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1.
Littoral '92     

Reports

Littoral '92  相似文献   
2.
A mixture of C33–C37 botryococcenes and partially reduced derivatives was isolated from ca. 32,000 year old sediment from Lake Masoko, a freshwater crater lake in the Rungwe Range area (Tanzania). Botryococcenes and derivatives accounted for 246 μg/g dry sediment and for >92% of the hydrocarbon fraction; 1D and 2D nuclear magnetic resonance spectroscopy (NMR) and mass spectrometry allowed the structure of the dominant botryococcene (43% of hydrocarbon fraction) to be established, after purification using high performance liquid chromatography (HPLC). The compound is a novel tetraunsaturated dicyclic C34 botryococcene and is named C34 masokocene. Overall, the structures of six other novel botryococcenes and four partially reduced derivatives were tentatively assigned. The structures of the new biomarkers, three dicyclic C34–C36 botryococcenes (or masokocenes) and seven monocyclic C34–C37 analogues are discussed along with their biosynthetic relationship. The high abundance of such polyunsaturated compounds preserved in 32,000 year old sediment from the lake indicates an aquatic ecosystem dominated at the time by the green alga Botryococcus braunii, as well very good preservation of the organic matter.  相似文献   
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Complexation of copper added to seawater was determined by bacterial bioassay and fixedpotential amperometry. Consistent results were obtained by these two fundamentally different methods. The results of this study support the validity of both techniques and the field applicability of fixed-potential amperometry.The intercomparison studies were performed on samples collected at the N.Y.C. sewage sludge dumpsite and in relatively unpolluted coastal waters. In this limited study, the calculated free cupric ion concentrations at ambient total copper concentrations were similar at both sites.  相似文献   
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In this paper we examine OTL displacements detected by GPS stations of a dedicated campaign and validate ocean tide models. Our area of study is the continental shelf of Brittany and Cotentin in France. Brittany is one of the few places in the world where tides provoke loading displacements of ∼10–12 cm vertically and a few cm horizontally. Ocean tide models suffer from important discrepancies in this region. Seven global and regional ocean tide models were tested: FES2004 corrected for K2, TPXO.7.0, TPXO.6.2, GOT00.2, CSR4.0, NAO.99b and the most recent regional grids of the North East Atlantic (NEA2004). These gridded amplitudes and phases of ocean tides were convolved in order to get the predicted OTL displacements using two different algorithms. Data over a period of 3.5 months of 8 GPS campaign stations located on the north coast of Brittany are used, in order to evaluate the geographical distribution of the OTL effect. We have modified and implemented new algorithms in our GPS software, GINS 7.1. GPS OTL constituents are estimated based on 1-day batch solutions. We compare the observed GPS OTL constituents of M2, S2, N2 and K1 waves with the selected ocean tide models on global and regional grids. Large phase-lag and amplitude discrepancies over 20° and 1.5 cm in the vertical direction in the semi-diurnal band of M2 between predictions and GPS/models are detected in the Bay of Mont St-Michel. From a least squares spectral analysis of the GPS time-series, significant harmonic peaks in the integer multiples of the orbital periods of the GPS satellites are observed, indicating the existence of multipath effects in the GPS OTL constituents. The GPS OTL observations agree best with FES2004, NEA2004, GOT00.2 and CSR4.0 tide models.  相似文献   
5.
Rivers, chemical weathering and Earth's climate   总被引:4,自引:0,他引:4  
We detail the results of recent studies describing and quantifying the large-scale chemical weathering of the main types of continental silicate rocks: granites and basalts. These studies aim at establishing chemical weathering laws for these two lithologies, describing the dependence of chemical weathering on environmental parameters, such as climate and mechanical erosion. As shown within this contribution, such mathematical laws are of primary importance for numerical models calculating the evolution of the partial pressure of atmospheric CO2 and the Earth climate at geological timescales. The major results can be summarized as follow: (1) weathering of continental basaltic lithologies accounts for about 30% of the total consumption of atmospheric CO2 through weathering of continental silicate rocks. This is related to their high weatherability (about eight times greater than the granite weatherability); (2) a simple weathering law has been established for basaltic lithologies, giving the consumption of atmospheric CO2 as a function of regional continental runoff, and mean annual regional temperature; (3) no such simple weathering law can be proposed for granitic lithologies, since the effect of temperature can only be identified for regions displaying high continental runoff; (4) a general law relating mechanical erosion and chemical weathering has been validated on small and large catchments. The consequences of these major advances on the climatic evolution of the Earth are discussed. Particularly, the impacts of the onset of the Deccan trapps and the Himalayan orogeny on the global carbon cycle are reinvestigated. To cite this article: B. Dupré et al., C. R. Geoscience 335 (2003).  相似文献   
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The dry‐stone retaining walls (DSRW) have been tipped as a promising solution for sustainable development. However, before recently, their behavior is relatively obscure. In this study, discrete element method (DEM) approach was applied to simulate the plane strain failure of these walls. A commercial DEM package (PFC2D™) was used throughout this study. The authors used a fully discrete approach; thus, both the wall and the backfill were modeled as discrete elements. The methodology for obtaining the micromechanical parameters was discussed in detail; this includes the three mechanical sub‐systems of DSRWs: wall, backfill and interface. The models were loaded progressively until failure, and then the results were compared with the full‐scale experimental results where the walls were loaded, respectively, with hydrostatic load and backfill. Despite its complexity and its intensive calculation time, DEM model can then be used to validate a more simplified approach. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   
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Hydrogeology Journal - Thanks to recent technological advances, hydrogeologists now have access to large amounts of data acquired in real time. Processing these data using traditional modelling...  相似文献   
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