to the coastal outcrops. Eight facies have been defined in this study and they have been grouped into three major facies associations. In the Coarse Channelled Association, conglomerates with carbonate boulders up to about 4 m are associated with graded-stratified finer grained conglomerates. Facies of this association make up about 25% of all the beds in the formation. The association is also characterized by abundant major channels 1–10 m deep and up to 250 m wide. Excellent outcrop allows the reconstruction of topographic highs (bars) within the channels and the association is interpreted as a braided channel and bar system. The second association, Multiple-Scoured Coarse Sandstones, contains some graded-stratified fine conglomerates, along with massive to structureless coarse and pebbly sandstones, and rare cross-bedded pebbly sandstones. Deep channels are absent, but multiple channelling on the scale of 0.5–1 m is characteristic. In the absence of the very coarse conglomerates and deeper channelling, this association is interpreted as being deposited on topographically higher terrace areas adjacent to the main braid plain. The third facies association, Unchannelled Sandstones, is characterized by massive sandstones with abundant fluid-escape structures, classical turbidites and thin shales. In the absence of any scouring deeper than a few tens of centimetres, this association is interpreted as being deposited on an even higher and smoother terrace, farther from the braid plain. Palaeoflow directions for conglomerate facies indicate fairly consistent south-westward transport, apparently parallel to the base of the Cambro-Ordovician continental slope. Flow directions in the finer-grained facies are rather variable, suggesting complex bar development and overbank spills. Thinning-and fining-upward sequences are present on two scales. The smaller, 1–10 m sequence, is related to channel filling and abandonment. Thicker sequences (10–100 m), with facies of the Multiple Scoured, and Unchannelled Sandstone Associations, may indicate switching of a main channel away from the area and its subsequent burial by marginal terrace and higher terrace deposits.  相似文献   
10.
Origin of authigenic carbonates in sediment from the deep Bering Sea   总被引:1,自引:0,他引:1  
Forty beds of authigenic carbonate were identified from the deep Bering Sea in cores taken on Leg 19 of the Deep Sea Drilling Project. Carbonate minerals were mainly high-magnesium calcite and protodolomite, less commonly siderite, rhodo-chrosite, low-magnesium calcite, and manganosiderite. Authigenic carbonates cement and replace diatom ooze, ash and bentonite beds, and, less commonly, clastic beds. Replacement zones are as much as 60 cm thick. Eighty-five per cent of carbonate beds occurred below 400 m sub-bottom depth and 70% in sediment older than 4 m.y. δ13C values averaged -17.200/00 PDB and δ18O ranged from 18.59 to 34–110/00SMOW. The carbon was derived from oxidation of organic matter under anaerobic conditions during bacterial reduction of sulphate, or from CO2 produced in concert with CH4 during degradation of organic matter. The cations (Ca, Mg, Fe, Mn) were derived from alteration of ash beds. In Bering Sea deposits, ash beds altered to smectite within about 3–5 m.y. Carbonate precipitated simultaneously at different stratigraphic levels within the 627–1057 m sections at temperatures of 7–85°C. No apparent calcite precursor of biogenic origin was found for these authigenic carbonates.  相似文献   
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