Inter‐laboratory Characterisation of Apatite Reference Materials for Chlorine Isotope Analysis     

Alicja Wudarska  Ewa S&#x;aby  Michael Wiedenbeck  Jaime D. Barnes  Magali Bonifacie  Neil C. Sturchio  Grard Bardoux  Frdric Couffignal  Johannes Glodny  Linnea Heraty  Timm John  Christof Kusebauch  Sathish Mayanna  Franziska D. H. Wilke  Ewa Deput 《Geostandards and Geoanalytical Research》2021,45(1):121-142

Here we report on a set of six apatite reference materials (chlorapatites MGMH#133648, TUBAF#38 and fluorapatites MGMH#128441A, TUBAF#37, 40, 50) which we have characterised for their chlorine isotope ratios; these RMs span a range of Cl mass fractions within the apatite Ca₁₀(PO₄)₆(F,Cl,OH)₂ solid solution series. Numerous apatite specimens, obtained from mineralogical collections, were initially screened for ³⁷Cl/³⁵Cl homogeneity using SIMS followed by δ³⁷Cl characterisation by gas source mass spectrometry using both dual‐inlet and continuous‐flow modes. We also report major and key trace element compositions as determined by EPMA. The repeatability of our SIMS results was better than ± 0.10‰ (1s) for the five samples with > 0.5 % m/m Cl and ± 0.19‰ (1s) for the low Cl abundance material (0.27% m/m). We also observed a small, but significant crystal orientation effect of 0.38‰ between the mean ³⁷Cl/³⁵Cl ratios measured on three oriented apatite fragments. Furthermore, the results of GS‐IRMS analyses show small but systematic offset of δ³⁷Cl_SMOC values between the three laboratories. Nonetheless, all studied samples have comparable chlorine isotope compositions, with mean 10³δ³⁷Cl_SMOC values between +0.09 and +0.42 and in all cases with 1s ≤ ± 0.25.  相似文献   

Temporal and geochemical evolution of the Cenozoic intraplate volcanism of Zealandia     

Christian Timm  Kaj Hoernle  Reinhard Werner  Folkmar Hauff  Paul van den Bogaard  James White  Nick Mortimer  Dieter Garbe-Schönberg 《Earth》2010,98(1-2):38-64

In order to constrain better the distribution, age, geochemistry and origin of widespread Cenozoic intraplate volcanism on Zealandia, the New Zealand micro-continent, we report new ⁴⁰Ar/³⁹Ar and geochemical (major and trace element and Sr–Nd–Hf–Pb isotope) data from offshore (Chatham Rise, Campbell and Challenger Plateaus) and onland (North, South, Auckland, Campbell, Chatham and Antipodes Islands of New Zealand) volcanism on Zealandia. The samples include nephelinite, basanite through phonolite, alkali basalt through trachyte/rhyolite, and minor tholeiite and basaltic andesite, all of which have ocean island basalt (OIB)-type trace element signatures and which range in age from 64.8 to 0.17 Ma. Isotope ratios show a wide range in composition (⁸⁷Sr/⁸⁶Sr = 0.7027–0.7050, ¹⁴³Nd/¹⁴⁴Nd = 0.5128–0.5131, ¹⁷⁷Hf/¹⁷⁶Hf = 0.2829–0.2831, ²⁰⁶Pb/²⁰⁴Pb = 18.62–20.67, ²⁰⁷Pb/²⁰⁴Pb = 15.54–15.72 and ²⁰⁸Pb/²⁰⁴Pb = 38.27–40.34) with samples plotting between mid-ocean-ridge basalts (MORB) and Cretaceous New Zealand intraplate volcanic rocks.Major characteristics of Zealandia's Cenozoic volcanism include longevity, irregular distribution and lack of age progressions in the direction of plate motion, or indeed any systematic temporal or spatial geochemical variations. We believe that these characteristics can be best explained in the context of lithospheric detachment, which causes upwelling and melting of the upper asthenospheric mantle and portions of the removed lithosphere. We propose that a large-scale seismic low-velocity anomaly, that stretches from beneath West Antarctica to Zealandia at a depth of > 600 km may represent a geochemical reservoir that has been in existence since the Cretaceous, and has been supplying the upper mantle beneath Zealandia with HIMU-type plume material throughout the Cenozoic. In addition, the sources of the Cenozoic intraplate volcanism may be at least partially derived through melting of locally detached Zealandia lower lithosphere.  相似文献   

Role of aeolian sediment accretion in the formation of heuweltjie earth mounds,western South Africa          下载免费PDF全文

Joseph R. McAuliffe  M. Timm Hoffman  Leslie D. McFadden  Matthew P. King 《地球表面变化过程与地形》2014,39(14):1900-1912

The action of organisms in shaping landforms is increasingly recognized; the field of biogeomorphology and the conceptual framework of ecosystem engineering have arisen in response to the need for integrated studies of the interactions between biotic and abiotic components of landscapes. Pathways by which organisms influence landscape development may be complex. For example, primary change initiated by one biotic element may initiate a cascade of other changes that eventually produce a significant landscape modification. Mound‐like landforms in North America and southern Africa are widely cited examples of biogenic structures, yet there is considerable controversy regarding the processes responsible for their formation. Heuweltjies (Afrikaans for little hills) are circular mounds ranging from 10–30 m diameter and 0.5–2 m height and are widespread in western South Africa. Colonies of the termite (Microhodotermes viator) are typically associated with heuweltjies and some investigators have attributed heuweltjie formation to the direct action of termites in redistributing earthen materials. However, rather than being directly responsible in this way, termites simply create nutrient‐rich islands, which support denser vegetation, thereby inducing the localized accretion of aeolian sediments and upward growth of mounds. Contrasting soil features in heuweltjies in one locale indicate these processes have occurred throughout the late Quaternary. Geographic variation in sizes of mounds is explained in part by the local availability of sediments that can be mobilized and redistributed by the wind. Recognition of the operation of aeolian processes in the formation of heuweltjies has important implications for conservation. Any land use that diminishes the sediment‐trapping effect of vegetation on heuweltjies truncates the very process by which new aeolian materials can accrue and may promote irreversible erosion and landscape degradation. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Assimilation and diffusion during xenolith-magma interaction: a case study of the Variscan Karkonosze Granite, Bohemian Massif     

Marta Adamuszek  Timm John  Marcin Dabrowski  Yuri Y. Podladchikov  Ralf Gertisser 《Mineralogy and Petrology》2009,97(3-4):203-222

Magmatic enclaves from the Rudolfov quarry near Liberec (Czech Republic) are interpreted to represent remnants of lamprophyric melt that intruded the Karkonosze granite at a stage at which the granite was not fully solidified. Based on the observation that larger enclaves are generally more circular than the smaller ones, we conclude that bigger blobs of mafic magma became more spherical during flow in the gravity field (sink or float). This flow is also interpreted to be responsible for the incorporation of mineral grains into the enclaves and may have facilitated the assimilation of granitic melt. Linear mixing trends on Harker diagrams for most network-forming and mainly slow-diffusing or fluid-immobile elements indicate such an assimilation process between granite and lamprophyre. In contrast, all fast-diffusing or fluid-mobile elements display scattered element distributions, implying that chemical diffusion also played a role. Pressure and temperature for this late magmatic stage are estimated at around 1 kbar and 500°C. These results suggest that two processes modified the composition of the enclaves in the Karkonosze granite: (1) assimilation (mechanical mixing) of granitic melt during the injection of the lamprophyric melt and the subsequent flow of the forming enclaves in the gravity field (responsible for the linear mixing trends) and (2) diffusion-controlled redistribution of elements between both solidifying rock types at the magmatic stage and/or due to late-stage magmatic fluids (responsible for the scattering and deviation from the linear mixing trends).  相似文献   

The relation between electric and redox potential: evidence from laboratory and field measurements     

F. Timm  P. Mller 《Journal of Geochemical Exploration》2001,72(2)

In field and laboratory experiments the relationship of redox, electric, and total potential was studied. This was carried out by using different arrangements of Pt and Ag/AgCl electrodes. The total potential is obtained by placing a Pt and an Ag/AgCl electrode at considerable distance apart on the rock. The studies indicate that the total potential yields the sum of redox and electric potential. Deviations larger than a couple of mV are caused by extensive fluid–rock interactions. In the laboratory it is seen that the magnitude of the electric potential is generally not larger than the artificially produced difference of the redox potential. The former is most likely attributed to a diffusion or membrane potential. At field scale the electric potential is designated as self potential. Redox potential measurements in the field may supply information from remnants of pore fluid of the rock and thereby may be suitable to support the exploration of concealed metal deposits. Detectable are in particular the fast H⁺ ions which are released by electrochemical reactions and transported by electromigration, both of which are attributed to the presence of the so called geobattery.  相似文献   

Deconstructing the Last Glacial termination: the role of millennial and orbital-scale forcings     

L. Menviel  A. Timmermann  O. Elison Timm  A. Mouchet 《Quaternary Science Reviews》2011,30(9-10):1155-1172

Using an Earth system model of intermediate complexity forced by continuously varying boundary conditions and a hypothetical profile of freshwater forcing, the model simulates Heinrich event 1 (H1), the Bølling warm period, the Older Dryas, the Antarctic Cold Reversal (ACR) and the Younger Dryas in close agreement with paleo-proxy data from different regions worldwide. The ACR can be simulated as the bipolar seesaw response to the AMOC recovery during the termination of H1. However, this study also demonstrates that the amplitude of the ACR can be further amplified by a rapid deglacial retreat of the Antarctic Ice sheets. We suggest that melting from both, the Laurentide and the Antarctic Ice sheets contributed to the sea level rise associated with Meltwater Pulse 1-A (MWP-1A). It is hypothesized that the northern hemispheric source of MWP-1A caused the Older Dryas cooling in the Northern Hemisphere, whereas the Southern Hemispheric source contributed to the ACR. The study also documents that for the majority of paleo-climate proxies considered here, the relative timing can be qualitatively reproduced by the transient modeling experiments. The climate model solution presented here may provide a means to further constrain dating uncertainties of some of paleo-climate proxies during the Last Glacial Termination.  相似文献   

Land degradation and climate change in South Africa   总被引：2，自引：0，他引：2  

Michael E Meadows  Timm M Hoffman† 《The Geographical journal》2003,169(2):168-177

This paper considers the potential impact of future climate change on the nature and extent of land degradation in South Africa. The basis of the assessment is the comprehensive review published by the Department of Environmental Affairs and Tourism (DEA&T) as a contribution to the South African effort in respect of the United Nations Convention to Combat Desertification. The DEA&T report is founded on information collated from 34 workshops, one in each of the agricultural regions of South Africa, involving some 453 participants consisting mainly of agricultural extension officers and soil conservation technicians. This analysis reveals that land degradation is underpinned by poverty and its structural roots in colonial and apartheid political planning. Nevertheless, future climate change represents a key challenge to the developing economies of countries like South Africa. Regionally downscaled models predicting the nature and degree of rainfall changes in the future are used to assess the possible impact of future change on the South African land degradation situation. It is concluded that the most severely degraded areas of the country, including large areas of the former 'homeland' states, are likely to become even more susceptible under predicted climate change scenarios.  相似文献   

A new scenario framework for climate change research: background,process, and future directions     

Kristie L. Ebi  Stephane Hallegatte  Tom Kram  Nigel W. Arnell  Timothy R. Carter  Jae Edmonds  Elmar Kriegler  Ritu Mathur  Brian C. O’Neill  Keywan Riahi  Harald Winkler  Detlef P. Van Vuuren  Timm Zwickel 《Climatic change》2014,122(3):363-372

The scientific community is developing new global, regional, and sectoral scenarios to facilitate interdisciplinary research and assessment to explore the range of possible future climates and related physical changes that could pose risks to human and natural systems; how these changes could interact with social, economic, and environmental development pathways; the degree to which mitigation and adaptation policies can avoid and reduce risks; the costs and benefits of various policy mixes; and the relationship of future climate change adaptation and mitigation policy responses with sustainable development. This paper provides the background to and process of developing the conceptual framework for these scenarios, as described in the three subsequent papers in this Special Issue (Van Vuuren et al., 2013; O’Neill et al., 2013; Kriegler et al., Submitted for publication in this special issue). The paper also discusses research needs to further develop, apply, and revise this framework in an iterative and open-ended process. A key goal of the framework design and its future development is to facilitate the collaboration of climate change researchers from a broad range of perspectives and disciplines to develop policy- and decision-relevant scenarios and explore the challenges and opportunities human and natural systems could face with additional climate change.  相似文献   

Controls on solid-phase inclusion during porphyroblast growth: insights from the Barrovian sequence (Scottish Dalradian)     

Katja?FarberEmail author  Mark?J.?Caddick  Timm?John 《Contributions to Mineralogy and Petrology》2014,168(6):1089

A series of Barrovian sequence samples ranging from garnet to sillimanite zones were investigated to infer their porphyroblast-forming reactions and mineral inclusion histories. Quartz is overgrown and partly consumed during garnet formation and remains as inclusion-rich layers in porphyroblasts of the garnet zone. Staurolite crystals in the staurolite zone display sharp transitions between inclusion-rich and inclusion-free areas, suggesting two stages of growth with a different role of quartz in each. The inclusion-rich domains formed similarly to those in garnet by simple overgrowth and resorption of matrix minerals, with thermodynamic constraints suggesting that this staurolite-forming reaction required the presence of chloritoid that is now absent from the examined samples. The participation of garnet was limited in staurolite formation, with chloritoid breakdown supplying sufficient material to form the large amounts (c. 25 vol%) of staurolite found in the rock. This reaction produces an excess of SiO₂, which leaves the crystal domain as SiO_2aq and thus caused the formation of the inclusion-free areas in the staurolite and precipitation of quartz in the matrix. In the sillimanite zone, staurolite is consumed forming new garnet. The newly formed garnet has less quartz inclusions than its core due to a proportionally greater consumption of quartz by the second garnet-forming reaction than by the initial, garnet-grade reactions. Textural and thermodynamic data both suggest that inclusions in these porphyroblasts represent leftovers of a preferentially overgrown matrix than co-products of the porphyroblast-forming reaction.  相似文献   

Multivariate Empirical Mode Decomposition Derived Multi‐Scale Spatial Relationships between Saturated Hydraulic Conductivity and Basic Soil Properties          下载免费PDF全文

Dongli She  Jiaxing Zheng  Ming'an Shao  Luis Carlos Timm  Yongqiu Xia 《洁净——土壤、空气、水》2015,43(6):910-918

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