Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

敦煌-格尔木铁路沿线风动力环境特征     

鱼燕萍  张克存  安志山  张余 《中国沙漠》2020,40(1):41-48

敦煌-格尔木铁路沿线地形复杂、起沙因素多变、沙源丰富，沙害问题日益严重。目前对其风沙活动规律还未有研究，不利于防沙工作的开展。为此，通过对自北向南的5个观测点（S1、S2、S3、S4、S5）风速和风向的观测、计算和分析，利用平均风速、起沙风况及输沙势对敦格铁路沿线的风动力环境特征进行研究。结果表明：S5、S4和S3的风况对铁路风沙灾害防治意义较大。S5年平均风速、起沙风频率和输沙势最大，春季风沙活动最为强烈，且风向单一、风力强劲，风沙运动方向基本与铁路垂直，沙粒易在铁路附近堆积。S4夏季风沙活动最为强烈；S3春季风沙活动最为强烈，且风向单一，S4和S3的风沙运动方向与铁路夹角小于90°，附近沙源广阔，铁路易受风沙侵蚀，阻碍交通运营。  相似文献   

Wavelet Spectrum Analysis Of Eit/Soho Images     

V. Delouille  J. De Patoul  J. F. Hochedez  L. Jacques  J. P. Antoine 《Solar physics》2005,228(1-2):301-321

The extreme ultraviolet imaging telescope (EIT) of SOHO offers a unique record of the solar atmosphere for its sampling in temperature, field of view, resolution, duration, and cadence. To investigate globally and locally its topology and evolution during the solar cycle, we consider a multi-scale approach, and more precisely we use the wavelet spectrum. We present three results among the applications of such a procedure. First, we estimate the typical dimension of the supergranules as seen in the 30.4 nm passband, and we show that the evolution of the characteristic network scale is almost in phase with the solar cycle. Second, we build pertinent time series that give the evolution of the signal energy present in the corona at different scales. We propose a method that detects eruptions and post-flaring activity in EUV image sequences. Third, we introduce a new way to extract active regions in EIT images, with perspectives in, e.g., long-term irradiance analysis.  相似文献   

Testing the circumstellar disc hypothesis: a search for H₂ outflow signatures from massive young stellar objects with linearly distributed methanol masers     

J. M. De Buizer 《Monthly notices of the Royal Astronomical Society》2003,341(1):277-298

The results of a survey searching for outflows using near-infrared imaging are presented. Targets were chosen from a compiled list of massive young stellar objects associated with methanol masers in linear distributions. Presently, it is a widely held belief that these methanol masers are found in (and delineate) circumstellar accretion discs around massive stars. If this scenario is correct, one way to test the disc hypothesis is to search for outflows perpendicular to the methanol maser distributions. The main objective of the survey was to obtain wide-field near-infrared images of the sites of linearly distributed methanol masers using a narrow-band 2.12-μm filter. This filter is centred on the  H₂ v = 1–0 S(1)  line; a shock diagnostic that has been shown to successfully trace CO outflows from young stellar objects. 28 sources in total were imaged of which 18 sources display H₂ emission. Of these, only two sources showed emission found to be dominantly perpendicular to the methanol maser distribution. Surprisingly, the H₂ emission in these fields is not distributed randomly, but instead the majority of sources are found to have H₂ emission dominantly parallel to their distribution of methanol masers. These results seriously question the hypothesis that methanol masers exist in circumstellar discs. The possibility that linearly distributed methanol masers are instead directly associated with outflows is discussed.  相似文献   

Does sediment grain size affect diatom grazing by harpacticoid copepods?     

De Troch M  Houthoofd L  Chepurnov V  Vanreusel A 《Marine environmental research》2006,61(3):265-277

Estuarine soft sediments support a diverse group of eukaryotic and prokaryotic organisms though the role of the sediment per se for the functioning of these organisms remains largely unknown. The present study aimed to test the effect of sediment grain size on the grazing activities of harpacticoid copepods. In controlled experiments, two common intertidal harpacticoid species (Paramphiascella fulvofasciata and Nitokra spinipes) were each offered a mix of two benthic diatom species (Navicula phyllepta and Seminavis robusta) in different sedimentary conditions. Several microcosms were created using a variety of sediment types, including fine silt (<63 microm), coarser grained sands (125-250, 250-450, 100-300 microm), artificial 'sediments' of glass beads (250-500, 2000 microm) and even the absence of sediment was tested. The diatoms were enriched in the stable carbon (13)C to facilitate tracing in the harpacticoids. Both copepod species were able to graze on the diatoms with highest uptake when sediment was absent. In contrast, both harpacticoid species showed no uptake in silty conditions. In general, grazing was favoured when mean sediment grain size increased. The strong negative effect of fine grains on the grazer's efficiency can be explained by the resulting differences in the structure (and accessibility) of the diatom biofilm on the one hand and the mobility of the grazer on the other hand. In view of the subtle equilibrium between primary producers and grazers, these results might have important implications for the effect of siltation of tidal flats due to, e.g., human activities.  相似文献   

Dissolution and depletion of ferromagnesian minerals from Holocene tephra layers in an acid bog,New Zealand,and implications for tephra correlation     

A. P. W. Hodder  P. J. De Lange  D. J. Lowe 《第四纪科学杂志》1991,6(3):195-208

This study examines the depletion of ferromagnesian silicate minerals from a sequence of thin, distal, mainly rhyolitic tephra layers of Holocene age preserved in an acid peat bog (Kopouatai), North Island, New Zealand. The rate of such depletion has been fast, as indicated by the complete loss of biotite from one tephra layer (Kaharoa Tephra), in which it is normally dominant, in only ca. 770 yr. Chemical dissolution is advocated as the likely cause for the depletion, with amphiboles and other mineral grains commonly showing etch pits, microcaves, and other characteristic surface solution features. Theoretical thermodynamic and kinetic models show a marked increase in the rate of dissolution of all ferromagnesian minerals under conditions of low pH (< 4), but that where silica concentrations in solution are high the relative proportions of minerals remaining are unaffected. However, where concentrations of dissolved silica are low, as in most bog environments, the relative proportions of ferromagnesian minerals are affected as well as absolute amounts being decreased. Amphiboles are depleted relative to pyroxenes, consistent with kinetic studies. The results show that the identification and correlation of tephras on the basis of relative abundances of ferromagnesian minerals alone may be unreliable, and emphasise the need to use multiple criteria in such studies.  相似文献   

Abundances of [WC] central stars and their planetary nebulaee     

O. De Marco  M. J. Barlow 《Astrophysics and Space Science》2001,275(1-2):53-66

We review elemental abundances derived for planetary nebula (PN) WCcentral stars and for their nebulae. Uncertainties in the abundances of[WC] stars are still too large to enable an abundance sequenceto be constructed. In particular it is not clear why the hotter [WCE]stars have C and O abundances which are systematically lower than those oftheir supposed precursors, the [WCL] stars. This abundance differencecould be real or it may be due to unaccounted-for systematic effects inthe analyses. Hydrogen might not be present in [WC] star winds asoriginallysuggested, since broad pedestals observed at the base of nebular lines canplausibly be attributed to high velocity nebular components. It isrecommended that stellar abundance analyses should be carried out withnon-LTE model codes, although recombination line analyses can provideuseful insights. In particular, C II dielectronic recombinationlines provide a unique means to determine electron temperatures in cool[WC] star winds. We then compare the abundances found for PNe which have [WC] central starswith those that do not. Numerous abundance analyses of PNe have beenpublished, but comparisons based on non-uniform samples and methods arelikely to lack reliability. Nebular C/H ratios, which might be expected todistinguish between PNe around H-poor and H-rich stars, are rather similarfor the two groups, with only a small tendency towards larger values fornebulae around H-deficient stars. Nebular abundances should be obtainedwith photoionization models using the best-fitting non-LTE modelatmosphere for the central star as the input. Heavy-metal line blanketingstill needs to be taken into consideration when modeling the central star,as its omission can significantly affect the ionizing fluxes as well asthe abundance determinations. We discuss the discrepancies between nebularabundances derived from collisionally excited lines and thosederived from optical recombination lines, a phenomenon that may havelinks with the presence of H-deficient central stars.  相似文献   

The nature of parallax microlensing events towards the Galactic bulge     

Martin C. Smith  Vasily Belokurov  N. Wyn Evans  Shude Mao  Jin H. An 《Monthly notices of the Royal Astronomical Society》2005,361(1):128-140

  相似文献   

Book reviews     

J. Schrijver  P. C. H. Martens 《Solar physics》1985,98(1):195-196

  相似文献   

WIMPs and solar evolution code     

Yannick Giraud-Héraud  Jean Kaplan  François De Volnay Martin  Charling Tao  Sylvaine Turck-Chièze 《Solar physics》1990,128(1):21-33

The Saclay solar evolution code is used to check the effect of WIMPs on solar evolution. In this paper we study the effects of various types of Cosmion-matter interactions, give constraints on the crosssections compatible with the measured neutrino rate of 2 SNU on chlorine, and relate these constraints to ongoing dark matter detection experiments.Unité associée au CNRS UA 280, F-75251 Paris Cedex 05, France.On leave from LPC, Collège de France.  相似文献