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Theoretical and Applied Climatology - The coastal waters of the southeastern USA contain important protected habitats and natural resources that are vulnerable to climate variability and singular...  相似文献   
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The structural, electronic properties and stability of thorium orthosilicate ThSiO4 polymorphs: thorite and huttonite are investigated by means of the full-potential linearized augmented-plane-wave method with the generalized gradient approximation for the exchange-correlation potential (FLAPW-GGA). The forbidden gaps of thorite and huttonite are estimated at about 7.8 and 7.6 eV, respectively. It is found that Th5f states in ThSiO4 partially overlap with occupied O2p bands. The data obtained showed that thorite is more stable than huttonite; in turn both ThSiO4 polymorphs are unstable with respect to their constituent binary oxides (thorianite ThO2 and α-quartz SiO2) in agreement with the experiments. The theoretical shapes of X-ray emission (XES) (Si,O)Kα,β spectra for thorite, huttonite as well as for SiO2 and ThO2 are calculated and discussed. We show that the XES spectroscopy near the (Si,O)K edge may be very useful technique not only for detailed investigation of the bulk-electronic structure of Th silicates but also for the phase analysis of complex mineral samples containing these species.  相似文献   
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Study of the composition, structure and morphology of microaggregates less than 1 mm in size in soils of one of the Behr hillocks revealed a high share of the clay-salt segregations (microaggregates and cutans). It was established that the segregation type depends on the mud content in soil, while the packing of particles, as well as the size and morphology of microaggregates, depend on the content and properties of salts. The clay component in the microaggregates is mainly represented by smectite. Carbonate (calcitic, dolomitic, and ferruginous) clay-salt microaggregates were found in all horizons of the studied soils, except for horizon Ap on the subhillock plain in the former rice paddy. Gypsum clay-salt microaggregates were identified in the salic horizon Bs of soils. The microaggregates in solonchaks were formed with the contribution of Na-Mg-Ca chlorides and sulfates. The formation of clay-salt aggregates promoted high microstructuring of soils and stability of the Behr hillocks under arid climatic conditions.  相似文献   
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Hourly wind data from a network of climate stations in the north-central United States (drawn from the states of Illinois, lowa, Kansas, Minnesota, Missouri, Nebraska, North Dakota, South Dakota, and Wisconsin) are analyzed to evaluate the efficacy of spatial analyses of near-surface wind speed and power. Spatial autocorrelation functions (acfs) were calculated at a number of timescales: annual, monthly, daily, and hourly. Annual wind speeds have virtually no coherent distance-decay relationship; monthly data produce a more consistent relationship, but still exhibit a large amount of scatter. Both daily and hourly data have classical decay with increasing distance between stations and there appears to be an optimal level of temporal aggregation, near the daily timescale, for spatial analysis of wind. In general, however, spatial acfs overestimate the spatial coherence of both wind speed and power. Temporal nonstationarities in wind data (i.e., diurnal and annual cycles) bias spatial autocorrelation functions and need to be removed before using spatial acfs to estimate characteristics of wind fields. Because mean absolute differences (MAD) of interstation wind speed and power are less affected by temporal nonstationarities, they produce more-robust representations of the spatial variability of wind speed and power. As a result, spatial MADs are recommended over spatial acfs for analyzing spatial coherence and decay of any spatial variable that contains nonstationarities. Methods for improving the spatial analysis of wind are discussed. [Key words: wind energy, spatial autocorrelation, spatial analysis, nonstationarity, north-central United States.]  相似文献   
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