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1.
Daniel P. Glavin Jason P. Dworkin Andrew Aubrey Oliver Botta James H. Doty Zita Martins Jeffrey L. Bada 《Meteoritics & planetary science》2006,41(6):889-902
Abstract— Amino acid analyses of the Antarctic CM2 chondrites Allan Hills (ALH) 83100 and Lewis Cliff (LEW) 90500 using liquid chromatography‐time of flight‐mass spectrometry (LC‐ToF‐MS) coupled with UV fluorescence detection revealed that these carbonaceous meteorites contain a suite of indigenous amino acids not present in Antarctic ice. Several amino acids were detected in ALH 83100, including glycine, alanine, β‐alanine, γ‐amino‐n‐butyric acid (γ‐ABA), and α‐aminoisobutyric acid (AIB) with concentrations ranging from 250 to 340 parts per billion (ppb). In contrast to ALH 83100, the CM2 meteorites LEW 90500 and Murchison had a much higher total abundance of these amino acids (440–3200 ppb). In addition, ALH 83100 was found to have lower abundances of the α‐dialkyl amino acids AIB and isovaline than LEW 90500 and Murchison. There are three possible explanations for the depleted amino acid content in ALH 83100: 1) amino acid leaching from ALH 83100 during exposure to Antarctic ice meltwater, 2) a higher degree of aqueous alteration on the ALH 83100 parent body, or 3) ALH 83100 originated on a chemically distinct parent body from the other two CM2 meteorites. The high relative abundance of ?‐amino‐n‐caproic acid (EACA) in the ALH 83100 meteorite as well as the Antarctic ice indicates that Nylon‐6 contamination from the Antarctic sample storage bags may have occurred during collection. 相似文献
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The offshore tide becomes strongly distorted as it propagates into shallow estuarine systems. Observations of sea surface elevation and horizontal currents over periods ranging from three days to one year, at nine stations within Nauset inlet/estuary, document the non-linear interaction of the off-shore equilibrium tidal constituents. Despite strong frictional attenuation within the estuary, the overtides and compound tides of M2, S2 and N2, in particular, reach significant amplitude, resulting in strong tidal distortion. High frequency forced constituents in sea surface are phase-locked, consistently leading the forcing tides by 60–70°, resulting in a persistent distortion where falling tide is longer than rising tide. Forced constituents in currents are more nearly in phase with equilibrium constituents, producing flood currents which are shorter but more intense than ebb currents. A compound fortnightly tide, MSf, modulates the mean water level such that lowest tides occur during neap phase instead of spring phase. This fortnightly tide can be contaminated by storm surge, changing the phase characteristics of this constituent. Implications of the overtides, compound tides, and lower frequency tides on near-bed, suspended and dissolved material transport are profound. 相似文献
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Bruce W. Fouke Aubrey L. Zerkle Walter Alvarez† Kevin O. Pope‡ Adriana C. OcampO§ Richard J. Wachtman Jose Manuel Grajales Nishimura¶ Phillipe Claeys & Alfred G. Fischer†† 《Sedimentology》2002,49(1):117-138
The depositional and diagenetic history of Cretaceous–Tertiary (KT) impact ejecta deposited 360 km from the Chicxulub crater, at Albion Island, Belize, has been investigated using integrated cathodoluminescence and isotopic analyses. A quarry exposes 26 m of Upper Cretaceous Barton Creek Formation dolomitized marine limestone overlain by 16 m of dolomitized Albion Formation impact ejecta. The Albion Formation consists of a lower fine‐grained ≈1‐m‐thick spheroid bed and an upper 15‐m‐thick coarse conglomeratic diamictite bed. A 14‐event paragenetic sequence has been documented and used as a temporal framework to interpret chemostratigraphic trends in bulk rock δ18O, δ13C and 87Sr/86Sr. The uppermost surface of the Barton Creek Formation was subaerially exposed before the KT impact, as indicated by a brecciated palaeosol that caps upsection decreases in δ13C and δ18O. Small 1‐cm‐diameter spheroids in the spheroid bed exhibit vermicular crystalline textures but lack the concentric zonations common to accretionary lapilli. These spheroids are hypothesized originally to have been impact glass or reactive Ca and Mg oxide dusts that adhered to water vapour particles condensing from the cooling impact vapour cloud. The spheroids were dolomitized soon after deposition. The earliest dolomitization in the matrix sediments of the Albion Formation was also post‐depositional, replacing clays formed by devitrification of impact glass. Dolomite and clay 87Sr/86Sr exhibit a distinct symmetrical distribution in the spheroid bed ranging from 0·707745 to 0·707872. Although unproven, this may represent primary changes in the chemical composition of the impact glass. The limestone clasts in the diamictite bed were dolomitized before the KT impact and exhibit upsection decreases in bulk rock 87Sr/86Sr. This suggests that the clasts were excavated from strata equivalent in age or older than the Barton Creek Formation at locations closer to, or in, the Chicxulub crater. 相似文献
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北大别黄土岭麻粒岩锆石U—Pb离子探针定年 总被引：28，自引：6，他引：28
阴极发光显微结构分析表明 ,北大别黄土岭麻粒岩中存在三种类型的锆石 :原岩锆石、麻粒岩相锆石和残留锆石。对它们分别进行离子探针定年 ,得到黄土岭麻粒岩的原岩年龄约为 2 70 0 Ma、麻粒岩相变质事件的年龄为 2 0 5 2± 10 0 Ma、残留锆石的年龄为约 3.4 Ga。以上研究表明黄土岭麻粒岩为残存的扬子板块的结晶基底 ,而约 3.4 Ga残留锆石的发现 ,则首次证明大别山地区存在古太古代的陆壳物质 相似文献
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Natural fisheries in most parts of the world are under pressure due to heavy fishing activities and pollution threats. The establishment of fish and shrimp hatcheries using native species provides an opportunity for replenishment of fish and shrimp stocks in an environmentally responsible manner. This paper provides guidelines for conducting an EIA of fish and shrimp hatcheries in a semi-enclosed water body, such as the Arabian Gulf and Red Sea. The purpose of the guidelines is to outline issues that may be relevant to the design and construction of hatcheries and to identify important factors for consideration in an EIA study. Effective consultations and technical discussions during the design stage with project proponent and relevant government agencies are recommended. Early evaluation of alternative sites and consideration of environmental factors in ascertaining the suitability of intended project site can help minimize potential impacts. Aspects to be considered in depth include impacts on water quality, sediment and habitat loss. The paper also provides suggested mitigation measures for minimizing potential impacts along with key elements to be considered in the development of an adequate Environmental Management and Monitoring Plan. 相似文献
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Spatial and temporal patterns of recent sea-level rise along the United States coastline have been examined to ascertain rates of rise, and possible causes for high-frequency fluctuations in sea level. Eigenanalysis identified several distinct coastal compartments within each of which sea-level behavior is consistent. The United States east coast has three of these compartments: one north of Cape Cod, where sea-level rise increases with distance to the north; one between Cape Cod and Cape Hatteras where sea-level rise increases to the south; and the third from Cape Hatteras south to Pensacola, where sea-level rise decreases to the south. The western gulf coast represents another compartment (poorly sampled in this study), where subsidence is partly due to compaction. The final compartment is along the United States west coast, where poor spatial sampling produces a highly spatially variable sea-level record that has some temporal uniformity. Spectral analysis shows a dominant time scale of six years for sea-level variability, with different coastal compartments responding relatively in or out of phase. No evidence for increased rates of sea-level rise over the past 10 years was found. This objective statistical technique is a valuable tool for identifying spatial and temporal sea-level trends in the United States. It may later prove useful for identifying elusive world-wide trends of sea level, related to glacial melting, glacial rebound, tectonism, and volcanic activity. 相似文献
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Sulfur cycling in a stratified euxinic lake with moderately high sulfate: Constraints from quadruple S isotopes 总被引：1，自引：0，他引：1
Aubrey L. Zerkle Alexey Kamyshny Jr. Lee R. Kump James Farquhar Harry Oduro Michael A. Arthur 《Geochimica et cosmochimica acta》2010,74(17):4953-154
We present a 3-year study of concentrations and sulfur isotope values (δ34S, Δ33S, and Δ36S) of sulfur compounds in the water column of Fayetteville Green Lake (NY, USA), a stratified (meromictic) euxinic lake with moderately high sulfate concentrations (12-16 mM). We utilize our results along with numerical models (including transport within the lake) to identify and quantify the major biological and abiotic processes contributing to sulfur cycling in the system. The isotope values of sulfide and zero-valent sulfur across the redox-interface (chemocline) change seasonally in response to changes in sulfide oxidation processes. In the fall, sulfide oxidation occurs primarily via abiotic reaction with oxygen, as reflected by an increase in sulfide δ34S at the redox interface. Interestingly, S isotope values for zero-valent sulfur sampled at this time still reflect production and recycling by phototrophic S-oxidation. In the spring, sulfide S isotope values suggest an increased input from phototrophic oxidation, consistent with a more pronounced phototroph population at the chemocline. This trend is associated with smaller fractionations between sulfide and zero-valent sulfur, suggesting a metabolic rate control on fractionation similar to that for sulfate reduction. Comparison of our data with previous studies indicates that the S isotope values of sulfate and sulfide in the deep waters are remarkably stable over long periods of time, with consistently large fractionations of up to 58‰ in δ34S. Models of the δ34S and Δ33S trends in the deep waters (considering mass transport via diffusion and advection along with biological processes) require that these fractionations are a consequence of sulfur compound disproportionation at and below the redox interface in addition to large fractionations during sulfate reduction. The large fractionations during sulfate reduction appear to be a consequence of the high sulfate concentrations and the distribution of organic matter in the water column. The occurrence of disproportionation in the lake is supported by profiles of intermediate sulfur compounds and by lake microbiology, but is not evident from the δ34S trends alone. These results illustrate the utility of including minor S isotopes in sulfur isotope studies to unravel complex sulfur cycling in natural systems. 相似文献
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Jeffrey M. Aristoff Joshua T. Horwood Aubrey B. Poore 《Celestial Mechanics and Dynamical Astronomy》2014,118(1):13-28
We present a new variable-step Gauss–Legendre implicit-Runge–Kutta-based approach for orbit and uncertainty propagation, VGL-IRK, which includes adaptive step-size error control and which collectively, rather than individually, propagates nearby sigma points or states. The performance of VGL-IRK is compared to a professional (variable-step) implementation of Dormand–Prince 8(7) (DP8) and to a fixed-step, optimally-tuned, implementation of modified Chebyshev–Picard iteration (MCPI). Both nearly-circular and highly-elliptic orbits are considered using high-fidelity gravity models and realistic integration tolerances. VGL-IRK is shown to be up to eleven times faster than DP8 and up to 45 times faster than MCPI (for the same accuracy), in a serial computing environment. Parallelization of VGL-IRK and MCPI is also discussed. 相似文献