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1.
Hydrothermal vein minerals directly associated with native gold mineralization in the Muruntau vein system (Uzbekistan) have been studied for noble gas, carbon isotope and halogen chemistry of the trapped ore-related fluids. Helium trapped in early arsenopyrite 1, which has preserved the original fluid signature better than associated scheelite and quartz, indicates a small input from a mantle source (?5% of total He). However, the overwhelming majority of the He in the fluid (∼95%) is from crustal sources. The noble gases Ne, Kr and Xe in the sample fluids are dominated by gases of atmospheric origin. The carbon isotope (δ13C: −2.1‰ to −5.3‰) and halogen characteristics of the fluids (log Br/Cl: −2.64 to −3.23) lend further support for the activity of juvenile fluids during the main ore stage. The high proportion of crustal components in the ore-forming fluids may be explained by intense fluid-rock interaction and is also supported by previous Nd and Sr isotope studies. The involvement of a juvenile fluid component during the main stage of hydrothermal activity at Muruntau (∼275 Ma) can be linked to the emplacement of lamprophyric dikes at Muruntau, due to apparently overlapping ages for high-temperature alteration, related ore vein formation and intrusion of the dikes. The input of mantle-derived fluids, possibly related to the Hercynian collisional event in the western Tien Shan, stimulated intense fluid-rock interaction in the crust. In this context, the mantle-derived fluid should be considered as one possible carrier of metals. Significant amounts of external meteoric fluids circulating in fracture systems are interpreted to have modified the noble gas signature of fluid in quartz, mostly during late, low temperature fluid circulation.  相似文献   
2.
We investigated the influence of thermal maturity on the hydrogen isotope ratios of sedimentary hydrocarbons to prove that the isotope ratio of hydrocarbons mirrors paleoclimate signatures. δD values from n-alkanes and acyclic isoprenoids of two sediment sections (Kupferschiefer [KS], 258 Ma, and Posidonienschiefer [PS], 184 Ma) with different maturation history were investigated. Both covered thermal maturity from 0.48 to 1.3 Rc (vitrinite reflectance and reflectance calculated from MPI1). Sediment burial up to 4500 m caused thermal maturation of organic matter in the KS horizon from the Early Zechstein basin of Poland, whereas contact metamorphic thermal maturation originated in the Early Toarcian PS (Posidonienschiefer) of the North German Vlotho Massif. The δD values of the extracted n-alkanes positively correlate with thermal maturity in the KS (y = 56‰ × MPI1[x] − 160‰ [VSMOW]) and in the PS (y = 104‰ × MPI1[x] − 200‰ [VSMOW]). The δD values of isoprenoids (i.e., pristane, phytane) were even more enriched with increasing maturity (y = 179‰ × MPI1[x] − 341‰ [VSMOW] in the KS; y = 300‰ × MPI1[x] − 415‰ [VSMOW] in PS).These results explain why isotope ratios of n-alkanes and isoprenoids in mature sediments are generally enriched in D and do not have the expected isotopic difference between n-alkanes and isoprenoids of ∼190‰. Moreover, the correlation between sediment maturity parameters and δD values suggests that after correction the δD values of n-alkanes can be used to reconstruct climate and environment in the geological past.  相似文献   
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Intra‐urban cooling rates were monitored for a year in the centre of Göteborg on the Swedish west coast. Five sites with different building geometry ‐ from dense canyon to open space ‐ within a radius of 300 m were analysed. Results showed two modes of cooling during the night. In the first mode, the cooling was site‐dependent ‐the open space cooled the most and the dense canyon the least. In the second mode, which began about 3–4 hours after sunset, all sites cooled at the same rate. Our hypothesis is that in the early part of the evening both radiative divergence and sensible heat dominate the cooling. However, as the evening progresses, a spatially homogeneous inversion is established which controls the radiative cooling, making the cooling independent of both surface geometry and surface type. From April to November the sites cooled rapidly around sunset and the cooling slowly decreased during the rest of the night. However, between December and March, the cooling was less intense, with an almost constant rate during the entire night. It has been suggested that this might be the result of the draining of stored solar heat during the summer and a continuous flux of anthropogenic heating during the winter.  相似文献   
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From the Sellevollmyra bog at Andøya, northern Norway, a 440‐cm long peat core covering the last c. 7000 calendar years was examined for humification, loss‐on‐ignition, microfossils, macrofossils and tephra. The age model was based on a Bayesian wiggle‐match of 35 14C dates and two historically anchored tephra layers. Based on changes in lithology and biostratigraphical climate proxies, several climatic changes were identified (periods of the most fundamental changes in italics): 6410–6380, 6230–6050, 5730–5640, 5470–5430, 5340–5310, 5270–5100, 4790–4710, 4890–4820, 4380–4320, 4220–4120, 4000–3810, 3610–3580, 3370–3340 (regionally 2850–2750; in Sellevollmyra a hiatus between 2960–2520), 2330–2220, 1950, 1530–1450, 1150–840, 730? and c. 600? cal. yr BP. Most of these climate changes are known from other investigations of different palaeoclimate proxies in northern and middle Europe. Some volcanic eruptions seemingly coincide with vegetation changes recorded in the peat, e.g. about 5760 cal. yr BP; however, the known climatic deterioration at the time of the Hekla‐4 tephra layer started some decades before the eruption event.  相似文献   
7.
A new tephra has been identified within a long core (EC 3) sequence recovered from Les Echets, near Lyon, France. This visible tephra was discovered as part of a high resolution multiproxy re-investigation of the Les Echets sequence. Independent chronological information suggests that the tephra is c . 2 000–45 000 years old, and geochemical analysis indicates that it is of basanitic composition. The latter suggests a possible origin in the Eifel; however, as yet, no other volcanic events or deposits can be correlated to the Les Echets tephra. New sedimentological and chronological data are presented indicating that the tephra falls within an interval that most likely correlates with Dansgaard–Oeschger events 12-9. Thus, this tephra could potentially be an important middle MIS 3 marker horizon in central Europe if it can be traced in other palaeorecords.  相似文献   
8.
Deeper water black shales, overlain by coccolith-bearing marlstones representing the incipient Paratethys (example: Early Oligocene; Austrian Molasse Basin), have sedimentary characteristics similar to those of the Holocene Black Sea since 7500 years bp. Framboid pyrite size, biomarker and C–N-isotope data additionally indicate that isolation of the Paratethys resulted in Black Sea-type characteristics during nannoplankton zone NP 23.In contrast to the estuarine circulation across the Bosphorus since 7500 years bp, marine conditions prevailed in the incipient Paratethys during NP 21/22. Nitrogen was fixed and low organic carbon accumulation rates prevailed. In both settings a vertical density water-column stratification was accompanied by photic zone anoxia, and by anaerobic methane oxidation in the Paratethys. In the Paratethys increased run off, starting in NP 22, led to estuarine circulation during NP 23. During this period cyclic blooms of calcareous nannoplankton resulted in high calcite accumulation rates which diluted the coeval clay sedimentation. Similar sedimentary features in the Black Sea and the Paratethys during the earliest Oligocene are result from opposite paleoceanographic developments, both leading to estuarine circulation patterns. In the Black Sea, permanent photic zone anoxic conditions were established 7500 years bp in response to the first invasion of saline Mediterranean waters into the former freshwater lake. In contrast, brackish surface water in the Paratethys resulted from nutrient-rich freshwater diluting the marine water body.  相似文献   
9.
Biomarker compositions of particulate organic matter (POM) from the oligotrophic Lake Brienz and the eutrophic Lake Lugano (both Switzerland) are compared, in order to obtain information about organic matter (OM) production and transformation processes in relation to water column stratification. Eutrophic conditions in Lake Lugano are reflected by enhanced alkalinity, elevated total organic carbon (TOC) and chlorin contents compared with Lake Brienz. Lower δ13C values of dissolved inorganic carbon (DIC) in Lake Lugano reflect enhanced OM respiration in the water column.Differences in OM dynamics between both lakes, as well as seasonal variations, are evidenced by TOC-normalised concentration profiles of total fatty acids (FAs) and total neutrals. In Lake Brienz, the results reflect the relative contributions of primary productivity and refractory, allochthonous OM to POM, governed by particle load and interflows due to density stratification. The depth trends at Lake Lugano are a result of high primary productivity, water column stratification and associated particle load in the upper layers, as well as microbially induced degradation close to the chemocline and greater preservation under anoxic conditions. Minor differences exist with regard to the OM composition. In both lakes, FA distributions and the composition of n-alkanols indicate a predominant autochthonous OM source (algae, zooplankton, bacteria). Inputs of OM from diatoms are reflected in highly-branched isoprenoid (HBI) alkenes, 16:1 n-FAs and 24-methylcholesta-5,22-dien-3β-ol (either epibrassicasterol or brassicasterol). Differences in relative proportions of n-C16 vs. n-C18 FAs and alkanols, respectively, as well as in the percentages of C27, C28 and C29 sterols relative to the sum of sterols are related to differences in the abundances of chrysophytes, diatoms and green algae within the euphotic zone of both lakes as well as in bacterial activity and soil in-wash. High relative proportions of cholesterol in the autumn samples, most pronounced at Lake Lugano, were attributed to an increased input from zooplankton grazing in the water column.Differences in OM degradation processes are reflected in slightly higher chlorin index values and higher relative proportions of saturated vs. unsaturated n-FAs in Lake Lugano. Higher contents of branched chain FAs, 16:1ω7 n-FA, and enhanced 18:1ω7/18:1ω9 n-FA ratios suggest enhanced bacterial biomass in the water column of Lake Lugano close to the chemocline. Increasing proportions of saturated n-FAs and n-alkanols with increasing water depth, most distinct in the autumn for both lakes, argue for intensified bacterial activity and degradation of OM during autumn. High relative contents of sterols and low n-alkanol concentrations in POM close to the chemocline at Lake Lugano during spring are interpreted to reflect higher primary productivity in the photic zone, OM export to the deeper parts and enhanced degradation rates of more labile constituents (i.e. C13–C20 n-alkanols), as compared to Lake Brienz.  相似文献   
10.
This study produced the first data on population parameters for sicklefin lemon shark Negaprion acutidens at the granitic Seychelles Islands, adding to a limited catalogue of species information. Juveniles at a site in the Curieuse Marine National Park were tagged over two periods, in 2014–2015 and 2015–2016, with measurements of length (precaudal, fork and total) and weight, sex, and state of the umbilical opening recorded. Recapture data were used to calculate growth rates and population size. Mean annual growth rate was 5.40 cm y–1. A mean size at birth of 62.5 cm TL is in line with previous assessments of the species. Population-size estimates were similar for the two sampling periods (comprising 311 and 255 individuals) and higher than anticipated. Movements to outside the lagoon were recorded for early ages, and this, combined with weight loss and a reduction in condition factor as displayed in several individuals, suggests that the study area alone could not support the large number of sharks pupped yearly.  相似文献   
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