Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

A possible method for the determination of the magnitude and inclination of a sunspot magnetic-field     

Jie-hai Jin 《Chinese Astronomy and Astrophysics》1985,9(1):15-19

A method is presented in this paper for the determination of both the H and the γ of a sunspot magnetic field by means of two polarizers with transmission axes inclined at ± 45° to the fast axis of a quarter-wave plate. Previously, this arrangement was used to determine H only.It is shown that the profiles of the Stokes parameters are sensitive to the sunspot atmosphere model used whereas the results given by the present method are not. It is shown, more ever, that the formula for determining H from the wave length shift, Δλ = 4.67 × 10^?5gHλ², cannot be used in many cases.  相似文献   

Wavelet Analysis of Space Solar Telescope Images   总被引：1，自引：0，他引：1  

Xi-An Zhu  Sheng-Zhen Jin  Jing-Yu Wang  Shu-Nian NingNational Astronomical Observatories  Chinese Academy of Science  Beijing  Department of Mechanical  Electric Engineering  China College of Mining  Technology  Beijing 《中国天文和天体物理学报》2003,3(6):587-596

The scientific satellite SST (Space Solar Telescope) is an important research project strongly supported by the Chinese Academy of Sciences. Every day, SST acquires 50 GB of data (after processing) but only 10GB can be transmitted to the ground because of limited time of satellite passage and limited channel volume. Therefore, the data must be compressed before transmission. Wavelets analysis is a new technique developed over the last 10 years, with great potential of application. We start with a brief introduction to the essential principles of wavelet analysis, and then describe the main idea of embedded zerotree wavelet coding, used for compressing the SST images. The results show that this coding is adequate for the job.  相似文献   

行星天文学的重要地位及其热点     

张威  朱进 《天文学进展》2002,20(4):379-383

对1995年至2001年《Natue》和《Science》上发表的天文学论文的统计表明，行星天文学领域的论文数量明显超过天文学的其它分支学科，占天文学总论文数的1/3左右。从这个角度来看，行星天文学是天文学最活跃和重要的分支学科之一。对这些论文具体内容的分析可以给出当前行星天文学领域的若干热点问题。相比之下，我国对这一重要领域的关注和投入还远远不够。  相似文献   

海岩小说的几种叙述模式及弊端     

姚国军  李霞 《广东海洋大学学报》2006,26(5):87-90

海岩的长篇小说《河流如血》再创出版高记录，但作家仍局限于特有的小说叙述模式，这部作品设能做到相应的创新。概言之，模式第一面是“刑侦＋恋爱”；模式第二面是“财子＋佳人”；模式第三面是“道德＋法制”。文学创作需要不断创新，创新的过程也是对创作模式的不断突破过程。作家应该警惕的是，不要让模式成为创作的桎梏。  相似文献   

STUDY ON DEVELOPMENT STRATEGY OF SHIPPING CENTERS AND TRANSPORTATION NETWORKS IN THE YELLOW SEA RIM IN THE YELLOW SEA RIM     

JINFeng-jun 《中国地理科学(英文版)》2003,13(2):97-103

It is very important to establish cooperative mechanism to guarantee all members to develop their e-conomies in the Yellow Sea Rim. In this paper, the development strategies ofshipplng centers and transportation networkare discussed based on economic giobalization tendency. The results argue that a united transportation network should bebuilt in order to promote the economic competition of Northeast Asia in the world. As a key component of the economiccooperation, a hierarchical shipping centers network should be established with Hong Kong, Shanghai, Pusan, Koho,and Tokyo as cores. The authorities of China, Japan, R. O. Korea and D. P. B. Korea should make more efforts tobuild a set of cooperation institutions based on raising the transportation efficiency.  相似文献   

Response of sediment characteristics to trophic state change at submerged macrophyte zones in a large shallow Lake Wuliangsuhai,China     

Liu  Zhenying  Jin  Zhaohui  Li  Yawei  Gu  Jiujun  Li  Tielong  Kang  Haiyan 《中国地球化学学报》2006,25(1):10-11

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A 2D numerical study of explosive events in the solar atmosphere     

S.-P. Jin  B. Inhester  D. Innes 《Solar physics》1996,168(2):279-295

Two-dimensional (2D) compressible magnetohydrodynamic simulations are performed to explore the idea that the asymmetric reconnection between newly emerging intranetwork magnetic field flux and pre-existing network flux causes the explosive events in the solar atmosphere. The dependence of the reconnection rate as a function of time on the density and temperature of the emerging flux are investigated. For a Lundquist number of L _u= 5000 we find that the tearing mode instability can lead to the formation and growth of small magnetic islands. Depending on the temperature and density ratio of the emerging plasma, the magnetic island can be lifted upward and convected out of the top boundary, or is suppressed downward and convected out of the top boundary, or is suppressed downward nad submerged below the bottom boundary. The motions of the magnetic islands with different direction are accompanied respectively with upward or downward high velocity flow which might be associated with the red- and blue-shifted components detected in the explosive events.  相似文献   

Tidal effects on temperature front in the Yellow Sea   总被引：5，自引：0，他引：5  

Ma Jian  Qiao Fangli  Xia Changshui  Yang Yongzeng 《中国海洋湖沼学报》2004,22(3):314-321

Temperature front (TF) is one of the important features in the Yellow Sea, which forms in spring, thrives in summer, and fades in autumn as thermocline declines. TF intensity ⋎S _T ⋎ is defined to describe the distribution of TF. Based on the MASNUM wave-tide-circulation coupled model, temperature distribution in the Yellow Sea was simulated with and without tidal effects. Along 36°N, distribution of TF from the simulated results are compared with the observations, and a quantitative analysis is introduced to evaluate the tidal effects on the forming and maintaining processes of the TF. Tidal mixing and the circulation structure adapting to it are the main causes of the TF. Supported by the National Basic Research Program of China (No. G1999043809) and the National Science Foundation of China (No. 49736190).  相似文献   

PALEOSOLS　OF　SANDY　LANDS　AND　ENVIRONMENTAL　CHANGES　IN　THE　WESTERN　PART　OF　NORTHEAST　PLAIN　OF　CHINA　WESTERN　DURING　HOLOCENE     

裘善文  李取生  夏玉梅  王景璐 《中国地理科学(英文版)》1995,5(2):137-148

ＰＡＬＥＯＳＯＬＳＯＦＳＡＮＤＹＬＡＮＤＳＡＮＤＥＮＶＩＲＯＮＭＥＮＴＡＬＣＨＡＮＧＥＳＩＮＴＨＥＷＥＳＴＥＲＮＰＡＲＴＯＦＮＯＲＴＨＥＡＳＴＰＬＡＩＮＯＦＣＨＩＮＡＷＥＳＴＥＲＮＤＵＲＩＮＧＨＯＬＯＣＥＮＥ￥ＱｉｕＳｈａｎｗｅｎ（裘善文）ＬｉＱｕｓ...  相似文献