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Atomistic simulations have been carried out to investigate the mechanisms of noble gas incorporation in minerals using both the traditional two-region approach and the “supercell” method. The traditional two-region approach has been used to calculate defect energies for Ne, Ar, Kr and Xe incorporation in MgO, CaO, diopside and forsterite in the static limit and at one atmosphere pressure. The possibilities of noble gas incorporation via both substitution and interstitial mechanisms are studied. The favored mechanism varies from mineral to mineral and from noble gas to noble gas. In all minerals studied, the variation of the solution energies of noble gas substitution with atomic radius appears approximately parabolic, analogous to those for 1+, 2+, 3+ and 4+ trace element incorporation on crystal lattice sites. Noble gas solution energies thus also fall on a curve, similar to those previously observed for cations with different charges, but with much lower curvature.The “supercell” method has been used to investigate the pressure dependence of noble gas incorporation in the same systems. Results indicate a large variation of the solubility of the larger noble gases, Kr and Xe with pressure. In addition, explicit simulation of incorporation at the (0 0 1) surface of MgO shows that the solubility of the heavier noble gases may be considerably enhanced by the presence of interfaces.  相似文献   
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Concentrations of atmospheric Hg species, elemental Hg (Hg°), reactive gaseous Hg (RGM), and fine particulate Hg (Hg-PM2.5) were measured at a coastal site near Weeks Bay, Alabama from April to August, 2005 and January to May, 2006. Mean concentrations of the species were 1.6 ± 0.3 ng m−3, 4.0 ± 7.5 pg m−3 and 2.7 ± 3.4 pg m−3, respectively. A strong diel pattern was observed for RGM (midday maximum concentrations were up to 92.7 pg m−3), but not for Hg° or Hg-PM2.5. Elevated RGM concentrations (>25 pg m−3) in April and May of 2005 correlated with elevated average daytime O3 concentrations (>55 ppbv) and high light intensity (>500 W m−2). These conditions generally corresponded with mixed continental-Gulf and exclusively continental air mass trajectories. Generally lower, but still elevated, RGM peaks observed in August, 2005 and January–March, 2006 correlated significantly (p < 0.05) with peaks in SO2 concentration and corresponded to periods of high light intensity and lower average daytime O3 concentrations. During these times air masses were dominated by trajectories that originated over the continent. Elevated RGM concentrations likely resulted from photochemical oxidation of Hg° by atmospheric oxidants. This process may have been enhanced in and by the near-shore environment relative to inland sites. The marine boundary layer itself was not found to be a significant source of RGM.  相似文献   
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Instrument calibration of ocean bottom seismographs   总被引:1,自引:0,他引:1  
To increase the accuracy of measuring sea floor motion with ocean bottom seismometers, we calibrate the seismometer system on the ocean floor. Data from the sea floor calibration, augmented with electronic and land calibration data, enables us to find the OBS transfer function to an accuracy of 0.5% in the frequency range of 0.1 to 32 Hz. We are able to distinguish between temperature, instrument and OBS ground coupling effects, all of which alter the transfer function. This paper reviews our method of calibration and discusses the effects of temperature and some of the instrument design features on the vertical seismometer transfer function.  相似文献   
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The atmospheric forcing of the Bering Sea over its eastern shelf is estimated using the 40-year record of daily data from the NCEP/NCAR Reanalysis. This data set includes estimates of the processes responsible for the atmospheric forcing, namely the surface fluxes of momentum, sensible and latent heat, and longwave and shortwave radiation, and therefore permits quantifying effects that previously could be inferred only from the large-scale nature of the flow. The forcing in 1995–1999 is described in detail using daily time series; historical context for these results is provided with seasonal averages for the years 1959–1999.The analysis for winter concentrates on aspects related to the formation and advection of sea ice. Results indicate that the presence of sea ice is strongly related to the net surface-heat fluxes as well as the cross-shelf component of the wind. The 40-year record lacks any discernible long-term trend in the winter forcing and response. There was a notably cold period in the early to middle 1970s, and a warm period from the late 1970s into the early 1980s, but conditions during the 1990s are similar to those in the late 1950s and 1960s.The analysis for the warm season focuses on the mechanisms responsible for the variability in SST warming. Much of the intraseasonal and interannual variability in this warming can be attributed to variations in the downward shortwave radiation (solar heating). The 40-year record does indicate a long-term trend toward increased solar heating, and reduced surface latent-heat fluxes (evaporative cooling). These changes have led to August SSTs in the 1990s that are roughly 1°C warmer than in the 1960s.  相似文献   
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