Assessment of imposex in the common whelk, Buccinum undatum (L.) from the Eastern Scheldt, The Netherlands     

B.P. Mensink  C.C. ten Hallers-Tjabbes  J. Kralt  I.L. Freriks  J.P. Boon 《Marine environmental research》1996,41(4):315-325

Several cruises were carried out on the Eastern Scheldt between September 1992 and March 1995 to study the frequency and appearance of imposex in the common whelk, Buccinum undatum L. Incidences of imposex were always > 90%. For the first time several stages of imposex in Buccinum undatum are reported. The evolution of imposex in the whelk seems to follow a similar route as in Hinia reticulata belonging to the same superfamily (Buccinacea). Tissue organotin concentrations of animals collected in February 1995 showed the highest organotin concentrations in the digestive gland and lowest in the foot of the animals. Concentrations of phenyltin compounds (up to 625 ngSn/g DW) were much higher than those of butyltin compounds (up to 40 ngSn/g DW).  相似文献   

The expression of CYP1A,vitellogenin and zona radiata proteins in Atlantic salmon (Salmo salar) after oral dosing with two commercial PBDE flame retardant mixtures: absence of short-term responses     

Boon JP  van Zanden JJ  Lewis WE  Zegers BN  Goksøyr A  Arukwe A 《Marine environmental research》2002,54(3-5):719-724

The short-term effects of the commercial PBDE flame retardant mixtures Penta-BDE and cta-BDE on the expression of cytochrome P450 1A (CYP1A), vitellogenin (Vtg) and zona radiata proteins (Zrp) were investigated in juvenile salmon (Salmo salar). For this purpose, groups of fish were dosed twice (oral intake at days I and 4) with 10 and 50 mg/kg body weight of both commercial mixtures. The fishes were sacrificed at day 7 (n = 5 for each group) and 14 (n = 6 for each group), and blood, liver, fillet, and brain were collected. Blanks and positive controls were also part of the experiment. The expressions of Vtg, Zrp, and CYPIA were measured with several techniques (EROD, ELISA, Western, Northern and Slot Blot). The values in the groups of fish treated with Penta-BDE or Octa-BDE did not significantly differ from the reference group for any of the parameters tested. In contrast, the positive control groups treated with estradiol-17beta for Vtg and Zrp expression, and beta-naphthoflavone for CYP1A expression did show a significant response, indicating the potential sensitivity of the fishes for the parameters measured. Since the results of the chemical analyses showed concentrations of a number of PBDE congeners in liver, fillet, and brain that were about three orders of magnitude above those of fish from the North Sea, it is concluded that the short-term toxicity of both commercial PBDE mixtures for these endpoints was low.  相似文献   

Cytochrome P450 differences in normal and imposex-affected female whelk Buccinum undatum from the open North Sea     

Santos MM  ten Hallers-Tjabbes CC  Vieira N  Boon JP  Porte C 《Marine environmental research》2002,54(3-5):661-665

Normal and imposex-affected female Buccinum undatum were sampled from the open North Sea at three locations, one with low, and two with high shipping densities. Cytochrome P450 components and P450 aromatase activity were determined in the microsomal fractions isolated from pooled digestive gland/gonads. Cytochrome P450 aromatase activity was significantly higher (P < 0.05) in normal females collected in the low shipping density area (1,325 +/- 295 fmol/h/mg protein) than levels from imposex animals from a high shipping density area (620 +/- 287 fmol/h/mg protein). A negative correlation was found between aromatase activity and organotin body burden (r = -0.99). Levels of CYP450, cytochrome b5 and NADPH cytochrome c reductase activity did not show differences among groups. This is the first field evidence of depressed aromatase activity in imposex affected females, although additional research under laboratory controlled conditions is required to fully understand the mechanisms underlying the development of imposex in this species.  相似文献   

The adsorption of rhodamine on to suspended sediments     

Talbot  J. W.; Boon  Myrtle J. 《ICES Journal of Marine Science》1975,36(2):128-132

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Interannual variability of monsoons in Malaysia and its relationship with ENSO     

Boon-khean Cheang 《Journal of Earth System Science》1993,102(1):219-239

Interannual variations of the monsoons have been studied utilising homogeneous rainfall records of 41 years (1951–1991) from Malaysia and upper air data of stations in Asia, Australia and Western Pacific. Sources of upper air data are U.S. Department of Commerce and Kuala Lumpur Northern Winter Monsoon Activity Centre. Extreme wet and dry years have been identified and the influence of ENSO on Malaysian annual rainfall has been discussed. Influence of ENSO on the performance of northern summer and winter monsoons has also been studied from Malaysian rainfall data. Further, regional circulation patterns associated with El Nino and La Nina years have also been identified. No linear trend has been found in the annual rainfall of 16 stations in Malaysia. Most El Nino years are associated with below median and La Nina years with above median rainfall at most stations in Malaysia. ENSO has greater influence over East Malaysia than peninsular Malaysia. Interannual variability of rainfall with reference to ENSO conditions has been discussed in details. Also, circulation features have been identified to foresee El Nino/La Nina events.  相似文献   

A combined pyrolysis mass spectrometric and light microscopic study of peatified Calluna wood isolated from raised bog peat deposits     

Edwin van der Heijden  Jaap J. Boon 《Organic Geochemistry》1994,22(6)

Stem wood of the Angiosperm Calluna vulgaris (Scotch heather), isolated at different depths from a selection of raised bog peat deposits, was chemically characterized using in-source pyrolysis mass spectrometry (Py-MS) and Curie-point pyrolysis gas chromatography mass spectrometry (Py-GC-MS). Light microscopy was performed to relate mass spectrometric characteristics with anatomical features. Peatified wood samples, isolated from increasing depth show a gradual decrease in carbohydrate content. This decrease in anatomically reflected in a selective removal of secondary cell wall material from the fibre-tracheids and wood parenchyma. During prolonged peatification a selective removal of hemicellulose sugars is observed, while a part of the cellulose fraction is preserved. This highly resistant cellulose is mainly located in the secondary cell walls of the vessels. The lignin macromolecule is preserved, but a gradual decrease in syringyl to guaiacyl ratio (S/G) is observed during peatification. Because no increase in catechol and phenolic compounds is observed, we conclude that S/G shifts are due to removal the of syringyl-rich secondary cell wall material and the retention of guaiacyl-rich compound middle lamella. Small chemical changes in the lignin macromolecule involve shifts in oxygen substitutions on the aliphatic side chains of the methoxyphenolics and the occurrence of aromatic acids.  相似文献   

Book reviews     

John A. Couch  Michael T. Ledbetter  Gerald N. Smith  John D. Boon 《Estuaries and Coasts》1986,9(3):229-231

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The coordination number of ferrous ions in silicate glasses     

J. A. Boon  W. S. Fyfe 《Chemical Geology》1972,10(4):287-298

Mössbauer and optical absorption measurements on a number of silicate glasses show that most of the ferrous ions in these glasses are distributed over two types of octahedral sites. Less than 0.5% of all ferrous ions occupy tetrahedral sites. It is shown that the Bernal liquid model of random close packing does not apply to silicate glasses. Attention is drawn to the fact that measurements on silicate glasses cannot provide reliable information about coordination numbers in silicate liquids.  相似文献   

Complex adaptive blended learning for higher GIS education: A theory-driven pedagogy moving forward after the pandemic     

Yingwei Yan  Chen-Chieh Feng  Lewis Kwek Boon Leong 《Transactions in GIS》2023,27(5):1479-1502

None of the prior studies implementing blended learning (BL) for GIS education has explored pedagogical theories to support BL design, and none coupled blended GIS learning practice with theories. Based on the theoretical framework of complex adaptive blended learning system (CABLS), this article presents a holistic and systematic view of BL for higher GIS education (termed as CABLS-GIS), where its key components are tightly integrated as an integral whole. The framework was implemented for an introductory-level GIS course to empirically evaluate the effectiveness of a BL design from students' perspectives. Most students involved in the implementation agreed that the BL enhanced their learning outcomes. They were mostly positive about the BL and motivated to use the BL materials. Incorporating more BL materials, especially practical ones, and active learning activities were suggested by them. A few negative comments about the BL suggested a thorough consideration of individual learners' characteristics.  相似文献   

Disaster resilience in a flood-impacted rural Australian town     

Helen J. Boon 《Natural Hazards》2014,71(1):683-701

This paper reports exploratory research conducted in a flood-impacted rural Australian town to identify the factors which residents perceived as supporting community resilience to disaster. There is a gap in this research area centred in the Australian disaster context. Since Australia is predicted to be highly impacted by the effects of climate change in the form of an increased incidence of flooding, an urgent need exists to examine the factors that confer resilience to disaster-impacted localities to inform suitable disaster mitigation and adaptation policies for the future. Because of the complexity of community resilience and its interrelationship with individual resilience, a multi-method approach was used: a demographic study to assess community stability and functioning before and after the flood disaster, focus group interviews to obtain from community members their views on what supported them and their community resilience and a survey to generalise the interview findings. Our operating hypothesis was that individuals remaining in the town post-flood were likely to be resilient to the flood disaster. The demographic study results pointed to a resilient community after the floods as they reflected stability in population numbers and socio-economic indicators. The interviews and survey showed that individual resilience was promoted by social connectedness and a sense of place, a factor that was also negatively linked to the desire to relocate from the community. The use of structural equation modelling of our results provided verification of prior research findings about the role of sense of place in supporting individuals’ resilience. Results are discussed in the context of future climate change adaptation policy.  相似文献