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1.
In snowmelt-driven mountain watersheds, the hydrologic connectivity between meteoric waters and stream flow generation varies strongly with the season, reflecting variable connection to soil and groundwater storage within the watershed. This variable connectivity regulates how streamflow generation mechanisms transform the seasonal and elevational variation in oxygen and hydrogen isotopic composition (δ18O and δD) of meteoric precipitation. Thus, water isotopes in stream flow can signal immediate connectivity or more prolonged mixing, especially in high-relief mountainous catchments. We characterized δ18O and δD values in stream water along an elevational gradient in a mountain headwater catchment in southwestern Montana. Stream water isotopic compositions related most strongly to elevation between February and March, exhibiting higher δ18O and δD values with decreasing elevation. These elevational isotopic lapse rates likely reflect increased connection between stream flow and proximal snow-derived water sources heavily subject to elevational isotopic effects. These patterns disappeared during summer sampling, when consistently lower δ18O and δD values of stream water reflected contributions from snowmelt or colder rainfall, despite much higher δ18O and δD values expected in warmer seasonal rainfall. The consistently low isotopic values and absence of a trend with elevation during summer suggest lower connectivity between summer precipitation and stream flow generation as a consequence of drier soils and greater transpiration. As further evidence of intermittent seasonal connectivity between the stream and adjacent groundwaters, we observed a late-winter flush of nitrate into the stream at higher elevations, consistent with increased connection to accumulating mineralized nitrogen in riparian wetlands. This pattern was distinct from mid-summer patterns of nitrate loading at lower elevations that suggested heightened human recreational activity along the stream corridor. These observations provide insights linking stream flow generation and seasonal water storage in high elevation mountainous watersheds. Greater understanding of the connections between surface water, soil water and groundwater in these environments will help predict how the quality and quantity of mountain runoff will respond to changing climate and allow better informed water management decisions.  相似文献   
2.
Ashok  N. M.  Chandrasekhar  T.  Ragland  Sam  Bhatt  H. C. 《Experimental Astronomy》1994,4(3-4):177-188
A recently developed near infrared high speed photometer intended for lunar oc-cultation studies is described. The primary scientific objective is to reach milli arc second levels of angular resolution so that circumstellar structure of the occulted sources can be resolved. Near infrared sky brightness close to the lunar limb is also studied. Angular diameter derived from the observed occultation of IRC +20169 is presented and system performance discussed.  相似文献   
3.
A hidden Markov model (HMM) technique for the estimation of the shape of a towed array is presented. It is assumed that there is a far-field source radiating sound containing possibly weak spectral lines. The technique uses either the Fourier coefficients at a given frequency computed from a single time block or the maximal eigenvector of a sample spectral covariance matrix. The technique is illustrated using several simulations. The results of these simulations indicate that the HMM technique yields shape and bearing estimates more accurate than those provided by a maximum-likelihood array shape estimation technique  相似文献   
4.
The Dead Sea Basin is the lowest point on earth and is tectonically subsiding. During the Holocene Period the climate became much drier with increasing evaporation whereby initially lacustrine sediments were deposited from the non-marine brines, giving a multi-layered stratigraphy of lime carbonate and halite sediments. The lime carbonate sediments are comprised of laminated, clay to silt sized, clastic sediments (calcite) and authigenic aragonite and gypsum. The halite commonly appears as rock salt. Chemical industries, based on harvesting the salts from the Dead Sea, have developed on both the Israeli and the Jordanian sides of the basin. The lime carbonate soils are used for dike construction, and these soils, together with significant salt layers, are encountered in the foundations of structures, dikes, and tailings dams, requiring definition of their geotechnical properties. Use of standard soil mechanics definitions and testing approaches for the lime carbonates have been found inapplicable, particularly in view of their exceptionally high saline content, and it has been necessary to develop new concepts. The rock salt is encountered at shallow depths, with unit weights considerably lower than those usually discussed in the literature, and with correspondingly different mechanical properties. The geotechnical properties of these soils, and approaches used to define them, are discussed in the paper.  相似文献   
5.
A theoretical evaluation of basic thermodynamic relationships reveals that variation of activity coefficients, ion pairing and electrical interactions must be considered when modelling ionic diffusion in seawater. The contributions of ion-pair formation and change in activity coefficient along the diffusion path were studied experimentally by conducting diffusion experiments in which solutions of KCl, NaCl, MgCl2, Li2SO4, K2SO4, Na2SO4 and MgSO4, at an ionic strength of 0.7, were allowed to diffuse into distilled water. The study reveals that the thermodynamic factor, required to correct for changes in the activity coefficient along the diffusion path, is significant for all the salts studied. Agreement between a simple diffusion model, which does not include ion pairing, and observed data was good for completely dissociated salts, but poor for salts which are known to form ion pairs at the concentration levels studied. The diffusion of MgSO4, 0.425 of which is associated at I = 0.7, was successfully modelled by assuming that the diffusion coefficient of the MgSO40 ion pair is different from the diffusion coefficient of the dissociated salt. The diffusion coefficient of this ion pair is estimated to be 1.9 × 10−5 cm2 s−1 at 30°C, as compared to 0.49 × 10−5 cm2 s−1 for the dissociated salt. It is suggested that the high mobility of this ion pair could cause magnesium enrichment in pore water of sulfate depleted sediments.  相似文献   
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Ports and shipping operations are under increased environmental scrutiny in Australia, particularly as so many of Australia's ports and shipping routes are located in or near major environmentally sensitive areas. The environmental risks involved have been highlighted by the publicity given to shipping accidents. Environmental regulations over aspects of port operations, including ballast water management, dredge spoil and waste reception, are also becoming stricter. While port authorities have adopted stringent environmental guidelines, they remain concerned that the full impact of proposed new environmental regulations on maritime industry may not be fully understood. This paper discusses some of the issues involved with achieving a balance between environmental protection and the need to recognise the importance of seaborne trade to Australia and to maintain Australia's competitiveness in international trade.  相似文献   
10.
Palladium and platinum concentrations were determined for twenty two species of seaweed from the California coast, U.S.A.. A new sensitive analytical technique using atomic absorption spectrometry was developed for palladium in seaweed. For the first time, palladium contents in seaweed were obtained. The contents of palladium and platinum varied from 0.09 to 0.61 ng g–1 and 0.25 to 1.75 ng g–1 in dried material, respectively.The average ratio of Pt/Pd found in seaweed was 3.5, while the ratio of Pt/Pd was 4.5 in seawater. Therefore, it is postulated that there is no discrimination for seaweed to accumulate palladium and platinum from the ambient seawater due to the chemical similarity of the metals.  相似文献   
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