Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

A CASE STUDY ON CONCENTRATION AND DECENTRALIZATION：BEHAVIOR AND DYNAMIC MECHANISM OF SPATIAL EVOLUTION IN METROPOLITAN AREA，NANJING，CHINA   总被引：1，自引：1，他引：0  

ZHUXi－gang  ZHANGJing－xiang 《中国地理科学(英文版)》2002,12(3):212-217

In rapid socio-economic development,the process of concentration and dispersal of various elements tends to be more dramatic,tremendously influencing the shaping and transformation of the space in metropolitan area.Survey of spatial concentration and decentralization has thus become a basic method in examining metropolitan spatial evolution.In this research,three elements were selected as the essential indicators of the process:demographic density distribu-tion,employment density distribution and business office location.Performance of these elements in Nanjing City was exam-ined historically.As Nanjing City could be regarded as a representative of metropolitan areas in China,its situation large-ly suggestes the general characteristics in similar areas of China.Hence based on the investigation of Nanjing City,four general implications were highlighted.First ,metropolitan areas in China are in a violent process and shift of spatial concentra-tion and decentralization.Second,from now to at least the near future,concentration will continue to be the central fea-ture.Third,the landscape of metropolitan areas basically exhibits a dual structure character.The gap in environmental and ecological qualities among different districts will continue for a long time.Fourth,Central Business District (CBD) is playing an important role in helping to convert the traditionally single-centered city structure into a polycentric one.  相似文献   

Discovery of 13 New Variable Stars in the Field of the Open Cluster NGC 2168 （M35）     

Juei-Hwa Hu  Wing-Huen Ip 《中国天文和天体物理学报》2005,5(4):356-362

A wide-field time-series CCD photometric survey of variable stars in the field of the open cluster NGC 2168 was carried out using the BATC Schmidt telescope. In total 13 new variable stars are discovered with three W UMa systems, one EA type and two EB type eclipsing binaries (one of them could be a W UMa system), and seven pulsating stars including three candidates of δScuti stars.  相似文献   

关于改进的Encke方法中参考轨道的选择和校正     

刘林  胡松杰 《天文学报》1996,37(3):285-293

对于改进的Ｅｎｃｋｅ方法，选择适当的参考轨道是一个关键．然而，对于人造地球卫星长弧轨道计算，目前所给出的几种参考轨道均需要逐段校正，这将给定轨问题带来附加的复杂性．本文将仔细探讨如何选择参考轨道和减少校正次数．  相似文献   

BRINGING FORWARD OF THE CONCEPT OF COGIS AND ITS ARCHITECUTRE RESEARCH     

HUXue-lian CHENGCheng-qi WUDe-wen MAAi-nai 《中国地理科学(英文版)》2003,13(1):84-90

Based on the analysis of the development of GIS technology and application,this paper brought forward the concept of GoGIS,namely Cooperative GIS ,CoGIS is GIS facing group-users and supporting human-human interaction,which makes it differ from the former GISs,Then,the characteristics of general Computer Spport Cooperative Work (CSCW)applications and the complexity of Geographic Information Science were analyzed,and the conclusion the CoGIS was not a simple GIS layer on CSCW was reached,Further,this paper gaver the hierarchical architecture of CoGIS,and analyzed the coperative platform in detail from the following:1)basic elements;2) collaboration patterns;3) cooperation control mechanism;4) synchronization mechanism;5) security and 6) group communication and so on.With those,the problems about GIS applications are discussed,such as 1)distributed multi-source GIS information and knowledge sharing platform;2)the fusion and visualization of GIS information;3)virtual reality cooperative modeling;4) dymamic simulation;5)expert system and 6) decision-making.Finally,this paper analyzed CoGIS application mode in brief.  相似文献   

Isolation of Protoplasts from Undaria pinnatifida by Alginate Lyase Digestion     

HU Xiaoke  JIANG Xiaolu*  GUAN Huashi Fishery College  Ocean University of China  Qingdao  P..R.China 《中国海洋大学学报(英文版)》2003,2(1)

1　Introduction　Protoplastsserveasabasicandversatiletoolforge neticengineeringandbiochemicalresearchforseveralreasons :theymayregeneratetheirwallsandprovideamodelsystemforstudyingwallbiogenesis ,theirlysisprovidesagentlemeansofpreparingsubcellularor ganelles ,andthemembraneexpositionallowsgeneticmanipulationsinvolvingfusionoruptakeofnucleicacidstobepossible .Theseadvantagesarelessachiev ablewhenusingintactcells (Liciaetal.,1999) .Incomparisonwithlandplantsandunicellularalgae ,on lylimitedrepo…  相似文献   

APPLICATION OF ANALYTIC HIERARCHY PROCESS TO ASSESSING THE ECOLOGICAL VULNERABILITY OF WETLANDS IN THE JIANGHAN PLAIN   总被引：5，自引：1，他引：4  

WANGXue-lei NINGLong-mei HUWang-bin 《中国地理科学(英文版)》2003,13(3):272-276

Wetlands in the Jianghan Plain are important components of wetland types in lake area in the middle and lower reaches the Changjiang (Yangtze) River and they fulfill many uses and functions related to hydrology,waste assimilation, ecosystem productivity and biodiversity. Owing to natural factors and human activities, especially excessive reclamation from lakes, the shrinking process of the lakes has been accelerated. Wetland ecosystem has shown the characteristics of vulnerability. According to the analysis of wetland ecological function in the Jianghan Plain, this paper presented an index system related to productivity, stability and environmental capacity. By using the method of Analytic Hierarchy Process, we computed the values of the relative weights of the indexes, and evaluated the vulnerability level of the wetland ecosystem by the method of multi-indexes. The case study showed that the fragile extent of wetland ecosystem in the Jianghan Plain is 5.6. This means that the wetland ecosystem in the Jiang-han Plain is laid to the state of middle vulnerability. Therefore, the wetland conservation and eco-rehabilitation in the JiangJaan Plain should be paid attention to.  相似文献   

Three Super Active Regions in the Descending Phase of Solar Cycle 23   总被引：2，自引：0，他引：2  

Hong-Qi Zhang  Xing-Ming Bao  Yin Zhang  Ji-Hong Liu  Shu-Dong Bao  Yuan-Yong Deng  Wei Li  Jie Chen  Jin-Ping Dun  Jiang-Tao Su  Juan Guo  Xiao-Fan Wang  Ke-Liang Hu  Gang-Hua Lin  Dong-Guang WangNational Astronomical Observatories  Chinese Academy of Sciences  Beijing   《中国天文和天体物理学报》2003,3(6):491-494

We analyze the magnetic configurations of three super active regions, NOAA 10484, 10486 and 10488, observed by the Huairou Multi-Channel Solar Telescope (MCST) from 2003 October 18 to November 4. Many energetic phenomena, such as flares (including a X-28 flare) and coronal mass ejections (CMEs), occurred during this period. We think that strong shear and fast emergence of magnetic flux are the main causes of these events. The question is also of great interest why these dramatic eruptions occurred so close together in the descending phase of the solar cycle.  相似文献   

QUEST on DASI: a South Pole CMB polarization experiment     

Sarah Church  Peter Ade  James Bock  Melanie Bowden  John Carlstrom  Ken Ganga  Walter Gear  James Hinderks  Wayne Hu  Brian Keating  John Kovac  Andrew Lange  Eric Leitch  Olivier Mallie  Simon Melhuish  Anthony Murphy  Ben Rusholme  Creidhe O&#x;Sullivan  Lucio Piccirillo  Clem Pryke  Andy Taylor  Keith Thompson 《New Astronomy Reviews》2003,47(11-12):1083

QUEST on DASI is a ground-based, high-sensitivity, high-resolution (ℓ_max2500) experiment designed to map CMB polarization at 100 and 150 GHz and to measure the power spectra from E-modes, B-modes from lensing of the CMB, and B-modes from primordial gravitational waves. The experiment comprises a 2.6 m Cassegrain optical system, equipped with an array of 62 polarization-sensitive bolometers (PSBs), located at the South Pole. The instrument is designed to minimize systematic effects; features include differencing of pairs of orthogonal PSBs within a single feed, a rotatable achromatic waveplate, and axisymmetric rotatable optics. In addition the South Pole location allows both repeatable and highly controlled observations. QUEST on DASI will commence operation in early 2005.  相似文献   

卫星星座与编队飞行问题综述   总被引：3，自引：0，他引：3  

胡松杰  王歆  刘林 《天文学进展》2003,21(3):231-240

卫星应用的日益发展需要由多颗卫星组成的卫星系统(形成各种类型的星座)来替代单颗卫星，这就给卫星轨道力学的应用增加了一些新内容。重点阐述了卫星星座整体结构的演化、卫星星座编队飞行中的星-星相对几何构形及其保持问题，以及星座卫星定轨所涉及的测控方式和天地基网联合定轨问题。这些内容都是卫星星座轨道力学中的重要组成部分。  相似文献