Limitations of the ferrozine method for quantitative assay of mineral systems for ferrous and total iron   总被引：1，自引：0，他引：1  

Alexandre S. Anastácio  Hae-In Yoo  Joseph W. Stucki 《Geochimica et cosmochimica acta》2008,72(20):5001-5008

The quantitative assay of clay minerals, soils, and sediments for Fe(II) and total Fe is fundamental to understanding biogeochemical cycles occurring therein. The commonly used ferrozine method was originally designed to assay extracted forms of Fe(II) from non-silicate aqueous systems. It is becoming, however, increasingly the method of choice to report the total reduced state of Fe in soils and sediments. Because Fe in soils and sediments commonly exists in the structural framework of silicates, extraction by HCl, as used in the ferrozine method, fails to dissolve all of the Fe. The phenanthroline (phen) method, on the other hand, was designed to assay silicate minerals for Fe(II) and total Fe and has been proven to be highly reliable. In the present study potential sources of error in the ferrozine method were evaluated by comparing its results to those obtained by the phen method. Both methods were used to analyze clay mineral and soil samples for Fe(II) and total Fe. Results revealed that the conventional ferrozine method under reports total Fe in samples containing Fe in silicates and gives erratic results for Fe(II). The sources of error in the ferrozine method are: (1) HCl fails to dissolve silicates and (2) if the analyte solution contains Fe³⁺, the analysis for Fe²⁺ will be photosensitive, and reported Fe(II) values will likely be greater than the actual amount in solution. Another difficulty with the ferrozine method is that it is tedious and much more labor intensive than the phen method. For these reasons, the phen method is preferred and recommended. Its procedure is simpler, takes less time, and avoids the errors found in the ferrozine method.  相似文献   

Design of ship's bow form by potential-based panel method     

Jaehoon Yoo   《Ocean Engineering》2007,34(8-9):1089-1095

A surface panel method treating a boundary-value problem of the Dirichlet type with the free surface is presented to design a three-dimensional body corresponding to a prescribed pressure distribution. The free surface boundary condition is linearized with respect to the oncoming flow, and computed by four-point finite difference scheme. Sample designs for submerged spheroids and Wigley hull are carried out to demonstrate the stable convergence, the effectiveness and the robustness of the method. The design of a 5500TEU container carrier is performed with respect to reduction of the wave resistance. To reduce the wave resistance, calculated pressure on the hull surface is modified to have the lower fluctuation, and is applied as a Dirichlet type dynamic boundary condition on the hull surface. The designed hull form is verified to have the lower wave resistance than the initial one not only by computation but also by experiment.  相似文献   

Abyssal bedforms and sediment drifts effected by deep-sea flows     

Hideo Kagami  Bong -Chool Suk 《Journal of Oceanography》1986,42(4):308-318

The investigation of abyssal bedforms and sediment drifts as a tool for understanding the deep flow characteristics allows us to interprete that a benthic storm is primarily related to sediment distribution, development of longitudinal ripple marks, and concentration of suspended particulate matter. There explicitly exists a strong and periodical bottom flow which is called the benthic storm having a current speed of over 15 cm sec^?1 and duration of more than two days. Hydrodynamic regime has been thought to affect underlying sediment textural natures which can be used to distinguish between bottom currents with different velocities. Therefore, concentration of medium silt mode (0.010–0.017 mm in size) delineates a high-velocity core of the benthic storm in the deep sea bottom. Bottom current measurements in most of the North Pacific Ocean indicate that present bottom current speeds are generally less than 10 cm sec^?1. It appears likely, therefore, that significant erosion is not taking place today. However, at current passages, bases of sea mounts, and other topographic obstructions locally accelerated current flows are recognized to affect bottom configuration. While, it is concluded from bottom echo-characteristics and bottom current measurements that widespread occurrences of echo type 3 (sediment-drift deposit facies) recognized at 22°N and 42°N in the Northwest Pacific are associated with the North Equatorial current and the North Pacific current respectively, and can best be interpreted to be originated from benthic storms, the source of which were come from those surface currents.  相似文献   

Fault slip analysis of Quaternary faults in southeastern Korea   总被引：1，自引：0，他引：1  

Youngdo Park  Jin-Han Ree  Seung-Hak Yoo 《Gondwana Research》2006,9(1-2):118

The Quaternary stress field has been reconstructed for southeast Korea using sets of fault data. The subhorizontal direction of the maximum principal stress (σ₁) trended ENE and the direction of the minimum principal stress (σ₃) was nearly vertical. The stress ratio (Φ = (σ₂ − σ₃) / (σ₁ − σ₃)) value was 0.65. Two possible interpretations for the stress field can be made in the framework of eastern Asian tectonics; (1) The σ_Hmax trajectory for southeast Korea fits well with the fan-shaped radial pattern of maximum principal stress induced by the India–Eurasia collision. Thus, we suggest that the main source for this recent stress field in southeast Korea is related to the remote India–Eurasia continental collision. (2) The stress field in Korea shows a pattern similar to that in southwestern Japan. The origin for the E–W trending σ_Hmax in Japan is known to be related to the mantle upwelling in the East China Sea. Thus, it is possible that Quaternary stress field in Korea has evolved synchronously with that in Japan. We suggest further studies (GPS and in situ stress measurement) to test these hypotheses.  相似文献   

Study on effects of damping in laminated rubber bearings on seismic responses for a ⅛ scale isolated test structure     

Bong Yoo  Yang‐Hann Kim 《地震工程与结构动力学》2002,31(10):1777-1792

The effects of damping in various laminated rubber bearings (LRB) on the seismic response of a ?‐scale isolated test structure are investigated by shaking table tests and seismic response analyses. A series of shaking table tests of the structure were performed for a fixed base design and for a base isolation design. Two different types of LRB were used: natural rubber bearings (NRB) and lead rubber bearings (LLRB). Three different designs for the LLRB were tested; each design had a different diameter of lead plug, and thus, different damping values. Artificial time histories of peak ground acceleration 0.4g were used in both the tests and the analyses. In both shaking table tests and analyses, as expected, the acceleration responses of the seismically isolated test structure were considerably reduced. However, the shear displacement at the isolators was increased. To reduce the shear displacement in the isolators, the diameter of the lead plug in the LLRB had to be enlarged to increase isolator damping by more than 24%. This caused the isolator stiffness to increase, and resulted in amplifying the floor acceleration response spectra of the isolated test structure in the higher frequency ranges with a monotonic reduction of isolator shear displacement. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

Crustal structure of the continental margin of Korea in the East Sea (Japan Sea) from deep seismic sounding data: evidence for rifting affected by the hotter than normal mantle   总被引：1，自引：0，他引：1  

Han-Joon Kim  Hyeong-Tae Jou  Hyun-Moo Cho  Harmen Bijwaard  Takeshi Sato  Jong-Kuk Hong  Hai-Soo Yoo  Chang-Eob Baag 《Tectonophysics》2003,364(1-2):25-42

Despite the various opening models of the southwestern part of the East Sea (Japan Sea) between the Korean Peninsula and the Japan Arc, the continental margin of the Korean Peninsula remains unknown in crustal structure. As a result, continental rifting and subsequent seafloor spreading processes to explain the opening of the East Sea have not been adequately addressed. We investigated crustal and sedimentary velocity structures across the Korean margin into the adjacent Ulleung Basin from multichannel seismic (MCS) reflection and ocean bottom seismometer (OBS) data. The Ulleung Basin shows crustal velocity structure typical of oceanic although its crustal thickness of about 10 km is greater than normal. The continental margin documents rapid transition from continental to oceanic crust, exhibiting a remarkable decrease in crustal thickness accompanied by shallowing of Moho over a distance of about 50 km. The crustal model of the margin is characterized by a high-velocity (up to 7.4 km/s) lower crustal (HVLC) layer that is thicker than 10 km under the slope base and pinches out seawards. The HVLC layer is interpreted as magmatic underplating emplaced during continental rifting in response to high upper mantle temperature. The acoustic basement of the slope base shows an igneous stratigraphy developed by massive volcanic eruption. These features suggest that the evolution of the Korean margin can be explained by the processes occurring at volcanic rifted margins. Global earthquake tomography supports our interpretation by defining the abnormally hot upper mantle across the Korean margin and in the Ulleung Basin.  相似文献   

Quantitative estimation of submarine groundwater discharge using airborne thermal infrared data acquired at two different tidal heights     

Ki‐mook Kang  Duk‐jin Kim  Yunjee Kim  Eunhee Lee  Bong‐Gwan Kim  Seung Hee Kim  Kyoochul Ha  Dong‐Chan Koh  Yang‐Ki Cho  Guebuem Kim 《水文研究》2019,33(7):1089-1100

Submarine groundwater discharge (SGD) plays an important role in coastal biogeochemical processes and hydrological cycles, particularly off volcanic islands in oligotrophic oceans. However, the spatial and temporal variations of SGD are still poorly understood owing to difficulty in taking rapid SGD measurements over a large scale. In this study, we used four airborne thermal infrared surveys (twice each during high and low tides) to quantify the spatiotemporal variations of SGD over the entire coast of Jeju Island, Korea. On the basis of an analytical model, we found a linear positive correlation between the thermal anomaly and squares of the groundwater discharge velocity and a negative exponential correlation between the anomaly and water depth (including tide height and bathymetry). We then derived a new equation for quantitatively estimating the SGD flow rates from thermal anomalies acquired at two different tide heights. The proposed method was validated with the measured SGD flow rates using a current meter at Gongcheonpo Beach. We believe that the method can be effectively applied for rapid estimation of SGD over coastal areas, where fresh groundwater discharge is significant, using airborne thermal infrared surveys.  相似文献   

Latitudinal change in benthic foraminiferal fauna by ITCZ movement along the ~131°W transect in the equatorial Pacific Ocean     

Hiroyuki Takata  Chan Min Yoo  Hyung Jeek Kim  Boo-Keun Khim 《Ocean Science Journal》2016,51(4):655-663

Modern and fossil benthic foraminifera were examined from nine surface sediments and two piston cores along the ~131°W transect in the equatorial Pacific Ocean. This study was conducted to clarify the biotic response of abyssal benthic foraminifera during the last 220 ka to changes in the seasonal extent of the Intertropical Convergence Zone (ITCZ). The abundance of modern benthic foraminifera was high at stations between the equator and 6°N, whereas it was low at stations north of 6°N, which is generally consistent with the latitudinal CaCO₃ distribution of surface sediments. The northward increase of Epistominella exigua from the equator to ~6°N is similar to the seasonal variations in chlorophyll-a concentrations in the surface water and ITCZ position along ~131°W. This species was more common at core PC5103 (~6°N) than at core PC5101 (~2°N) after ~130 ka, when the Shannon-Wiener diversity (H’) between the two cores started to diverge. Hence, the presentday latitudinal difference in benthic foraminifera (E. exigua and species diversity) between ~2°N and ~6°N along ~131°W has been generally established since ~130 ka. According to the modern relationship between the seasonality of primary production and seasonal ITCZ variations in the northern margin of the ITCZ, the latitudinal divergence of benthic foraminiferal fauna between ~2°N and ~6°N since ~130 ka appear to have been induced by more distinct variations in the seasonal movement of ITCZ.  相似文献   

Long-term variations in macrobenthic community diversity (species number) in the Chokchon macrotidal flat,Incheon, Korea     

Jae-Won Yoo  Hyun-Jung Lee  Jae-Sang Hong 《Ocean Science Journal》2016,51(3):435-445

We performed a time-series analysis of environmental variables and biological parameters to understand temporal variations in the macrobenthic community in the Chokchon macrotidal flats, Incheon, Korea. Bimonthly sampling of macrobenthos and sediments was conducted from May 1989 through November 2001. A decomposition method composed of seasonality, trends and cyclical variation was employed in this study. We focused on trends of the selected variables and assumed that those with positive or negative trends caused changes in biological parameters. Most variables showed strong seasonality (≥ 95% of the total variance). Significant positive trends (p < 0.0001) were observed in sea water temperature and sediment ignition loss. Macrobenthic biomass and species number also showed significant positive trends (p < 0.0001). Biomass indicated that the study area underwent eutrophication since the mid 1990s. A notable increase in species number occurred throughout the study period. The flattened temperature trend after 1994 and intensified eutrophication after the mid 1990s indicated that the species increase in the former period was in response to increasing temperature, while that in the latter period was caused by eutrophication. Although our study suggested an increasing trend in diversity, it is important to check for unexpected changes and establish monitoring programs to provide early warnings, especially in lower latitudes.  相似文献   

Isolation of <Emphasis Type="Italic">Bacillus cereus</Emphasis> from botanical soil and subsequent biodegradation of waste engine oil     

S. Bhurgri  F. N. Talpur  S. M. Nizamani  H. I. Afridi  M. A. Surhio  Muhammad Raza Shah  C. W. Bong 《International Journal of Environmental Science and Technology》2018,15(7):1453-1466

Waste engine oil causes a vital environmental pollution when it spill during change and transportation and products of waste engine oil causes lethal effects to the living systems. Thus, abiotic and biotic approaches are being extensively used for removal of waste engine oil pollution. Therefore in present study, waste engine oil degradation was accomplished by a new bacterial culture, isolated from the soil by an enrichment technique. Morphological, biochemical and gene sequence analysis revealed that isolate was Bacillus cereus. Subsequently, biodegradation potential of B. cereus for waste engine oil was studied. Experimental variables, such as pH, substrate concentration, inoculum size, temperature and time on the biodegradation, were checked in mineral salt medium. The biodegradation efficiency of B. cereus was determined by gravimetry, UV–visible spectrophotometry and gas chromatography. In addition, waste engine oil was also characterized by GC–MS and FTIR for its major constituents, which showed total 38 components in waste engine oil, including hopanes, benzopyrene, long-chain aliphatic hydrocarbons, dibenzothiophenes, biphenyl and their derivatives. Results of successive biodegradation indicated that B. cereus was capable to degrade 1% of waste engine oil with 98.6% degradation potential at pH 7 within 20 days. Hence, B. cereus presents an innovative tool for removing the engine oil from the contaminated area.  相似文献