High-resolution H i and radio continuum observations of the SNR G290.1−0.8     

Estela M. Reynoso †  Simon Johnston  Anne J. Green  Bärbel S. Koribalski 《Monthly notices of the Royal Astronomical Society》2006,369(1):416-424

We have observed the supernova remnant (SNR) G290.1−0.8 in the 21-cm H  i line and the 20-cm radio continuum using the Australia Telescope Compact Array (ATCA). The H  i data were combined with data from the Southern Galactic Plane Survey to recover the shortest spatial frequencies. In contrast, H  i absorption was analysed by filtering extended H  i emission, with spatial frequencies shorter than 1.1 kλ. The low-resolution ATCA radio continuum image of the remnant shows considerable internal structure, resembling a network of filaments across its 13-arcmin diameter. A high-resolution ATCA radio continuum image was also constructed to study the small-scale structure in the SNR. It shows that there are no structures smaller than ∼17 arcsec, except perhaps for a bright knot to the south, which is probably an unrelated object. The H  i absorption study shows that the gas distribution and kinematics in front of SNR G290.1−0.8 are complex. We estimate that the SNR probably lies in the Carina arm, at a distance 7 (±1) kpc. In addition, we have studied nearby sources in the observed field using archival multiwavelength data to determine their characteristics.  相似文献   

The Baby's Gone: On Regional Polarization In British Elections     

R. J. Johnston  P. J. Taylor 《The Professional geographer》1987,39(1):62-64

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Surface complexation of U(VI) on goethite (α-FeOOH)     

David M. Sherman  Caroline L. Peacock  Christopher G. Hubbard 《Geochimica et cosmochimica acta》2008,72(2):298-310

Sorption of U(VI) to goethite is a fundamental control on the mobility of uranium in soil and groundwater. Here, we investigated the sorption of U on goethite using EXAFS spectroscopy, batch sorption experiments and DFT calculations of the energetics and structures of possible surface complexes. Based on EXAFS spectra, it has previously been proposed that U(VI), as the uranyl cation , sorbs to Fe oxide hydroxide phases by forming a bidentate edge-sharing (E2) surface complex, >Fe(OH)₂UO₂(H₂O)_n. Here, we argue that this complex alone cannot account for the sorption capacity of goethite (α-FeOOH). Moreover, we show that all of the EXAFS signal attributed to the E2 complex can be accounted for by multiple scattering. We propose that the dominant surface complex in CO₂-free systems is a bidentate corner-sharing (C2) complex, (>FeOH)₂UO₂(H₂O)₃ which can form on the dominant {101} surface. However, in the presence of CO₂, we find an enhancement of UO₂ sorption at low pH and attribute this to a (>FeO)CO₂UO₂ ternary complex. With increasing pH, U(VI) desorbs by the formation of aqueous carbonate and hydroxyl complexes. However, this desorption is preceded by the formation of a second ternary surface complex (>FeOH)₂UO₂CO₃. The three proposed surface complexes, (>FeOH)₂UO₂(H₂O)₃, >FeOCO₂UO₂, and (>FeOH)₂UO₂CO₃ are consistent with EXAFS spectra. Using these complexes, we developed a surface complexation model for U on goethite with a 1-pK model for surface protonation, an extended Stern model for surface electrostatics and inclusion of all known UO₂-OH-CO₃ aqueous complexes in the current thermodynamic database. The model gives an excellent fit to our sorption experiments done in both ambient and reduced CO₂ environments at surface loadings of 0.02-2.0 wt% U.  相似文献   

The composition and crystallinity of the near-surface regions of weathered alkali feldspars     

Martin R. Lee  Mark E. Hodson  Maureen MacKenzie  Caroline L. Smith 《Geochimica et cosmochimica acta》2008,72(20):4962-4975

Our ability to identify thin non-stoichiometric and amorphous layers beneath mineral surfaces has been tested by undertaking X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM) work on alkali feldspars from pH 1 dissolution experiments. The outcomes of this work were used to help interpret XPS and TEM results from alkali feldspars weathered for <10,000 years in soils overlying the Shap Granite (north-west England). The chemistry of effluent solutions indicates that silica-rich layers a few nanometers in thickness formed during the pH 1 experiments. These layers can be successfully identified by XPS and have lower Al/Si, Na/Si, K/Si and Ca/Si values than the outermost ∼9 nm of unweathered controls. Development of Al-Si non-stoichiometry is coupled with loss of crystal structure to produce amorphous layers that are identifiable by TEM where >∼2.5 nm thick, whereas the crystallinity of albite is retained despite leaching of Na to depths of tens to hundreds on nanometers. Integration of XPS data over the outermost 6-9 nm of naturally weathered Shap feldspars shows that they have stoichiometric Al/Si and K/Si ratios, which is consistent with findings of previous TEM work on the same material that they lack amorphous layers. There is some XPS evidence for loss of K from the outermost couple of nanometers of Shap orthoclase, and the possibility of leaching of Na from albite to greater depths cannot be excluded using the XPS or TEM results. This study demonstrates that the leached layer model, as formulated from laboratory experiments, is inapplicable to the weathering of alkali feldspars within acidic soils, which is an essentially stoichiometric reaction.  相似文献   

Pollutants and their ecotoxicological significance: H.W. Nürnberg (Editor). Wiley-Interscience, New York, 1985, xiv + 515 pp., £49.50     

R. Johnston 《Marine Chemistry》1986,19(4)

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Monitoring fish movement patterns in a reservoir using horizontally scanning split-beam techniques     

Steig  Tracey W.; Johnston  Samuel V. 《ICES Journal of Marine Science》1996,53(2):435-441

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An evaluation of temperature scales for silica diagenesis in diatomaceous sequences including a new approach based on the Miocene Monterey Formation,California     

Margaret A. Keller  Caroline M. Isaacs 《Geo-Marine Letters》1985,5(1):31-35

Geologic relations indicate that silica phases transformed in the Monterey Formation in two zones that persist over a narrow depth/temperature range and do not stratigraphically overlap. The wide and overlapping range of reported temperatures of these transformations is mainly a result of the many uncertainties inherent in the different methods used to estimate temperature and does not indicate that phases transform throughout these ranges. Our approach to a reliable temperature scale for silica diagenesis combines as empirical zonation of silica phases with temperature calibration from a sequence at maximum temperature and depth of burial.  相似文献   

Sea-level, sediment supply and coastal changes: Examples from the coast of Ireland     

R.W.G. Carter  T.W. Johnston  J. McKenna  J.D. Orford 《Progress in Oceanography》1987,18(1-4)

Sediment supply and pre-existing shoreline morphology are crucial factors in controlling coastal changes due to sea-level rise. Using examples from both southeast and northeast Ireland, it can be shown that sea-level change may trigger a sequence of events which leads to both static and dynamic shoreline equilibrium. Cliff erosion and longshore sediment movement in east Co. Wexford has led to injection of sediment onto the shelf, and the growth, under both wave and tide regimes, of linear offshore shoals. These shoals now control the pattern of shoreline erosion and provide a template for possible stepwise evolution of the coast under any future sea-level rise. In contrast, the nearby coast of south Co. Wexford comprises a series of coarse clastic barriers moving monotonously onshore, via overwash processes. Here the behavior of the barrier is conditioned by the antecedent morphology of both the beach face and stream outlet bedforms. Finally, the rock platform coast of Co. Antrim presents a far more resistant shoreline to incident marine processes, yet even here there is strong evidence of present process control over so-called ‘raised’ platforms and embayments. It is concluded that coastal sediment supply and dynamics, together with coastal morphology and its interaction with waves, present a far more complex variety of sea-level indicators than is normally acknowledged.  相似文献   

Land-based activities: what remains to be done     

Caroline Williams  PhD candidate  Bruce Davis  Leader 《Ocean & Coastal Management》1995,29(1-3)

The Global Programme of Action for the Protection of the Marine Environment from Land-based Activities (GPA) represents an ambitious attempt to make the leap between the rhetoric of protecting and preserving the marine environment and action. With degradation of the marine environment from land based activities posing one of the most serious threats to the quality and productivity of the coastal and marine environment, the GPA can only be viewed as a milestone rather than a destination, as so much work remains to be done in this field.States supporting the GPA are entering the most challenging phase of the program, that of implementation. But the international community in taking on this challenge is not without a few signposts. The failure of the Montreal Guidelines to be implemented, provides States with many important lessons. This paper suggests that if the GPA is to have an impact on the complex problem of land-based activities then several tasks need to be grappled with. Substantial financial support needs to be generated, a proactive and cooperative secretariat established and the nexus between the GPA and United Nations Environment Programme Regional Seas Programme examined. The importance of people and training to the capacity building process needs to be recognised and a wider variety of stakeholders engaged in the follow up phase. Pivotal to the aforementioned is the need to generate political will to address the problem, without which the GPA will become yet another dusty volume on the bookshelf.  相似文献   

Abundance versus rates of accumulation in fine-grained strata of the Miocene Santa Barbara Basin,California     

Caroline M. Isaacs 《Geo-Marine Letters》1985,5(1):25-30

Although best known as a deposit rich in silica and organic matter, the Miocene Monterey Formation actually had long-term rates of silica and organic Matter accumulation equal to or lower than values in the underlying and overlying detritus-rich formations in the Santa Barbara coastal area. The factor Mainly influencing the composition of the Monterey Formation in this area was the slow accumulation of terrigenous debris. In contrast, with greater than average silica abundance within the Monterey Formation probably resulted from rapid short-term silica accumulation (of hundreds to tens of thousands years duration) rather than from especially slow accumulation of diluting debris.  相似文献