Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

Book reviews     

Howard  R. F.  van den Oord  G. H. J.  Švestka  Z. 《Solar physics》1996,169(1):225-227

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The Faint Sky Variability Survey – I. Goals and data reduction process     

P. J. Groot  P. M. Vreeswijk  M. E. Huber  M. E. Everett  S. B. Howell  G. Nelemans  J. van Paradijs  E. P. J. van den Heuvel  T. Augusteijn  E. Kuulkers  R. G. M. Rutten  J. Storm 《Monthly notices of the Royal Astronomical Society》2003,339(2):427-434

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Erratum: Towards cosmological concordance on galactic scales     

Frank C. van den Bosch  H. J. Mo  Xiaohu Yang 《Monthly notices of the Royal Astronomical Society》2004,348(2):736-736

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Obscured AGB Stars in the LMC     

Jacco Th. Van Loon  Albert A. Zijlstra  Patricia A. Whitelock  M.A.T. Groenewegen  Cecile Loup  Peter Te Lintel Hekkert  Norman R. Trams  L.B.F.M. Waters 《Astrophysics and Space Science》1997,255(1-2):403-404

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Modeling X-Ray Photoionized Plasmas Produced at the Sandia Z-Facility     

P. A. M. Van Hoof  M. E. Foord  R. F. Heeter  J. E. Bailey  H.-K. Chung  M. E. Cuneo  W. H. Goldstein  V. Jonauskas  F. P. Keenan  R. Kisielius  D. A. Liedahl  C. Ramsbottom  S. J. Rose  P. T. Springer  R. S. Thoe 《Astrophysics and Space Science》2005,298(1-2):147-153

In experiments at the high-power Z-facility at Sandia National Laboratory in Albuquerque, New Mexico, we have been able to produce a low density photoionized laboratory plasma of Fe mixed with NaF. The conditions in the experiment allow a meaningful comparison with X-ray emission from astrophysical sources. The charge state distributions of Fe, Na and F are determined in this plasma using high resolution X-ray spectroscopy. Independent measurements of the density and radiation flux indicate unprecedented values for the ionization parameter ξ = 20–25 erg cm s⁻¹ under nearly steady-state conditions. First comparisons of the measured charge state distributions with X-ray photoionization models show reasonable agreement, although many questions remain.  相似文献   

The nature of parallax microlensing events towards the Galactic bulge     

Martin C. Smith  Vasily Belokurov  N. Wyn Evans  Shude Mao  Jin H. An 《Monthly notices of the Royal Astronomical Society》2005,361(1):128-140

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The angular momentum of gas in protogalaxies – II. The impact of pre-heating     

Frank C. van den Bosch  Tom Abel  Lars Hernquist 《Monthly notices of the Royal Astronomical Society》2003,346(1):177-185

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North European last glacial–interglacial transition (LGIT; 15–9 ka) tephrochronology: extended limits and new events     

C. S. M. Turney  K. Van Den Burg  S. Wastegrd  S. M. Davies  N. J. Whitehouse  J. R. Pilcher  C. Callaghan 《第四纪科学杂志》2006,21(4):335-345

High‐precision correlation of palaeoclimatic and palaeoenvironmental records is crucial for testing hypotheses of synchronous change. Although radiocarbon is the traditional method for dating late Quaternary sedimentary sequences, particularly during the last glacial–interglacial transition (LGIT; 15–9 ka), there are inherent problems with the method, particularly during periods of climate change which are often accompanied by major perturbations in atmospheric radiocarbon content. An alternative method is the use of tephras that act as time‐parallel marker horizons. Within Europe, numerous volcanic centres are known to have erupted during the LGIT, providing considerable potential for high‐precision correlation independent of past radiocarbon fluctuations. Here we report the first identification of the Vedde Ash and Askja Tephra in Ireland, significantly extending the known provenance of these events. We have also identified two new horizons (the Roddans Port Tephras A and B) and tentatively recognise an additional horizon from Vallensgård Mose (Denmark) that provide crucial additional chronological control for the LGIT. Two phases of the Laacher See Tephra (LST) are reported, the lower Laacher See Tephra (LLST) and probably the C2 phase of the Middle Laacher See Tephra (MLST‐C2) indicating a more northeasterly distribution of this fan than reported previously. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

Modeling the distribution of aluminum speciation in acid soil solution equilibria with the mineral phase alunite     

S. Bi  S. An  W. Tang  M. Yang  H. Qian  J. Wang 《Environmental Geology》2001,41(1-2):25-36

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