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1.
The Paasivaara PGE reef in the Penikat layered intrusion,northern Finland   总被引:1,自引:0,他引:1  
Summary Three major PGE-bearing mineralized zones have been found in the layered series of the early Proterozoic Penikat layered intrusion. These are designated as the Sompujärvi (SJ), Ala-Penikka (AP) and Paasivaara (PV) Reefs according to the site of their initial discovery.The uppermost of these, the PV Reef, has the highest Pt/Pd ratio. It is located in the transition zone between the fourth and the fifth megacyclic units. The main host rock is the uppermost anorthosite, disseminated sulphides and associated PGM being concentrated in the interstices of this plagioclase orthocumulate. The Reef has also been encountered in other parts of the transition zone, however, and sometimes even in the lowermost parts of the fifth megacyclic unit. The dominant sulphide paragenesis is chalcopyrite-pyrrhotite-pentlandite, whereas the PGM identified are represented by sperrylite (PtAs2), kotulskite (PdTe), merenskyite (PdTe2), isomertieite (Pd11Sb2As2), stibiopalladinite (Pd5Sb2), cooperite (PtS) and braggite ((Pt, Pd, Ni)S).It is suggested that the PV Reef was formed in the mixing process when the fifth magma pulse intruded into the magma chamber. Mixing of the new magma with the older residual magma in the chamber accounted for the sulphide precipitation. Mixing and convection were probably turbulent at first and the sulphides were thus able to "scavenge" PGE from a large amount of silicate melt. The metal ratios in the mineralization point to a close genetic relationship with the fifth magma pulse.
Das Paasivaara PGE Reef in der Penikat-Intrusion, Nord-Finnland
Zusammenfassung In den geschichteten Serien der frühproterozoischen Intrusion von Penikat kommen drei grössere PGE-führende Zonen vor. Diese werden als die Sompujärvi (SJ), Ala-Penikka (AP) und Paasivaara (PV) Reefs bezeichnet, entsprechend den Lokalitäten der Entdeckung.Das am höchsten gelegene PV Reef hat die höchsten Pt/Pd Verhältnisse. Es liegt in der Übergangszone zwischen der vierten und der fünften megazyklischen Einheit. Das wichtigste Wirtsgestein ist der oberste Anorthosit, wo disseminierte Sulfide und assoziierte PGM in den Zwischenräumen dieses Plagioklas-Orthokumulates vorkommen. Das Reef wurde auch in anderen Teilen der Überganszone beobachtet und manchmal sogar in den untersten Partien der fünften megazyklischen Einheit. Die dominierende Sulfidparagenese ist Kupferkies-Magnetkies-Pentlandit; PGM sind Sperrylith (PtAs2), Kotulskit (PdTe), Merenskyit (PdTe2), Isomertieit (Pd11Sb2As2), Stibiopalladinit (Pd5Sb2), Cooperite (PtS) und Braggit ((Pt, Pd, Ni)S).Es wird angeregt, dass das PV Reef während der Mischungsvorgänge bei der Intrusion des fünften Magma Pulses in die Magmenkammer entstanden ist. Mischung des neuen Magmas mit dem alten Residual-Magma in der Kammer war für die Ausfällung der Sulfide verantwortlich. Mischung und Konvektion dürften anfangs turbulent gewesen sein, und so konnten die Sulfide die PGE aus einem beträchtlichen Anteil der Silikatschmelze entfernen. Die Metallverhältnisse dieser Vererzung lassen eine enge genetische Verbindung mit dem fünften Magmapuls erkennen.


With 8 Figures  相似文献   
2.
Summary Early Proterozoic layered intrusions, about 2440 Ma in age, are widespread over a large area of the northeastern Fennoscandian Shield in Finland, Sweden and the Soviet Union. Only one intrusion, the Kukkola intrusion, is encountered in Sweden whereas in Finland, their number exceeds twenty. These are concentrated principally in two areas, the dicontinuous Tornio-Närdnkävaara intrusion belt which crosses northern Finland and the Koitelainen intrusion with its satellites located in central Finnish Lapland. The intrusions in the Soviet Union are concentrated in three areas: (i) on the Kola Peninsula, (ii) in the Paanajärvi area close to the Finnish border and (iii) northeast of Lake Onega.Examples of all the ore types characteristic of layered intrusions have been found in these intrusions. Chromitite layers are encountered in the Kukkola/Tornio, Kemi, Penikat, Koitelainen and Burakovsky intrusions, but only one, the Kemi chromitite, has so far been mined. The Portimo, Koillismaa, Monchegorsk and Fedorova intrusions are characterized by PGE-bearing Cu-Ni-deposits in their marginal series. Mineralized zones enriched in PGE are also encountered in the layered series. Those in the Penikat intrusion and in the Portimo intrusions are the most remarkable and the best known to date. Vanadium-bearing Fe-Ti-oxide layers are encountered in several intrusions, but only one, the Mustavaara deposit, is presently being exploited.Two types of parental magma have tentatively been proposed for these intrusions. The first type is represented by a magma which was relatively rich in magnesium and chromium and was as a whole boninitic in composition, whereas the plagioclase-rich intrusions and megacyclic units are interpreted as having crystallized from a magma which was greatly depleted in these elements, especially Cr, and had melted crustal material incorporated in it.The emplacement of the early Proterozoic layered intrusions in Fennoscandia was part of the world-wide igneous activity indicated by other layered intrusions and mafic dyke swarms of similar age in other ancient cratons, i.e. the Jimberlana intrusion in Australia, the Great Dyke in Zimbabwe, the Scouric picrite suite in Scotland, the Hearst-Matachewan dyke swarm, Copper Cliff Formation and East Bull Lake intrusion in Ontario, Canada, and the Vestfold Hills and Napier Complex dyke swarms in Antarctica. This almost contemporaneous occurrence in different parts of the world would suggest a more intimate relationship between the Fennoscandian Shield, northwest Scotland, Canadian Shield, Yilgarn Block, Zimbabwe Craton and East Antarctic Shield at the beginning of the Proterozoic than at present.
Früh-Proterozoische geschichtete Intrusionen im nordöstlichen Teil des Fennoskandischen Schildes
Zusammenfassung Im Nordost-Teil des Fennoskandischen Schildes in Finnland, Schweden und der Sowjetunion kommen fast vierzig frühproterozoische geschichtete Intrusionen, die ungefähr 2440 Mio J. alt sind, vor. Nur eine davon, die Kukkola Intrusion, liegt in Schweden, während in Finnland mehr als zwanzig Intrusionen vorkommen. Diese sind hauptsächlich in zwei Gebieten konzentriert, nämlich in dem nicht-zusammenhängenden Tornio-Näränkävaara Gürtel, der das nördliche Finnland durchzieht, und die Koitelainen-Intrusion mit ihren Satelliten im zentralen Finnischen Lapland. Die Intrusionen in der Sowjetunion sind in drei Gebieten konzentriert: (i) auf der Kola Halbinsel (ii) im Paanajärvi Gebiet nahe der Finnischen Grenze und (iii) östlich vom Onega-See.Beispiele aller für geschichtete Intrusionen charakteristischen Erztypen kommen vor. Chromititlagen sind in den Intrusionen von Kukkola/Tornio, Kemi, Penikat, Koitelainen und Burakovsky zu finden, aber nur eine davon, der Kemi Chromitit, ist bisher in Abbau genommen worden.Die Portimo-, Koillismaa-, Monchegorsk- und Fedorova-Intrusionen werden durch PGE-führende Kupfer-Nickel-Lagerstätten in ihren randlichen Bereichen charakterisiert. Mineralisierte Zonen die an PGE angereichert sind kommen auch in den geschich teten Serien vor. Die bemerkenswertesten sind die PGE-Vererzungen der Penikat- und der Portimo-Intrusionen. Vanadium-führende Fe-Ti-Oxidlagen kommen in verschiedenen Intrusionen vor, aber nur eine davon, die Mustavaara-Lagerstätte, ist bisher abgebaut worden.Diese Intrusionen werden auf zwei verschiedene Magmentypen zurückgeführt. Ersteres ist ein Magma das relativ reich an Magnesium und Chrom war und eine boninitische Zusammensetzung hatte, während die Plagioklas-reichen Intrusionen, und die megazyklischen Einheiten auf ein Magma das an diesen Elementen (besonders Cr) verarmt war, und das Krustenmaterial aufgeschmolzen hat, zurückgehen.Die Platznahme der frühproterozoischen geschichteten Intrusionen in Fennoskandien stellt einen Teil weltweiter magmatischer Aktivität dar, die durch andere geschichtete Intrusionen und mafische Gänge von fast identischem Alter in anderen alten Kratonen repräsentiert wird. Hier ist die Jimberlana-Intrusion in Australien, der Great Dyke in Zimbabwe, die Pikrit-Suite von Scourie in Schottland, die Gänge von Hearst-Matachewan, die Copper Cliff Formation und die East Bull Lake Intrusion in Ontario, Kanada ebenso wie die Gangsysteme der Vesthold Hills und des Napier Komplexes in Antarctica zu nennen. Diese fast gleichaltrigen Vorkommen in verschiedenen Teilen der Welt weisen auf eine engere Beziehung zwischen dem Fennoskandischen Schild, Nordwest-Schottland, dem Kanadischen Schild, dem Yilgarn Block, dem Zimbabwe-Craton und dem Ostantarktischen Schild zum Beginn des Proterozoikums hin.


With 7 Figures  相似文献   
3.
Reference conditions and changes in limnological conditions during the 20th century have been inferred in a palaeolimnological study of sediments from six lakes of the District of Sortavala, Karelian Republic, Russia. The area is former Finnish territory, which was in intensive use for arable field cultivation until the World War II, when the area was ceded to the Soviet Union. After the war, farming was resumed by cattle sovkhozes, and the fields were mainly used as pasture without regular ploughing. We have studied the history of eutrophication and recovery in some lakes related with the changes of agricultural intensity. The trophic level of the lakes was studied by sedimentary diatom assemblages, including reconstructions of total phosphorus levels in the lakes based on a weighted averaging transfer function. Pollen analyses were used to assess the changes in the land use near the lakes. Valuable background data on all the lakes used in the present study are provided by a doctoral thesis done on their limnology from the 1920s. According to our results, the four lakes situated on the clayey lowlands near the coast of Lake Ladoga were eutrophicating during the first half of the 20th century, and in two of them, a rapid recovery is evident. In two lakes situated in hilly landscape with limited agricultural activities, only minor changes are recorded in the diatom profiles.  相似文献   
4.
A short-core paleolimnological investigation was carried out to acquire knowledge of the recent history of Lake Pihlajavesi, Saimaa Lake complex, and define its natural state before cultural disturbances. In the natural state, with negligible human interference, the basin was oligotrophic and oxygen-rich. The bioproductivity in the littoral zone was low and the profundal benthic quality was good according to Wiederholm's Benthic Quality Index.Based on diatom analyses, no significant changes have taken place in the phytoplankton communities during the past decades. Sedimentary chironomid communities reveal, however, slight changes on profundal life in the Pihlajavedenselkä basin, near the main pollution sources, whereas there were no significant changes in the outer basin. Three stages could be distinguished in the pollution history of Pihlajavedenselkä: (1) 'The natural state' up until the 1960s, (2) 'the period of increasing loading' during the 1960s and 1970s, and (3) 'the recovery of the basin' during the past two decades.Untreated municipal waste water from the town of Savonlinna was partly responsible for the commencement of eutrophication in the Pihlajavedenselkä basin in the 1960s. The paper and pulp industry in Varkaus, some 40 kilometres upstream from Lake Pihlajanvesi, has also increased eutrophication, especially during the worst period of water quality in the 1960s and 1970s. More effective waste water purification has markedly reduced effluent loading and led to a general recovery of the area. Neverthless the effects of slight nutrient loading can still be seen, especially in littoral bioproductivity.Our paleolimnological data indicate that the present ecosystem will offer living conditions for the endemic Saimaa ringed seal population that are similar to those that existed prior to human disturbances.  相似文献   
5.
Reclamation of peat bogs for agriculture changes the physical and chemical characteristics of the peat matrix, for example, drainage and tillage accelerate decomposition, altering peat porosity, pore size distribution, and hydraulic properties. This study investigated changes in near-saturated hydraulic conductivity over time after drainage of peat soil for agricultural use by conducting tension infiltrometer measurements in a mire that has been gradually drained and reclaimed for agriculture during the past 80 years (with fields drained 2, 12, 40, and 80 years before the measurements). At pore water pressure closest to saturation (pressure head −1 cm), hydraulic conductivity in the newest field was approximately nine times larger than that in the oldest field, and a decreasing trend with field age was observed. A similar (but weaker) trend was observed with −3 cm pressure head (approximately four times larger in the newest field in comparison to the oldest), but at −6 cm head, there were no significant differences. These results indicate that peat degradation reduces the amount of millimetre-sized pores in particular. They also indicate that changes in peat macroporosity continue for several decades before a new steady state is reached.  相似文献   
6.
The Paleoproterozoic cover sequence at the 100–150 km wide western margin of the Archean Karelian Province is dominated by deep water Lower and Upper Kaleva metasediments. We present here an interpretation of Sm–Nd isotope and geochemical data on 36 samples, TIMS multi-grain U–Pb zircon analyses on nine samples, and ca. 100 SIMS analysis of detrital zircon grains from four Upper Kaleva and one Lower Kaleva samples.The Lower Kaleva is characterized by autochthonous–parautochthonous, lithologically heterogeneous metaturbidites showing common enrichment in quartz. All the analysed detrital zircons are of a local Neoarchean source but tDM variation up to 2.4 Ga combined with geochemical data indicate abundant mixing of Paleoproterozoic mafic material, presumably from 2.1 Ga plateau lavas and dykes, in most of the Lower Kaleva samples.The Upper Kaleva is dominantly allochthonous with tectonically enclosed fragments of ophiolite bodies, and it is characterized by lithological and geochemical-isotopic homogeneity. Geochemical, isotopic and detrital zircon data favour material derived from an orogenic domain, comprising both Archean and Proterozoic units, followed by effective mixing during the transport. The Archean zircon grains (25%) are mostly Neoarchean. The Paleoproterozoic grains lack zircons at 2.5–2.2 Ga and plot dominantly (92%) between 1.92 and 2.05 Ga. The indicated maximum deposition ages vary from 1.95–1.94 Ga to 1.92 Ga. The main source area proposed is the Himalaya-type Lapland-Kola orogen (now) in the northeast, which experienced mountain building and erosion at 1.95–1.91 Ga.The western margin of the Karelian Province shows evidence of rifting and lithosphere thinning from 2.1 to 1.95 Ga but it is still under debate whether the craton breakup occurred at 2.06 Ga in a volcanic or later at 1.95 Ga in a non-volcanic margin setting. One hypothesis is that the onset of collision in the northeast changed plate motion and lead to a new spreading within the pre-existing passive margin at 1.97–1.95 Ga. Thus, both a volcanic margin at 2.06 Ga and a non-volcanic margin at ca. 1.95 Ga could have been operated at the western margin of the Karelian Province.  相似文献   
7.
In the central part of the Fennoscandian Shield, the Talvivaara Ni–Zn–Cu–Co deposit, hosted by Palaeoproterozoic metamorphosed black schists, contains low uranium concentrations ranging from 10 to 30 ppm. The Talvivaara black schists were deposited 2.0–1.9 Ga ago and underwent subsequent metamorphism during the 1.9–1.79 Ga Svecofennian orogeny. Anhedral uraninite crystals rimmed by bitumen constitute the main host of uranium. U–Pb secondary ion mass spectrometry dating indicates that uraninite crystals were formed between 1,878?±?17 and 1,871?±?43 Ma, during peak metamorphism. Rare earth element patterns and high Th content (average 6.38 wt%) in disseminated uraninite crystals indicate that U was concentrated during high temperature metamorphism (>400 °C). The formation of bitumen rims around uraninite may be explained by two distinct scenarios: (a) a transport of U coincident with the migration of hydrocarbons or (b) post-metamorphic formation of bitumen rims, through radiolytic polymerization of gaseous hydrocarbons at the contact with uraninite.  相似文献   
8.
Geochronology of detrital zircons and their overgrowths combined with whole-rock geochemical and Sm–Nd isotopic data can be used to distinguish different stages of sediment recycling and metamorphism during multiphase orogenic evolution. This approach is applied to the Paleoproterozoic sedimentary rocks of the Tampere and Pirkanmaa belts (southern Finland) in the center of the composite Svecofennian orogen.The lower part of the Tampere belt succession and bulk of the Pirkanmaa belt are characterized by turbidites whereas the upper part of the Tampere belt succession is dominated by 1.90–1.89 Ga mature arc-type volcanic rocks. Detrital zircon geochronology indicates that the Tampere and Pirkanmaa belts have a coeval 1.92–1.89 Ga depositional and tectonic history. Ages of pre-depositional zircon overgrowths vary from 1.91 Ga to 2.0 Ga with clusters at 1.92 Ga and 1.98 Ga. Within the Pirkanmaa belt, post-depositional zircon overgrowths indicate metamorphic culmination at c. 1885 Ma in the Vammala Ni-zone and at c. 1875 Ma in the northern part.The lower conglomerates and graywackes in the Tampere belt and their equivalents in the Pirkanmaa belt are rich both in Neoarchean and Paleoproterozoic grains, the latter ranging in age from 1.9 to 2.1 Ga. Compared to these, a sample from the Vammala Ni-zone has an exotic provenance with at least c. 1.90 Ga, 2.04–2.15 Ga, 2.38–2.48 Ga and 2.57–2.63 Ga components.A sedimentary recycling and tectonic model for the central Fennoscandia is proposed, in which the Paleoproterozoic Keitele + Bergslagen continent was formed during an unnamed orogeny at 1.98–1.97 Ga. The Archean Norrbotten microcontinent was attached to the continent at 1.97–1.93 Ga. Upper Kaleva turbidites, derived from the Lapland-Kola orogen in the north, were deposited before 1.92 Ga on a passive margin of the Archean Karelia craton. The Karelia craton collided with the Keitele + Bergslagen + Norrbotten continent at c. 1.92 Ga forming the Lapland-Savo orogen. Subsequent evolution led to rifting and break-up of the latter continent into two microcontinents in the hinterland. At 1.92–1.91 Ga the rift was developed into a subsiding passive margin of the Keitele microcontinent with voluminous turbidite deposition, now seen as graywackes in the Tampere, Pirkanmaa and Pohjanmaa (western Finland) belts. The turbidite material was derived from the rising Lapland-Savo orogen and included recycled Upper Kaleva, recycled (sandstones) and first-cycle 2.03–1.97 Ga detritus from Keitele, 1.93–1.92 Ga Savo arc material, as well as detritus from the Archean craton and its cover deposits. The collision between Karelia and Keitele caused a subduction reversal and the onset of Tampere arc volcanism at 1.90 Ga. Arc-derived materials started to deposit and were mixed with older sedimentary rocks, and trench-parallel distal turbidites from exotic source were being deposited in the accretionary wedge.  相似文献   
9.
The change in the mean temperature in Finland is investigated with a dynamic linear model in order to define the sign and the magnitude of the trend in the temperature time series within the last 166 years. The data consists of gridded monthly mean temperatures. The grid has a 10 km spatial resolution, and it was created by interpolating a homogenized temperature series measured at Finnish weather stations. Seasonal variation in the temperature and the autocorrelation structure of the time series were taken account in the model. Finnish temperature time series exhibits a statistically significant trend, which is consistent with human-induced global warming. The mean temperature has risen very likely over 2 °C in the years 1847–2013, which amounts to 0.14 °C/decade. The warming after the late 1960s has been more rapid than ever before. The increase in the temperature has been highest in November, December and January. Also spring months (March, April, May) have warmed more than the annual average, but the change in summer months has been less evident. The detected warming exceeds the global trend clearly, which matches the postulation that the warming is stronger at higher latitudes.  相似文献   
10.
A Paleoproterozoic lateritic paleosol overlain by ultra-mature/mature quartzite is reported for the first time from three localities in the Svecofennian province in southern Finland. These are important indicators for warm paleoclimate and continental paleoenvironment. Ultra-mature quartzites above the lateritic paleosols are overlain by matrix-supported conglomerates followed by mature quartzites. These latter rocks are related to incipient rifting followed by main rift stage starting with increasingly more immature meta-arkose.  相似文献   
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