Mineralogical and geochemical alteration of Hitura sulphide mine tailings with emphasis on nickel mobility and retention     

Päivi M. Heikkinen  Marja L. Räisänen 《Journal of Geochemical Exploration》2008

Weathering of Hitura (W Finland) nickel sulphide mine tailings and release of heavy metals into pore water was studied with mineralogical (optical and electron microscopy, X-ray diffraction) and geochemical methods (selective extractions). Tailings were composed largely of serpentine, micas and amphiboles with only minor carbonates and sulphides. Sulphides, especially pyrrhotite, have oxidized intensively in the shallow tailings in 10–15 years, but a majority of the tailings have remained unchanged. Oxidation has resulted in depletion of carbonates, slightly decreased pH, and heavy metal (Ni, Zn) release in pore water as well as in the precipitation of secondary Fe precipitates. Nevertheless, in the middle of the tailings area, where the oxidation front moves primarily downward, released heavy metals have been adsorbed and immobilized with these precipitates deeper in the oxidation zone. In contrast to what was seen in pore water pH, but in accordance with static tests of the previous studies, the neutralisation potential ratio (NPR) calculated based on the mineralogical composition and the total sulphur content suggested that tailings are ‘not potentially acid mine drainage (AMD) generating’. However, the calculated buffering capacity of the tailings resulted largely from the abundant serpentine because of the low carbonate content. Despite its slow weathering rate, serpentine may buffer the acidity to some extent through ion exchange processes in fine ground tailings. Nevertheless, in practice, acid production capacity of the tailings depends primarily on the balance between Ca–Mg carbonates and iron sulphides. NPR calculation based on carbonate and sulphur contents suggested, that the Hitura tailings are ‘likely AMD generating’. The study shows that sulphide oxidation can be significant in mobilisation of heavy metals even in apparently non-acid producing, low sulphide tailings. Therefore, prevention of oxygen diffusion into tailings is also essential in this type of sulphide tailings.  相似文献   

Mercury-bearing black shales and human Hg intake in eastern Finland: impact and mechanisms   总被引：1，自引：0，他引：1  

K. Loukola-Ruskeeniemi  M. Kantola  T. Halonen  K. Seppänen  P. Henttonen  E. Kallio  P. Kurki  H. Savolainen 《Environmental Geology》2003,43(3):283-297

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Foreword     

I. Ethem Gönenç 《International Journal of Salt Lake Research》1997,6(2):89-89

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Relationships between texture and mechanical properties of hybrid rocks from the Jaala–Iitti complex, southeastern Finland     

M. Risnen 《Engineering Geology》2004,74(3-4):197-211

The relationships between petrographical and mechanical properties of rock aggregate raw materials from the hybridised, subvolcanic Jaala–Iitti complex, southeastern Finland, were investigated. Petrography was quantified from polished thin sections with a polarising microscope to determine the modal composition and grain size distribution, and resistance to fragmentation and abrasion were determined. Abundance of fine-grained minerals (especially of hornblende), fine grain size-dominated grain size distribution, uniform spatial dispersion of hornblende crystals, and intense micrographic intergrowth texture with interlocking grain boundaries were found to have the greatest positive influence on the mechanical properties. The results showed the potentiality of hybridised rocks as raw materials for high quality aggregates that can resist fragmentation and abrasion.  相似文献   

Spatial Analysis Techniques as Successful Mineral-Potential Mapping Tools for Orogenic Gold Deposits in the Northern Fennoscandian Shield,Finland   总被引：1，自引：0，他引：1  

Vesa Nykänen  V. Juhani Ojala 《Natural Resources Research》2007,16(2):85-92

Geoscientific Information Systems (GIS) provide tools to quantitatively analyze and integrate spatially referenced information from geological, geophysical, and geochemical surveys for decision-making processes. Excellent coverage of well-documented, precise and good quality data enables testing of variable exploration models in an efficient and cost effective way with GIS tools. Digital geoscientific data from the Geological Survey of Finland (GTK) are being used widely as spatial evidence in exploration targeting, that is ranking areas based on their exploration importance. In the last few years, spatial analysis techniques including weights-of-evidence, logistic regression, and fuzzy logic, have been increasingly used in GTK’s mineral exploration and geological mapping projects. Special emphasis has been put into the exploration for gold because of the excellent data coverage within the prospective volcanic belts and because of the increased activity in gold exploration in Finland during recent years. In this paper, we describe some successful case histories of using the weights-of-evidence method for the Au-potential mapping. These projects have shown that, by using spatial modeling techniques, exploration targets can be generated by quantitatively analyzing extensive amounts of data from various sources and to rank these target areas based on their exploration potential.  相似文献   

Mapping the mesospheric CO₂ clouds on Mars: MEx/OMEGA and MEx/HRSC observations and challenges for atmospheric models     

A. Määttänen  F. Montmessin  F. Scholten  F. González-Galindo  A. Spiga  E. Hauber  J.-P. Bibring 《Icarus》2010,209(2):452-469

This study presents the latest results on the mesospheric CO₂ clouds in the martian atmosphere based on observations by OMEGA and HRSC onboard Mars Express. We have mapped the mesospheric CO₂ clouds during nearly three martian years of OMEGA data yielding a cloud dataset of ∼60 occurrences. The global mapping shows that the equatorial clouds are mainly observed in a distinct longitudinal corridor, at seasons L_s = 0-60° and again at and after L_s = 90°. A recent observation shows that the equatorial CO₂ cloud season may start as early as at L_s = 330°. Three cases of mesospheric midlatitude autumn clouds have been observed. Two cloud shadow observations enabled the mapping of the cloud optical depth (τ = 0.01-0.6 with median values of 0.13-0.2 at λ = 1 μm) and the effective radii (mainly 1-3 μm with median values of 2.0-2.3 μm) of the cloud crystals. The HRSC dataset of 28 high-altitude cloud observations shows that the observed clouds reside mainly in the altitude range ∼60-85 km and their east-west speeds range from 15 to 107 m/s. Two clouds at southern midlatitudes were observed at an altitude range of 53-62 km. The speed of one of these southern midlatitude clouds was measured, and it exhibited west-east oriented speeds between 5 and 42 m/s. The seasonal and geographical distribution as well as the observed altitudes are mostly in line with previous work. The LMD Mars Global Climate Model shows that at the cloud altitude range (65-85 km) the temperatures exhibit significant daily variability (caused by the thermal tides) with the coldest temperatures towards the end of the afternoon. The GCM predicts the coldest temperatures of this altitude range and the season L_s = 0-30° in the longitudinal corridor where most of the cloud observations have been made. However, the model does not predict supersaturation, but the GCM-predicted winds are in fair agreement with the HRSC-measured cloud speeds. The clouds exhibit variable morphologies, but mainly cirrus-type, filamented clouds are observed (nearly all HRSC observations and most of OMEGA observations). In ∼15% of OMEGA observations, clumpy, round cloud structures are observed, but very few clouds in the HRSC dataset show similar morphology. These observations of clumpy, cumuliform-type clouds raise questions on the possibility of mesospheric convection on Mars, and we discuss this hypothesis based on Convective Available Potential Energy calculations.  相似文献   

Final analysis of ELAIS 15-μm observations: method, reduction and catalogue     

M. Vaccari  C. Lari  L. Angeretti  D. Fadda  C. Gruppioni  F. Pozzi  O. Prouton  H. Aussel  T. Babbedge  P. Ciliegi  A. Franceschini  E. Gonzalez-Solares  F. La Franca  S. Oliver  I. Perez-Fournon  M. Rowan-Robinson  S. Serjeant  P. Väisänen 《Monthly notices of the Royal Astronomical Society》2005,358(2):397-418

We present the final analysis of the European Large Area Infrared Space Observatory ( ISO ) Survey (ELAIS) 15-μm observations, carried out with the ISO Camera (ISOCAM) instrument on board the ISO .
The data-reduction method, known as the Lari Method, is based on a mathematical model of the behaviour of the detector and was specifically designed for the detection of faint sources in ISOCAM/ISO Photopolarimeter (ISOPHOT) data. The method is fully interactive and leads to very reliable and complete source lists.
The resulting catalogue includes 1923 sources detected with signal-to-noise ratio of  > 5  in the 0.5–100 mJy flux range and over an area of 10.85 deg² split into four fields, making it the largest non-serendipitous extragalactic source catalogue obtained to date from the ISO data.
This paper presents the concepts underlying the data-reduction method together with its latest enhancements. The data-reduction process, the production and basic properties of the resulting catalogue are discussed. The catalogue quality is assessed by means of detailed simulations, optical identifications and comparison with previous analyses.  相似文献   

Projections of daily mean temperature variability in the future: cross-validation tests with ENSEMBLES regional climate simulations   总被引：1，自引：0，他引：1  

Jouni Räisänen  Olle Räty 《Climate Dynamics》2013,41(5-6):1553-1568

Because of model biases, projections of future climate need to combine model simulations of recent and future climate with information on observed climate. Here, 10 methods for projecting the distribution of daily mean temperatures are compared, using six regional climate change simulations for Europe. Cross validation between the models is used to assess the potential performance of the methods in projecting future climate. Delta change and bias correction type methods show similar cross-validation performance, with methods based on the quantile mapping approach doing best in both groups due to their apparent ability to reduce the errors in the projected time mean temperature change. However, as no single method performs best under all circumstances, the optimal approach might be to use several well-behaving methods in parallel. When applying the various methods to real-world temperature projection for the late 21st century, the largest intermethod differences are found in the tails of the temperature distribution. Although the intermethod variation of the projections is generally smaller than their intermodel variation, it is not negligible. Therefore, it should be preferably included in uncertainty analysis of temperature projections, particularly in applications where the extremes of the distribution are important.  相似文献   

Use of biliary PAH metabolites as a biomarker of pollution in fish from the Baltic Sea   总被引：2，自引：0，他引：2  

Vuorinen PJ  Keinänen M  Vuontisjärvi H  Barsiene J  Broeg K  Förlin L  Gercken J  Kopecka J  Köhler A  Parkkonen J  Pempkowiak J  Schiedek D 《Marine pollution bulletin》2006,53(8-9):479-487

During field campaigns of the BEEP project (Biological Effects of Environmental Pollution in Marine Coastal Ecosystems) in 2001-2002, metabolites of polycyclic aromatic hydrocarbons (PAHs) were determined in bile samples from three fish species, flounder (Platichthys flesus), perch (Perca fluviatilis) and eelpout (Zoarces viviparus), from four separate areas in the Baltic Sea. Two determination methods were applied: fixed wavelength fluorescence (FF) for pyrene-type metabolites and high-performance liquid chromatography with fluorescence detection (HPLC). There was a good correlation between the FF method and 1-OH pyrene determined by HPLC. Normalisation of the FF data for absorbance at 380 nm or bile protein concentrations greatly increased variance in one third and decreased it in two thirds of the cases and resulted in a loss of significant differences (protein normalisation) between the sampling stations, but normalisation of the HPLC data had little effect on the results. The biliary PAH metabolite content was usually higher in males than in females. In perch and eelpout the biliary PAH contents were at similar levels, whereas in flounder the levels were lower. The sampling areas arranged in decreasing order of biliary PAH contents were: Wismar Bay > Gulf of Gdansk > Lithuanian coast > Kvadofj?rden (reference area). It is concluded that FF with un-normalised data is a reliable and simple method for monitoring purposes and only one sex of a selected species should be used.  相似文献   

Preservation of Palaeoproterozoic early Svecofennian structures in the Orijärvi area, SW Finland—Evidence for polyphase strain partitioning   总被引：1，自引：1，他引：0  

Pietari Skytt  Markku Visnen  Irmeli Mnttri 《Precambrian Research》2006,150(3-4):153-172

The predominantly migmatitic Palaeoproterozoic Uusimaa belt preserves early lower-grade Svecofennian structures in the Orijärvi area in SW Finland. This study aims at explaining the deformational history responsible for its preservation and also at defining the age of the early Svecofennian deformation. Detailed structural analysis reveals that the preservation was enabled by polyphase strain partitioning, which initiated during the early Svecofennian D₂ deformation, 1875 Ma ago, as revealed by ion microprobe U–Pb data on zircons from granodioritic and intermediate syn-D₂ intrusive dykes. The D₂ structures were low-strain upright folds at high crustal levels and sub-horizontal high-strain folds at deeper crustal levels. The sub-horizontal D₂ structures were refolded into upright folds during the subsequent late Svecofennian D₃ deformation, whereas the upright D₂ structures behaved as almost rigid blocks that caused strain partitioning into high-strain zones along the block margins. This accounts for the low cumulative strain in specific parts of the Orijärvi area. Further strain partitioning during D₄ caused reverse dip-slip movements along regional-scale shear zones. Crustal depth controlled the metamorphic grade during D₂, when local migmatisation took place at deep crustal levels. Later metamorphic overprint during D₃ deformation is evident from post-D₂ growth of sillimanite and a second generation of andalusite.Similarities in the structural patterns between the Orijärvi area and the Tampere-Vammala area (100 km to the north) suggest that irrespective of the age of the later overprint, subsequent deformation was localised along the margins of the early formed upright domains, while the low-grade rocks within the domains were preserved.  相似文献