Hostrocks to the stratabound iron-formation-hosted Starra gold-copper deposit,Australia     

G. J. Davidson 《Mineralium Deposita》1994,29(3):237-249

This paper documents the timing, geochemistry and possible origin of sodium enrichment associated with Proterozoic iron formation-hosted copper-gold ore lenses at the Starra deposit, Australia. The ore lenses are immediately underlain by variably sheared albitemagnetite-hematite-pyrite-bearing rocks, and overlain by mainly unaltered, less-sheared, meta-sediments. Evidence indicating that albite was abundant prior to deformation, and also prior to the main hydrothermal addition of Fe, S, Cu and Au, includes (1) regional albite development at this stratigraphic level; (2) alteration of albite by ore-related sericite; and (3) inclusion of unfoliated inclusions of albite and hematite in ore-related pyrite. Nevertheless, albite also developed around dolerites and within hangingwall shears during metamorphism and deformation. Least altered albite footwall rocks have SiO₂ (67.31–73.13 wt.%), Al₂O₃(9.89–12.51 wt.%), total alkali elements (6.40–9.43 wt.%) and HFS elements (e.g., Zr = 179–275 ppm; Ti/Zr = 7.6–14.1) comparable with felsic volcanics, but have high relative Na₂O contents (5.08–5.81 wt. %), and variable to high Na₂O/K₂O ratios (0.05–68.37). An episode of alkali alteration by high-Na fluids prior to the ore-related alteration is postulated to account for sodic compositions, after chemical consideration of the alternatives (1) arkosic sediments; (2) trondhjemitic volcaniclastics; and (3) Na-metasomatism of Staveley Formation sediments. During the most intense ore-alteration, isocon analysis indicates a density increase of 23% compared to the least altered albitised hostrocks. Cu, Fe, Au, Sn, W, Zn, K, Ba and Rb were enriched during the mineralising process, whereas Mn, Ca, Si, Nb and Zr were lost, and Al, Ti and Y were not changed (and were used to define the isocon). The loss of some high field strength elements during this alteration indicates that igneous rock classification diagrams based on immobile element ratios should be used with caution for albitemuscovite magnetite-pyrite assemblages associated with iron formation-hosted copper-gold deposits. Zircon was partially soluble, whereas titanium oxides were probably stable in the saline, high temperature (260°–380 °C), acid (pH = 3.9–6.0) fluids envisaged for ore-related alteration.  相似文献   

Sm−Nd and Pb isotopic study of mafic rocks associated with early Proterozoic continental rifting: the Peröpohja schist belt in northern Finland     

Hannu Huhma  Robert A. Cliff  Vesa Perttunen  Matti Sakko 《Contributions to Mineralogy and Petrology》1990,104(3):369-379

The Peräpohja schist belt in northern Finland rests unconformably on Archaean granitoids, and marks the early stages of Proterozoic crustal evolution in the Fennoscandian (Baltic) shield. 2440 Ma old layered mafic intrusions predate the supracrustal , and ca. 2200 Ma old sills of the gabbro-wehrlite association intrude the lowest quartzites and volcanics (Runkaus) of the sequence. The Sm-Nd mineral isochron of the Penikat layered intrusion gives an age of 2410±64 Ma. The initial _Nd-values of the Penikat intrusion (_Nd(2440) = –1.6) and the Runkausvaara sill (_Nd(2200) 0) suggest that these mafic magmas were contaminated by older crustal material. The Sm-Nd and Pb isotopic results on the 2.44–2.2 Ga old Runkaus volcanics indicate mobility of Pb, fractionation of Sm/Nd during late greenschist facies metamorphism, and crustal contamination. The Pb-Pb data provide an age of 1972±80 Ma with a high initial ²⁰⁷Pb/²⁰⁴Pb ratio (₁ = 8.49), while scattered Sm-Nd data result in an imprecise age of 2330±180 Ma, with an initial _Nd-value of about zero. Secondary titanite gives an U-Pb age of ca. 2250 Ma. The Jouttiaapa basalts, in contrast, ascended from the mantle without interaction with older crust. These LREE depleted tholeiites mark a break in continental sedimentation, and yield a Sm-Nd age of 2090±70 Ma. Their initial _Nd = + 4.2 ±0.5 implies that the subcontinental early Proterozoic mantle had been depleted in LREE for a long period of time. The first lava flows are strongly depleted in LREE, suggesting that their source was significantly more depleted than the source of mid-ocean ridge basalts today.  相似文献   

The transition from peraluminous to peralkaline granitic melts: Evidence from melt inclusions and accessory minerals     

R. Thomas  J.D. Webster  D. Rhede  W. Seifert  K. Rickers  H.-J. Frster  W. Heinrich  P. Davidson 《Lithos》2006,91(1-4):137-149

Fractional crystallization of peraluminous F- and H₂O-rich granite magmas progressively enriches the remaining melt with volatiles. We show that, at saturation, the melt may separate into two immiscible conjugate melt fractions, one of the fractions shows increasing peraluminosity and the other increasing peralkalinity. These melt fractions also fractionate the incompatible elements to significantly different degrees. Coexisting melt fractions have differing chemical and physical properties and, due to their high density and viscosity contrasts, they will tend to separate readily from each other. Once separated, each melt fraction evolves independently in response to changing T/P/X conditions and further immiscibility events may occur, each generating its own conjugate pair of melt fractions. The strongly peralkaline melt fractions in particular are very reactive and commonly react until equilibrium is attained. Consequently, the peralkaline melt fraction is commonly preserved only in the isolated melt and mineral inclusions.

We demonstrate that the differences between melt fractions that can be seen most clearly in differing melt inclusion compositions are also visible in the composition of the resulting ore-forming and accessory minerals, and are visible on scales from a few micrometers to hundreds of meters.  相似文献   

Origin of fluids in iron oxide–copper–gold deposits: constraints from δ 37Cl, 87Sr/86Sri and Cl/Br     

Massimo Chiaradia  Dave Banks  Robert Cliff  Robert Marschik  Antoine de Haller 《Mineralium Deposita》2006,41(6):565-573

The origin of the hypersaline fluids (magmatic or basinal brine?), associated with iron oxide (Cu–U–Au–REE) deposits, is controversial. We report the first chlorine and strontium isotope data combined with Cl/Br ratios of fluid inclusions from selected iron oxide–copper–gold (IOCG) deposits (Candelaria, Raúl–Condestable, Sossego), a deposit considered to represent a magmatic end member of the IOCG class of deposit (Gameleira), and a magnetite–apatite deposit (El Romeral) from South America. Our data indicate mixing of a high δ ³⁷Cl magmatic fluid with near 0‰ δ ³⁷Cl basinal brines in the Candelaria, Raúl–Condestable, and Sossego IOCG deposits and leaching of a few weight percent of evaporites by magmatic-hydrothermal (?) fluids at Gameleira and El Romeral. The Sr isotopic composition of the inclusion fluids of Candelaria, Raúl–Condestable, and El Romeral confirms the presence of a non-magmatic fluid component in these deposits. The heavy chlorine isotope signatures of fluids from the IOCG deposits (Candelaria, Raúl–Condestable, Sossego), reflecting the magmatic-hydrothermal component of these fluids, contrast with the near 0‰ δ ³⁷Cl values of porphyry copper fluids known from the literature. The heavy chlorine isotope compositions of fluids of the investigated IOCG deposits may indicate a prevailing mantle Cl component in contrast to porphyry copper fluids, an argument also supported by Os isotopes, or could result from differential Cl isotope fractionation processes (e.g. phase separation) in fluids of IOCG and porphyry Cu deposits.  相似文献   

Effects of melt viscosity and silica activity on the rate and mechanism of quartz dissolution in melts of the CMAS and CAS systems     

Cliff S. J. Shaw 《Contributions to Mineralogy and Petrology》2006,151(6):665-680

The dissolution rate of quartz in melts of the CMAS and CAS systems at 1,600°C and 1.5 GPa is a function of both the silica activity of the melt and its viscosity. In melts with low silica activity quartz dissolves more quickly than in higher aSiO₂ melts regardless of viscosity. For melts with equal aSiO₂, dissolution is faster in the low viscosity melt. Quartz dissolution is controlled by interface kinetics in three of the four melts used in this study for times much greater than predicted by the model of Zhang et al. (in Contrib Mineral Petrol 102:492–513 1989). One melt which was previously shown to adhere to the predicted behaviour at lower temperature shows a significant activation time at higher temperature. All the dissolution data indicate that there are likely to be three distinct domains of dissolution behaviour, although the details of why a particular melt falls in any one domain require further study. Although the current database is small, the relationship between quartz solubility and the dissolution constant indicate that solubility may be a useful parameter for predicting dissolution rates, particularly if silica activity and melt viscosity are also known.  相似文献   

The origin of reaction textures in mantle peridotite xenoliths from Sal Island, Cape Verde: the case for “metasomatism” by the host lava   总被引：1，自引：1，他引：1  

Cliff S. J. Shaw  Florian Heidelbach  Donald B. Dingwell 《Contributions to Mineralogy and Petrology》2006,151(6):681-697

Reaction zones around minerals in mantle xenoliths have been reported from many localities worldwide. Interpretations of the origins of these textures fall into two groups: mantle metasomatic reaction or reaction during transport of the xenoliths to the surface. A suite of harzburgitic mantle xenoliths from Sal, Cape Verde show clear evidence of reaction during transport. The reactions resulted in the formation of olivine–clinopyroxene and Si- and alkali-rich glass reaction zones around orthopyroxene and sieve-textured clinopyroxene and sieve textured spinel, both of which are associated with a Si- and alkali-rich glass similar to that in the orthopyroxene reaction zones. Reaction occurred at pressures less than the mantle equilibration pressure and at temperatures close to the liquidus temperature of the host magma. In addition, there is a clear spatial relation of reaction with the host lava: reaction is most intense near the lava/xenolith contact. The residence time of the xenoliths in the host magma, determined from Fe–Mg interdiffusion profiles in olivine, was approximately 4 years. Our results cannot be reconciled with a recent model for the evolution of the mantle below the Cape Verde Archipelago involving mantle metasomatism by kimberlitic melt. We contend that alkali-rich glasses in the Sal xenoliths are not remnants of a kimberlitic melt, but rather they are the result of reaction between the host lava or a similar magma and xenolith minerals, in particular orthopyroxene. The formation of a Si- and alkali-rich glass by host magma–orthopyroxene reaction appears to be a necessary precursor to formation of sieve textured spinel and clinopyroxene.  相似文献   

Representation of fish communities by scale sub-fossils in shallow lakes: implications for inferring percid–cyprinid shifts     

T.A. Davidson  C.D. Sayer  M.R. Perrow  M.L. Tomlinson 《Journal of Paleolimnology》2003,30(4):441-449

The palaeoecological potential of fish scales was assessed by comparing contemporary population data with scale remains obtained from littoral (n = 10) and open water (n = 10) surface sediment samples in two English shallow lakes, Selbrigg Pond and Cockshoot Broad. Scales and/or scale fragments were present, in low numbers (<20 per 100 cm³ wet sediment) in 34 of 40 sediment samples. In accordance with fish population data, higher densities of scale remains were found in Selbrigg compared to Cockshoot, and in littoral compared to open water samples. Taxonomic difficulties, exacerbated by scale fragmentation, made it impossible to assign the majority of remains to individual species. Most remains could, however, be placed into one of two groups: (i) percids – represented by both scales and scale fragments; and (ii) cyprinids – largely represented by scale fragments. To allow comparison of fish population and sedimentary scale data, both were converted to percentages of the aggregate percid–cyprinid total. Whole scales recovered were almost exclusively percid (45 of 48), thus bore little resemblance to the contemporary fish data. Nevertheless, percentages of scale fragments (Selbrigg: 34 and 66%; Cockshoot: 13 and 87% percid and cyprinid, respectively) and of whole scales and fragments combined (Selbrigg: 54 and 46%; Cockshoot: 46 and 54% percid and cyprinid, respectively) reflected the presence of the numerically dominant fish groups and the broad inter-site differences in their relative abundance (Selbrigg: 36 and 64%; Cockshoot: 10 and 90% percid and cyprinid, respectively). A running mean of scales per sediment volume indicated that some 400 cm³ of sediment was required to accurately characterise the remains present. This study suggests that, with the appropriate methodological considerations (e.g., collection of large sediment samples), fish scale remains may be used to determine the past presence–absence and relative abundance of percid and cyprinid species. As such, this technique may be a valuable supplementary tool for establishing longer-term changes in the fish communities of shallow lakes.  相似文献   

Application of Very Fast Simulated Annealing to the Determination of the Crustal Structure Beneath Tibet   总被引：7，自引：0，他引：7  

Lian-She Zhao  Mrinal K. Sen  Paul Stoffa  Cliff Frohlich 《Geophysical Journal International》1996,125(2):355-370

  相似文献   

Syn‐metamorphic folding in the Tauern Window,Austria dated by Th–Pb ages from individual allanite porphyroblasts          下载免费PDF全文

R. A. Cliff  F. Oberli  M. Meier  G. T. R. Droop  M. Kelly 《Journal of Metamorphic Geology》2015,33(4):427-435

High‐precision ²³²Th–²⁰⁸Pb dates have been obtained from allanite porphyroblasts that show unambiguous microstructural relationships to fabrics in a major syn‐metamorphic fold in the SE Tauern Window, Austria. Three porphyroblasts were analysed from a single garnet mica schist from the Peripheral Schieferhülle in the core of the Ankogel Synform, one of a series of folds which developed shortly before the thermal peak of Alpine epidote–amphibolite facies metamorphism: allanite grain 1 provided two analyses with a combined age of 27.7 ± 0.7 Ma; grain 2, which was slightly bent and fractured during crenulation, provided two analyses with a combined age of 27.7 ± 0.4 Ma; a single analysis from grain 3, which overgrew an already crenulated fabric, gave an age of 28.0 ± 1.4 Ma. The five ²³²Th–²⁰⁸Pb ages agree within error and define an isochron with an age of 27.71 ± 0.36 Ma (95% confidence level; MSWD = 0.46). The results imply that the crenulation event was in progress in a short interval (<1 Ma) c. 28 Ma, and that the Ankogel Synform was forming at this time. The thermal peak of regional metamorphism in the SE Tauern Window was probably attained shortly after 28 Ma, only c. 5 Ma after eclogite facies metamorphism in the central Tauern Window. Metasediment may contain allanite porphyroblasts with clear‐cut microstructural relationships to fabric development and metamorphic crystallization; for such rocks, ²³²Th–²⁰⁸Pb dating on microsamples offers a powerful geochronological tool.  相似文献   

Contemporary Deposition and Long-Term Accumulation of Sediment and Nutrients by Tidal Freshwater Forested Wetlands Impacted by Sea Level Rise   总被引：1，自引：0，他引：1  

Gregory?B.?NoeEmail author  Cliff?R.?Hupp  Christopher?E.?Bernhardt  Ken?W.?Krauss 《Estuaries and Coasts》2016,39(4):1006-1019

Contemporary deposition (artificial marker horizon, 3.5 years) and long-term accumulation rates (²¹⁰Pb profiles, ~150 years) of sediment and associated carbon (C), nitrogen (N), and phosphorus (P) were measured in wetlands along the tidal Savannah and Waccamaw rivers in the southeastern USA. Four sites along each river spanned an upstream-to-downstream salinification gradient, from upriver tidal freshwater forested wetland (TFFW), through moderately and highly salt-impacted forested wetlands, to oligohaline marsh downriver. Contemporary deposition rates (sediment, C, N, and P) were greatest in oligohaline marsh and lowest in TFFW along both rivers. Greater rates of deposition in oligohaline and salt-stressed forested wetlands were associated with a shift to greater clay and metal content that is likely associated with a change from low availability of watershed-derived sediment to TFFW and to greater availability of a coastal sediment source to oligohaline wetlands. Long-term accumulation rates along the Waccamaw River had the opposite spatial pattern compared to contemporary deposition, with greater rates in TFFW that declined to oligohaline marsh. Long-term sediment and elemental mass accumulation rates also were 3–9× lower than contemporary deposition rates. In comparison to other studies, sediment and associated nutrient accumulation in TFFW are lower than downriver/estuarine freshwater, oligohaline, and salt marshes, suggesting a reduced capacity for surface sedimentation (short-term) as well as shallow soil processes (long-term sedimentation) to offset sea level rise in TFFW. Nonetheless, their potentially large spatial extent suggests that TFFW have a large impact on the transport and fate of sediment and nutrients in tidal rivers and estuaries.  相似文献