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The chemical similarity of magnetite-bearing amphibolites from the Yangyang iron mine in Korea to mixtures of pelite and limestone or dolomite is consistently indicated by all the available chemical data. The chemical variation trends of the rocks were compared with ortho-(discordant-) and massive amphibolites from the Gyeonggi metamorphic complex, Korea. Samples of nine amphibolites from the Yangyang mine, and two ortho-amphibolites and six massive amphibolites from the Gyeonggi metamorphic complex were analyzed for twenty-two elements by wet-chemical, X-ray fluorescence and emission-spectroscopic methods. Trace-element analyses of the magnetites from the Yangyang mine were compared to those from a deposit of magmatic-segregation type and from six Precambrian sedimentary magnetite deposits found elsewhere in Korea. It is suggested that the magnetite ore may have been derived by metamorphism of iron-rich sediment originally deposited in an environment of pelite-carbonate sedimentation.  相似文献   
2.
Origin of Mesozoic gold mineralization in South Korea   总被引:6,自引:0,他引:6  
Seon-Gyu  Choi  Sung-Tack  Kwon  Jin-Han  Ree  Chil-Sup  So  Sang Joon  Pak 《Island Arc》2005,14(2):102-114
Abstract   The Mesozoic gold–silver deposits in South Korea are closely associated with the Mesozoic granitoids. The Jurassic gold–silver deposits can be distinguished from the Cretaceous ones in terms of occurrence, alteration style, gold fineness, associated mineral assemblage, fluid inclusion and stable isotopic compositions. The Jurassic deposits were formed in mesozonal environments related to deep-seated granitoids, whereas the Cretaceous ones were formed in epizonal environments related to shallow-level granitoids. The Jurassic auriferous deposits (about 165–145 Ma) show fluid characteristics typical of an orogenic-type gold deposit, and were probably generated in a compressional regime caused by an orthogonal convergence of the Izanagi oceanic plate into the Asiatic margin. However, strike-slip faults and caldera-related fractures, together with subvolcanic to volcanic activity, may have played an important role in the formation of Cretaceous gold–silver lode deposits (about 110–45 Ma) under a continental arc setting.  相似文献   
3.
The Wolyu mine is one of the largest vein-type gold-silver-bearing epithermal systems in the Youngdong district and is the first gold-silver deposit in Korea found to contain significant germanium, in the form of argyrodite (Ag8GeS6). Mineralized veins (78.9 ± 1.2 Ma) crosscutting Late Cretaceous hostrock tuff and quartz porphyry (81.5 ± 1.8 Ma) consist of three stages of quartz and carbonates, the first of which contains pyrite, basemetal sulfides and Au-Ag-minerals. Stage I Au-Ag-Ge-mineralized veins show a systematic variation of mineral assemblage with time: (1) quartz + pyrite; (2) quartz + pyrite + sphalerite + electrum + argentite; (3) carbonate + quartz + sphalerite + electrum + argentite; (4) carbonate + native silver + argentite + Ag-sulfosalts + argyrodite + sphalerite. Calculated values of temperature and sulfur activity are: assemblage (1), 360-280°C and 10–7-10–10; (2), 280-210°C and 10–10-10–14; (3), 210-180°C and 10–14-10–16; (4), 180-155°C and 10–17-10–18. These data, the frequent association of gold with sulfides, and the abundance of pyrite in alteration zones indicate that decreasing sulfur activity and cooling were important in triggering gold deposition. Hydrogen and oxygen isotope compositions of ore fluids display a systematic variation with increasing time. Within the main Ag-Au-Ge mineralization, D and 18O values decrease with the transition from quartz to carbonate deposition (from -78 and –2.8% to –90 and –8.7%., respectively), indicating increasing involvement (mixing) of less evolved meteoric water which resulted in progressive cooling and dilution of ore fluids in the shallow ( 370–600 m) Wolyu epithermal system.  相似文献   
4.
Abstract

In order to evaluate groundwater quality and geochemical reactions arising from mixing between seawater and dilute groundwater, we performed a hydrochemical investigation of alluvial groundwater in a limestone-rich coastal area of eastern South Korea. Two sites were chosen for comparison: an upstream site and a downstream site. Data of major ion chemistry and ratios of oxygen–hydrogen isotopes (δ18O, δD) revealed different major sources of groundwater salinity: recharge by sea-spray-affected precipitation in the upstream site, and seawater intrusion and diffusion zone fluctuation in the downstream site. The results of geochemical modelling showed that Ca2+ enrichment in the downstream area is caused by calcite dissolution enhanced by the ionic strength increase, as a result of seawater–groundwater mixing under open system conditions with a constant PCO2 value (about 10?1.5 atm). The results show that, for coastal alluvial groundwater residing on limestone, significant hydrochemical change (especially increased hardness) due to calcite dissolution enhanced by seawater mixing should be taken into account for better groundwater management. This process can be effectively evaluated using geochemical modelling.

Editor D. Koutsoyiannis; Associate editor Y. Guttman

Citation Chae, G.-T., Yun, S.-T., Yun, S.-M., Kim, K.-H., and So, C.-S., 2012. Seawater–freshwater mixing and resulting calcite dissolution: an example from a coastal alluvial aquifer in eastern South Korea. Hydrological Sciences Journal, 57 (8),1–12.  相似文献   
5.
Mesothermal gold mineralization at the Samdong mine (5.5–13.5 g/ton Au), Youngdong mining district, is situated in massive quartz veins up to 1.2 m wide which fill fault fractures within upper amphibolite to epidote-amphibolite facies, Precambrian-banded biotite gneiss. The veins are mineralogically simple, consisting of iron- and base-metal sulfides and electrum, and are associated with weak hydrothermal alteration zones (<0.5 m wide) characterized by silicification and sericitization. Fluid inclusion data and equilibrium thermodynamic interpretation of mineral assemblages indicate that the quartz veins were formed at temperatures between 425 and 190°C from relatively dilute aqueous fluids (4.5–13.8 wt. % equiv NaCl) containing variable amounts of CO2 and CH4. Evidence of fluid unmixing (CO2 effervescence) during the early vein formation indicates approximate pressures of 1.3–1.9 kbars, corresponding to minimum depths of 5–7 km under a purely lithostatic pressure regime. Gold deposition occurred mainly at temperatures between 345 and 240 °C, likely due to decreases in sulfur activity accompanying fluid unmixing. The 34S values of sulfide minerals (-3.0 to 5.3 ), and the measured and calculated O-H isotope compositions of ore fluids (18O = 5.7 to 7.6; = –74 to –80) indicate that mesothermal gold mineralization at the Samdong mine may have formed from dominantly magmatic hydrothermal fluids, possibly related to intrusion of the nearby ilmenite-series, Kimcheon Granite of Late Jurassic age.  相似文献   
6.
The Taebaek Pb-Zn(-Ag) deposit of the Yeonhwa I mine, Republic of Korea, occurs in a broadly folded and reverse-faulted terrain of Paleozoic sedimentary rocks: the Taebaeksan basin. The orebodies consist of several thin tabular orebodies of hydrothermal replacement type where they are hosted by carbonate rocks. The Pb-Zn(-Ag) mineralization can be divided into four distinct stages based upon the mode of occurrence of ore minerals, ore textural relationships and their composition. Based on temperatures inferred from arsenopyrite compositions by means of electron microprobe and fluid inclusions, the estimated temperatures for the stages I, II, III and IV reach 330 to 350 °C, 270 to 340 °C, 230 to 250 °C, and <220 °C, respectively. The sulphur activity (atm) of ore formation at the Taebaek deposit was estimated for each stage as 10–11 to 10–11.5, 10–9.5 to 10–13, 10–13.5 to 10–15, and <10–15, respectively. Even though application of sphalerite geobarometry is problematic because of the absence of good mineral assemblages, sphalerite coexisting with pyrite but not with pyrrhotite was used to estimate the minimum mineralization pressure (about 1 kbar).  相似文献   
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