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1.
QUEST on DASI is a ground-based, high-sensitivity, high-resolution (ℓmax2500) experiment designed to map CMB polarization at 100 and 150 GHz and to measure the power spectra from E-modes, B-modes from lensing of the CMB, and B-modes from primordial gravitational waves. The experiment comprises a 2.6 m Cassegrain optical system, equipped with an array of 62 polarization-sensitive bolometers (PSBs), located at the South Pole. The instrument is designed to minimize systematic effects; features include differencing of pairs of orthogonal PSBs within a single feed, a rotatable achromatic waveplate, and axisymmetric rotatable optics. In addition the South Pole location allows both repeatable and highly controlled observations. QUEST on DASI will commence operation in early 2005.  相似文献   
2.
Biominerals are natural composite materials comprising organic and inorganic components. Detailed knowledge of the nature and distribution of both components is a crucial requirement in order to advance our understanding of biomineral formation, their material properties and preservation potential as well as the interpretation of environmental data. Detailed chemical data are essential for our understanding of the nature and distribution of such components. Micro-XANES mapping at the sulphur K-edge reveals that, in the brachiopod Terebratulina retusa, the sulphate concentration is higher in the outer (primary) layer than in the calcite fibres of the secondary layer. This is co-incident with a higher magnesium concentration. In contrast, the sheaths surrounding the calcite fibres contain sulphur as thiol, confirming the presence of protein while, the sulphur within the fibres themselves, occurs as sulphate. Micro-XANES analysis of the insoluble organic extract from T. retusa indicates the presence of organic sulphate while Micro-Raman spectroscopy confirms that structurally substituted sulphate (SSS) is also present although semi-quantitative Raman spectroscopy carried out in this spectral region (wavenumbers 900–1200) indicates that the sulphate present is at the threshold of detection by Raman spectroscopy. The distribution of phosphorus in the shell of T. retusa correlates well with that of protein indicating the presence of phosphorylated proteins in the periostracum, the sheaths surrounding the calcite fibres and the interface between the primary and secondary layer.  相似文献   
3.
Our ability to identify thin non-stoichiometric and amorphous layers beneath mineral surfaces has been tested by undertaking X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM) work on alkali feldspars from pH 1 dissolution experiments. The outcomes of this work were used to help interpret XPS and TEM results from alkali feldspars weathered for <10,000 years in soils overlying the Shap Granite (north-west England). The chemistry of effluent solutions indicates that silica-rich layers a few nanometers in thickness formed during the pH 1 experiments. These layers can be successfully identified by XPS and have lower Al/Si, Na/Si, K/Si and Ca/Si values than the outermost ∼9 nm of unweathered controls. Development of Al-Si non-stoichiometry is coupled with loss of crystal structure to produce amorphous layers that are identifiable by TEM where >∼2.5 nm thick, whereas the crystallinity of albite is retained despite leaching of Na to depths of tens to hundreds on nanometers. Integration of XPS data over the outermost 6-9 nm of naturally weathered Shap feldspars shows that they have stoichiometric Al/Si and K/Si ratios, which is consistent with findings of previous TEM work on the same material that they lack amorphous layers. There is some XPS evidence for loss of K from the outermost couple of nanometers of Shap orthoclase, and the possibility of leaching of Na from albite to greater depths cannot be excluded using the XPS or TEM results. This study demonstrates that the leached layer model, as formulated from laboratory experiments, is inapplicable to the weathering of alkali feldspars within acidic soils, which is an essentially stoichiometric reaction.  相似文献   
4.
Far-from-equilibrium batch dissolution experiments were carried out on the 2000–500, 500–250, 250–53 and 53–2 μm size fractions of the mineral component of the B horizon of a granitic iron humus podzol after removal of organic matter and secondary precipitates. The different size fractions were mineralogically and chemically similar, the main minerals present being quartz, alkali and plagioclase feldspar, biotite and chlorite. Specific surface area increased with decreasing grain size. The measured element release rates decreased in the order 53–2>>>2000–500>500–250>250–53 μm. Surface area normalised element release rates from the 2000–500, 500–250 and 250–53 μm size fractions (0.6–77×10−14 mol/m2/s) were intermediate between literature reported surface area normalised dissolution rates for monomineralic powders of feldspar (0.1–0.01×10−14 mol/m2/s) and sheet silicates (100×10−14 mol/m2/s) dissolving under similar conditions. Element release rates from the 53–2 μm fraction (400–3000×10−14 mol/m2/s) were a factor of 4–30 larger than literature reported values for sheet silicates. The large element release rate of the 53–2 μm fraction means that, despite the small mass fraction of 53–2 μm sized particles present in the soil, dissolution of this fraction is the most important for element release into the soil. A theoretical model predicted similar (within a factor of <2) bulk element release rates for all the mineral powders if observed thicknesses of sheet silicate grains were used as input parameters. Decreasing element release rates with decreasing grain size were only predicted if the thickness of sheet silicates in the powders was held constant. A significantly larger release rate for the 53–2 μm fraction relative to the other size fractions was only predicted if either surface roughness was set several orders of magnitude higher for sheet silicates and several orders of magnitude lower for quartz and feldspars in the 53–2 μm fraction compared to the other size fractions or if the sheet silicate thickness input in the 53–2 μm fraction was set unrealistically low. It is therefore hypothesised that the reason for the unpredicted large release rate from the 52–3 μm size fraction is due to one or more of the following reasons: (1) the greater reactivity of the smaller particles due to surface free energy effects, (2) the lack of proportionality between the BET surface area used to normalise the release rates and the actual reactive surface area of the grains and, (3) the presence of traces quantities of reactive minerals which were undetected in the 53–2 μm fraction but were entirely absent in the coarser fractions.  相似文献   
5.
Bob Forsyth and Andy Breen report from the RAS G Discussion Meeting at the Geological Society on 11 January 2002. Presentations came from both the solar and heliospheric communities, on the 3-D structure and dynamics of the solar corona and heliosphere and their inter-relation during the present maximum in the solar activity cycle.  相似文献   
6.
我国实施“天然林保护工程”以来,林区人民积极转产分流,寻找新的就业门路和生计,为走出困境、改善生活做出了不懈的努力。为了进一步开阔视野,拓展思路,借鉴他国的经验,我们选刊了“国际森林趋势组织”的几篇关于寻找新的林区就业渠道和森林环境服务市场开发方面的研究文章,以期对我国的林业改革与建设有所启示。(注:这些文章已经“森林趋势组织”的执行主管Mivhael Jenkins先生同意译成中文在本刊刊登,本刊作了部分删节和改动。原文及参考文献请参阅森林趋势组织的网页:http://www. forest-trends. org)  相似文献   
7.
Despite the wealth of archaeological sites and excellent conditions for preservation, few phytolith investigations have been undertaken from the Arabian Gulf region. The results from the Sasanian and Islamic archaeological tell of Kush, Ras al-Khaimah, United Arab Emirates, are presented. Kush is situated just inside the Gulf on an important trade route. The occupation sequence dates from the 4th century A.D. until the 13th century A.D., recording the development of the site in the Sasanian period, followed by the arrival of Islam in the 7th century A.D. and the final abandonment of the site in the late 13th century when the nearby site of al-Mataf (Julfar) began to develop closer to the present day coastline. All the samples analyzed contained abundant phytoliths (short cells, elongated cells, and groups of elongated cells) of various types. They included date palm (Phoenix dactylifera), papillae (possibly from barley (Hordeum)), and hair cells possibly from species of canary grass (Phalaris spp.). Some researchers have suggested that groups of elongated cells may indicate the presence of irrigation in semiarid environments. The present results for this class of phytoliths appeared to imply that intensive irrigation was unlikely to have taken place around Kush.  相似文献   
8.
Lipid extracts from a 61.7-cm-long subtropical stalagmite in southern China, spanning the period of ca. 10,000–21,000 yr ago as constrained by U–Th dating, were analyzed using gas chromatography–mass spectrometry. The higher plants and microorganisms in the overlying soils contribute a proportion of n-alkanes identified in the stalagmite. The occurrence of LMW (lower molecular weight) n-alkanols and n-alkan-2-ones in the stalagmite was mainly related to the soil microorganisms. We suggest that HMW (higher molecular weight) n-alkanols and n-alkan-2-ones identified in the stalagmite originate from soil organics and reflect input from contemporary vegetation. Shifts in the ratio of LMW to HMW n-alkanols or n-alkan-2-ones indicative of the variation of soil ecosystems (e.g., microbial degradation of organic matter and/or the relative abundance of soil microorganisms to higher plants) are comparable with the subtropical alkenone-SST (sea surface temperature) record of the same period. The similar trends seen in the δ13C data and the lipid parameters in this stalagmite imply that the overlying soil ecosystem response to climate might be responsible for the variation of δ13C values.  相似文献   
9.
In the Western layered syenite stock of the Kûngnât complex, close to the intrusion wall, there are two groups of regularly spaced, horizontally aligned, stacks of infilled troughs. These features resemble, to some extent, the trough layering within the UZa trough zone of the gabbroic Skaergaard1 intrusion. Such features have never before been described in syenitic rocks. The lower group comprises six stacks of infilled troughs; the upper group comprises seven. The two groups are vertically separated by about 10 m of sparsely layered syenite. The infilled troughs in the upper group are stacked vertically; those in the lower group gradually shift laterally and appear to converge over an antiformal structure. It is not possible to measure the plunge of the troughs due to outcrop geometry. Troughs are up to about 80 cm deep. The material filling the troughs is more melanocratic than the syenite that surrounds them. Individual troughs exhibit normal grading. The syenite within the troughs contains large amphibole and biotite oikocrysts. Faintly layered syenite occurs laterally between stacks. Minerals in the host syenite are more ferroan than those in the troughs, this is thought to represent re-equilibration with residual melt. Feldspar textures, irregular pyroxene and apatite zoning, and the presence of irregular shaped amphibole patches within pyroxene grains all imply alteration by a pervasive deuteric fluid in both troughs and host syenite. We suggest the following hypothesis for the formation of the troughs. A mafic crystal sheath which grows on the walls of the magma chamber becomes detached and flows downwards. The descending slurry forms a series of regularly spaced streams which erode trough shaped channels into the crystal pile at the base of the chamber. Uneroded crystal material separates the channels. Crystals are deposited from these streams. Successive streams flow over each other to generate stacks of troughs.  相似文献   
10.
The devolution and regionalisation of political and administrative structures following the election of New Labour in 1997 have changed the nature of the state and territorial development and governance in the UK. A regional and sub-national tier has opened up within the existing multi-layered governance system operating at the supra-national, national and local scales. This ‘new institutional space’ is increasingly open to the participation of social institutions--including trade unions--in economic and social governance. Drawing upon empirical analysis of the experience of the Northern Trade Union Congress (NTUC) in the North East region of England, the paper argues that the NTUC--in contrast to its national organisation--is beginning to engage with the emergent institutional structures but its role is inhibited by the centralised strategy and structure of the TUC nationally, its own need for upgrading, capacity building and greater financial resources and the interaction between the North East’s particular legacy of tripartite corporatism and the more pluralist modes of regional development governance emerging in the English regions. Unless such issues are addressed regional trade union centres--such as the NTUC--risk remaining relatively junior partners in the emergent regional governance structures.  相似文献   
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