排序方式： 共有8条查询结果，搜索用时 437 毫秒
1
1.
Jennifer Vandenhecke Matthieu Waeles Jean-Yves Cabon Cédric Garnier Ricardo D. Riso 《Estuarine, Coastal and Shelf Science》2010
Over this one-year study, the variations of inorganic As species were examined monthly along the salinity gradient of the Penzé estuary (NW France) in relation with different biogeochemical parameters. In most cases, dissolved As exhibited a non-conservative behaviour which resulted from the competition between two major processes. In the upstream section of the estuary, a strong input of both total inorganic As and As(III) occurred. Then, the removal of the same species, under precipitation of iron oxides/oxyhydroxides, was observed in the low-salinity range (S < 10). Using our experimental data, the fluxes of the various As species were estimated for the first time in estuarine waters. Inputs from the river were mainly constituted of particulate As (∼70%). Conversely, dissolved species were predominant in the net fluxes (∼65%) and As(III) accounted for ∼15% of the dissolved net flux. 相似文献
2.
Thallium(I) has been added to estuarine sediment suspended in various natural and artificial aqueous samples in order to examine its reactivity under simulated estuarine conditions. In river water and sea water, adsorption of Tl to sediment was so rapid that a period of desorption-relaxation succeeded instantaneous adsorption. Entire time-courses could not be fitted with a conventional kinetic model, but pseudo-first-order forward and reverse rate constants of 0.0044 and 0.30 h−1, respectively, were derived for river water by omitting measurements defining the adsorption “overshoot” observed at the onset of the experiment. The extent of adsorption after a 16 h equilibration period was considerably greater in river water than in sea water, and displayed a quasi-linear increase with increasing pH over the range 2-9 in the former but no clear dependence on pH in the latter. A logarithmic reduction in the sediment-water distribution coefficient, KD, was observed on estuarine mixing from river water to sea water. Experiments conducted in electrolyte solutions coupled with inorganic equilibrium speciation modeling revealed that the effect was the combined result of a reduction in the activity of Tl+, an increase in the proportion of TlCl0 and increasing competition for adsorption sites from K+ with an increase in salinity. Overall, there was little experimental evidence for either the oxidation of Tl+ or its complexation by dissolved organic matter. The findings of the investigation are discussed in terms of the likely behavior of Tl in estuaries. 相似文献
3.
新疆东准噶尔石炭纪火山机构类型与时限 总被引：10，自引：2，他引：8
东准噶尔卡拉麦里大气田的主要储层是石炭纪火山岩,石炭纪古火山机构的样式与组合特征,与火山岩储层展布关系密切。野外调查表明,隐爆角砾岩是东准噶尔石炭纪古火山机构最常见的标志之一。东准噶尔石炭纪古火山机构类型主要有中心式、裂隙式和裂隙-中心式等样式。中心式火山机构以大石头层状火山、柯克巴斯套锥状火山最为典型;巴塔玛依内山附近沿断裂分布的带状火山岩具有裂隙式喷发的特征;东黑山火山具有火山口串珠状排列特征,是裂隙-中心式喷发的产物。大石头地区原缪林托凯陶山组火山岩的锆石SHRIMP U-Pb年龄为345.6±7.1 Ma,而已知巴塔玛依内山组火山岩年龄是350.0±6.3Ma,因此东准噶尔火山活动的主要时期是早石炭世。 相似文献
4.
郯庐断裂带北段构造特征及构造演化序列 总被引：10，自引：3，他引：7
根据大量野外地质调查和盆地地震资料分析,认为郯庐断裂北段在中-新生代发生多期不同性质的活动,形成各具特色的构造变形现象。密山县知一镇敦密断裂韧性剪切带具有左旋走滑特征,其中黑云母~(40)Ar/~(36)Ar-~(39)Ar/~(36)Ar等时线年龄为161±3Ma,是郯庐断裂带被利用发生第二期左旋走滑运动并向北扩展到中国东北-俄罗斯远东地区的产物。四平市叶赫乡佳伊断裂带中负花状断裂形成于早白垩世早中期,是郯庐断裂北段在早白垩世遭受左旋走滑-拉张作用的典型代表。四平市石岭镇佳伊断裂大型走滑-逆冲断褶带、桦甸县敦密断裂"逆地堑"、沈阳-哈尔滨逆冲断裂形成于晚白垩世嫩江运动-晚白垩世末期,这一时期脆性右旋走滑-逆冲事件规模大,影响范围广,导致整个郯庐断裂北段遭受到强烈改造。佳伊断裂带和敦密断裂带中古近纪盆地在横剖面上呈不对称地堑,并且不对称地堑沿断裂带走向发生断、超方向左右变位,是郯庐断裂带北段在古近纪时受右旋走滑、伸展双重机制控制的产物。根据郯庐断裂带北段中-新生代不同地质时期变形特征,建立了郯庐断裂北段构造演化序列。即郯庐断裂北段构造演化分为左旋韧性剪切(J_2末期)、左旋张扭(K_1早中期)、右旋压扭(K_2晚期-末期)、右旋走滑断陷(E)和构造反转(E_3末期)五个阶段。其演化历史主要受控于环太平洋构造域的构造作用。 相似文献
5.
Jaffrennou C Giamarchi P Cabon JY Stephan L Burel-Deschamps L Bautin F Thomas A Dumont J Le Floch S 《Marine pollution bulletin》2007,54(12):1932-1939
Coal is currently becoming an increasingly interesting fossil energy resource and that is the reason why its maritime transport, and hence the risk of collier accidents, increase. In this work, the environmental impact of an accidental coal immersion at sea is studied: the physicochemical effects are estimated using innovative experimental setups – a laboratory seawater canal called “polludrome” is used to evaluate the behaviour of coal particles submitted to a seawater flow, and a specifically designed tub is used to study the physicochemical consequences induced when coal is introduced into continuously renewed seawater. When coal is introduced into seawater, the most easily visible consequences are physical: fine coal particles reduce the daylight penetration up to 100% and move along with the flow, and coal chunks accumulate on the floor. Chemical effects are also measured: humic matters are dissolved from coal into seawater (up to 2 mg L−1), but no release of polycyclic aromatic hydrocarbons is evidenced. Some inorganic compounds are dissolved, among which manganese, whose concentrations can reach 1 μg L−1. Fortunately, the results show that the environmental impact of this type of accident would remain limited. 相似文献
6.
This study examined the potential metal pollution induced by the accidental spill of different acids into seawater. The acids sink to the bottom according to their densities and subsequently react with marine sediments. The acids selected for this study were acetic, hydrochloric, nitric, sulfuric, and phosphoric acids; the metallic elements selected were Cr, Cu, Fe, Mn, Pb and Zn. The sediment was collected in Brest Harbour. The percentages of metals released from this sediment in the presence of various concentrations of acids in seawater were important; concentrations of approximately 7 mg L−1 for Mn and 60 mg L−1 for Zn were observed under our experimental conditions. We also examined the rate of release of these metals from the sediment into the seawater in the presence of the different acids and under different experimental conditions. We found that most of the metallic elements were released from the sediments into the seawater during the first fifteen minutes of exposure. After this time, a high degree of pollution was induced if acids leached into seawater were not rapidly diluted. 相似文献
7.
Corinne Tarits Robin W. Renaut Jean‐Jacques Tiercelin Alain Le Hriss Jo Cotten Jean‐Yves Cabon 《水文研究》2006,20(9):2027-2055
Lake Baringo, a freshwater lake in the central Kenya Rift Valley, is fed by perennial and ephemeral rivers, direct rainfall, and hot springs on Ol Kokwe Island near the centre of the lake. The lake has no surface outlet, but despite high evaporation rates it maintains dilute waters by subsurface seepage through permeable sediments and faulted lavas. New geochemical analyses (major ions, trace elements) of the river, lake, and hot spring waters and the suspended sediments have been made to determine the main controls of lake water quality. The results show that evaporative concentration and the binary mixing between two end members (rivers and thermal waters) can explain the hydrochemistry of the lake waters. Two zones are recognized from water composition. The southern part of the lake near sites of perennial river inflow is weakly influenced by evaporation, has low total dissolved species (TDS), and has a seasonally variable load of mainly detrital suspended sediments. In contrast, waters of the northern part of the lake show evidence for strong evaporation (TDS of up to eight times inflow). Authigenic clay minerals and calcite may be precipitating from those more concentrated fluids. The subaerial hot‐spring waters have a distinctive chemistry and are enriched in some elements that are also present in the lake water. Comparison of the chemical composition of the inflowing surface waters and lake water shows (1) an enrichment of some species (HCO3?, Cl, SO42?, F, Na, B, V, Cr, As, Mo, Ba and U) in the lake, (2) a depletion in SiO2 in the lake, and (3) a possible hydrothermal origin for most F. The rare earth element distribution and the F/Cl and Na/Cl ratios give valuable information on the rate of mixing of the river and hydrothermal fluids in the lake water. Calculations imply that thermal fluids may be seeping upward locally into the lake through grid‐faulted lavas, particularly south of Ol Kokwe Island. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
8.
Matthieu Waeles Ricardo D. Riso Jean-Yves Cabon Jean-François Maguer Stéphane L'Helguen 《Estuarine, Coastal and Shelf Science》2009
Dissolved cadmium and copper species were measured in the Loire estuary and the North Biscay Bay continental shelf (France) in spring 2002. Metal behaviours along the salinity gradient, metal fluxes from the Loire system and surface distributions on the continental shelf were described and compared with the ones obtained at a period of higher discharge (i.e., winter 2001). Vertical distributions at different stations were also examined with the aim to assess whether the Loire inputs affect the Cu and Cd speciation over the continental shelf. In the Loire estuary, different metal behaviours were observed from winter. Cu and its various species mostly followed a theoretical dilution line whereas a Cd addition composed of chloro- and organic complexes was observed. According to our estimations, the Cu flux was composed, as in winter, of 40% hydrophobic organic complexes. On the other hand, Cd organic complexes accounted for less in the total dissolved metal flux than they did in winter (55 and 78% for spring and winter, respectively). On the continental shelf, a C18Cu-to-TDCu ratio of 40% was observed in the stratified area under Loire influence. For Cd, the organic fraction was relatively important in the surface waters near the mouth of the estuary and decreased deeper and seaward. Thus, the Cu and Cd speciation on the North Biscay Bay continental shelf are firstly determined by the extent of the estuarine plume. Beyond the estuarine influence, biological processes appeared to be the origin of the observed variations. 相似文献
1