On the survivability of an enantiomeric excess of amino acids in comet nuclei during the decay of26Al and other radionuclides     

Rafael Navarro-González  Alfredo Romero 《Astrophysics and Space Science》1996,236(1):49-60

We present a computer model calculation for the racemization of a possible excess of amino acids in the icy fraction of comet nuclei bring about by ionizing radiation released during the decay of²⁶Al,⁴⁰K,²³⁵U,²³⁸U and²³²Th. The model takes into account a total of 110 chemical reactions, of which 91 are needed to explain the radiation chemical processing of the major constituents of comet nuclei (Navarro-Gonzálezet al., 1992) and 19 are necessary to simulate the radiolysis of glycine/alanine mixtures in aqueous solutions (Navarro-Gonzálezet al., 1994 and 1996). It is predicted that an enantiomeric excess of alanine would not be destroyed by radioracemization during the decay of embedded radionuclides. Nevertheless, this enantiomeric excess could be attenuated by the formation of racemic amino acids in the interior of comet nuclei as a result of the radiation-induced polymerization of HCN.  相似文献   

Trace elements contamination of agricultural soils affected by sulphide exploitation (Iberian Pyrite Belt,Sw Spain)   总被引：1，自引：0，他引：1  

María López  Isabel González  Antonio Romero 《Environmental Geology》2008,54(4):805-818

Agricultural soils of the Riotinto mining area (Iberian Pyrite Belt) have been studied to assess the degree of pollution by trace elements as a consequence of the extraction and treatment of sulphides. Fifteen soil samples were collected and analysed by ICP-OES and INAA for 51 elements. Chemical analyses showed an As–Cu–Pb–Zn association related with the mineralisation of the Iberian Pyrite Belt. Concentrations were 19–994 mg kg⁻¹ for As, 41–4,890 mg kg⁻¹ for Pb, 95–897 mg kg⁻¹ for Zn and of 27–1,160 mg kg⁻¹ for Cu. Most of the samples displayed concentrations of these elements higher than the 90th percentile of the corresponding geological dominium, which suggests an anthropogenic input besides the bedrock influence. Samples collected from sediments were more contaminated than leptosols because they were polluted by leachates or by mining spills coming from the waste rock piles. The weathering of the bedrock is responsible for high concentrations in Co, Cr and Ni, but an anthropogenic input, such as wind-blown dust, seems to be indicative of the high content of As, Cu, Pb and Zn in leptosols. The metal partitioning patterns show that most trace elements are associated with Fe amorphous oxy-hydroxides, or take part of the residual fraction. According to the results obtained, the following mobility sequence is proposed for major and minor elements: Mn, Pb, Cd, > Zn, Cu > Ni > As > Fe > Cr. The high mobility of Pb, Cu and Zn involve an environmental risk in this area, even in soils where the concentrations are not so high.  相似文献   

Response of zooid size in Cupuladria exfragminis (Bryozoa) to simulated upwelling temperatures     

Aaron O'Dea  Felix Rodríguez  & Tania Romero 《Marine Ecology》2007,28(2):315-323

We investigate the effect of the temperature–size rule upon zooids of the tropical American bryozoan Cupuladria exfragminis. Results show that mean zooid length, zooid width and zooid area vary significantly between clonal replicates of C. exfragminis kept under different controlled temperature conditions. Significantly larger zooids are produced during times of lowered water temperature that are comparable with the temperatures that occur during seasonal upwelling along the Pacific coast of Panama where the animal lives in abundance. Interpolation of data suggests that a drop of 1 °C causes a 5% increase in zooid size, and that almost all variation in zooid size in natural populations can be explained by temperature. Results are discussed in context of the potential use of zooid size variation in cupuladriid bryozoans to measure the strength of seasonal upwelling in ancient seas by analysing zooid size changes in fossil colonies. The technique of cloning cupuladriid colonies by fragmentation is also discussed with reference to its benefits in experimental studies where genotypes need to be controlled or replicated.  相似文献   

Otolith shape as a stock discrimination tool for ling (Genypterus blacodes) in the fjords of Chilean Patagonia     

Rodrigo Wiff  Andrés Flores  Angel M. Segura  Mauricio A. Barrientos  Vilma Ojeda 《新西兰海洋与淡水研究杂志》2020,54(2):218-232

ABSTRACT

Genypterus blacodes, in terms of its fishing history and local economic importance, is an emblematic species harvested in Chilean Patagonia (41°00’–57°00’S). Most of the current fisheries and biological knowledge of this species come from the open ocean, whereas information about the species in fjords and inner channels is fragmentary. In 2018, two research surveys targeting G. blacodes were conducted in the fjords and inner channels of Chilean Patagonia. A total of 253 pairs of sagittal otoliths were sampled at three different localities, and their contours were modelled using wavelet analysis as a tool for stock discrimination. Contours were compared using canonical analysis, and classification was performed using linear discriminant and Random Forest analyses. The results indicated that the wavelet method is efficient in modelling otolith contours, and the discriminant analyses showed differences among fishing grounds across the latitudinal gradient, thus confirming the hypothesis that G. blacodes conform to at least two separate stock units in Chilean Patagonia. Fishing grounds that were closer in space showed higher levels of misclassification. The discussion focuses on how environmental variables and the geography of fjords shape stock differences and how this information can be used for the sustainable management of G. blacodes.  相似文献   

Reconstruction of total annual rainfall in Andalusia (Southern Spain) during the 16th and 17th centuries from documentary sources     

F. S. Rodrigo  M. J. Esteban Parra  Y. Castro Diez 《Theoretical and Applied Climatology》1995,52(3-4):207-218

Summary This study describes a reconstruction of rainfall characteristics in Southern Spain from 1501 to 1700 AD, during the beginning of the period called the Little Ice Age. Weather information was taken from original documentary sources (urban annals, local and religious histories, municipal documents, relations, etc.) in the region. A numerical index was established to characterize the rainfall, its characteristics, evolution and geographical distribution. Results were characteristics compared with modern precipitation data and with the results of other studies of historical climate. The general conclusion is that rainfall in Western Andalusia increased from approximately 1550 to 1650 AD. Some perspectives for future research work are outlined.With 6 Figures  相似文献   

Hydrochemical and isotopical tracers in the lacustrine aquifer of the Cerro Prieto area, Baja California, México     

E. Portugal  J. lvarez  B.I. Romero 《Journal of Geochemical Exploration》2006,88(1-3):139

A series of patterns in the chemical and isotopic composition of the groundwater of the Cerro Prieto area have been recognized. These patterns were used to define four hydrochemical and isotopical zones in the area. One of these areas located at the east side was found to be the source of recharge, while another in the central part is where an older aquifer exist in lacustrine deposits. The low permeability of the area causes the aquifer to act as an aquitard, which at least is partly surrounded by an interface zone where mixing of waters occurs. Tritium and radiocarbon method revealed that the aquitard is an isolate system whose residence time is of 32 ka.  相似文献   

Intermittent chaos in nonlinear wave–wave interactions in space plasmas     

Rodrigo A. Miranda  Erico L. Rempel  Abraham C.-L. Chian  Felix A. Borotto 《Journal of Atmospheric and Solar》2005,67(17-18):1852

There is increasing observational evidence of nonlinear wave–wave interactions in space and astrophysical plasmas. We first review a number of theoretical models of nonlinear wave–wave interactions which our group has developed in the past years. We next describe a nonlinear three-mode truncated model of Alfvén waves, involving resonant interactions of one linearly unstable mode and two linearly damped modes. We construct a bifurcation diagram for this three-wave model and investigate the phenomenon of intermittent chaos. The theoretical results presented in this paper can improve our understanding of intermittent time series frequently observed in space and astrophysical plasmas.  相似文献   

Coupling watersheds,estuaries and regional ocean through numerical modelling for Western Iberia: a novel methodology   总被引：1，自引：1，他引：0  

Francisco Campuzano  David Brito  Manuela Juliano  Rodrigo Fernandes  Hilda de Pablo  Ramiro Neves 《Ocean Dynamics》2016,66(12):1745-1756

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Glacial flood pulse effects on benthic fauna in equatorial high‐Andean streams          下载免费PDF全文

Sophie Cauvy‐Fraunié  Patricio Andino  Rodrigo Espinosa  Roger Calvez  Fabien Anthelme  Dean Jacobsen  Olivier Dangles 《水文研究》2014,28(6):3008-3017

Equatorial glacier‐fed streams present unique hydraulic patterns when compared to glacier‐fed observed in temperate regions as the main variability in discharge occurs on a daily basis. To assess how benthic fauna respond to these specific hydraulic conditions, we investigated the relationships between flow regime, hydraulic conditions (boundary Reynolds number, Re*), and macroinvertebrate communities (taxon richness and abundance) in a tropical glacier‐fed stream located in the high Ecuadorian Andes (> 4000 m). Both physical and biotic variables were measured under four discharge conditions (base‐flow and glacial flood pulses of various intensities), at 30 random points, in two sites whose hydraulic conditions were representative to those found in other streams of the study catchment. While daily glacial flood pulses significantly increased hydraulic stress in the benthic habitats (appearance of Re* > 2000), low stress areas still persisted even during extreme flood events (Re* < 500). In contrast to previous research in temperate glacier‐fed streams, taxon richness and abundance were not significantly affected by changes in hydraulic conditions induced by daily glacial flood pulses. However, we found that a few rare taxa, in particular rare ones, preferentially occurred in highly stressed hydraulic habitats. Monte‐Carlo simulations of benthic communities under glacial flood reduction scenarios predicted that taxon richness would be significantly reduced by the loss of high hydraulic stress habitats following glacier shrinking. This pioneer study on the relationship between hydraulic conditions and benthic diversity in an equatorial glacial stream evidenced unknown effects of climate change on singular yet endangered aquatic systems. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Analysis of shaft resistance of jacked piles in sands     

Rodrigo Salgado 《国际地质力学数值与分析法杂志》2011,35(15):1605-1635

In recent years, pile jacking has become a viable alternative installation method for displacement piles. Pile jacking produces minimal noise, vibration and air pollution during installation. In addition, it is possible, at the end of jacking, to have a good estimate of the ultimate static capacity of the pile. In this paper, the shaft resistance of piles jacked into sand is studied using one‐dimensional finite element analysis. The finite element simulations, using a two‐surface plasticity model, demonstrate the effects of relative density and confinement on the unit shaft resistance of piles jacked in sand. The impact of the number of jacking strokes on the unit shaft capacity is also assessed. Based on the numerical results, we developed equations for shaft resistance quantifying the effects of relative density, initial confinement and number of jacking strokes. Predictions using these equations are compared with data obtained from centrifuge tests and field tests. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献