Identification of the interstellar cyanomethyl radical (CH2CN) in the molecular clouds TMC-1 and Sagittarius B2     

Irvine WM  Friberg P  Hjalmarson A  Ishikawa S  Kaifu N  Kawaguchi K  Madden SC  Matthews HE  Ohishi M  Saito S  Suzuki H  Thaddeus P  Turner BE  Yamamoto S  Ziurys LM 《The Astrophysical journal》1988,334(2):L107-L111

We report the astronomical identification of the cyanomethyl radical, CH2CN, the heaviest nonlinear molecular radical to be identified in interstellar clouds. The complex fine and hyperfine structures of the lowest rotational transitions at about 20.12 and 40.24 GHz are resolved in TMC-1, where the abundance appears to be about 5 x 10(-9) relative to that of H2. This is significantly greater than the observed abundance of CH3CN (methyl cyanide) in TMC-1. In Sgr B2 the hyperfine structure is blended in the higher frequency transitions at 40, 80, and 100 GHz, although the spin-rotation doubling is clearly evident. Preliminary searches in other sources indicate that the distribution of CH2CN is similar to that for such carbon chain species as HC3N or C4H.  相似文献   

Upwelling, species, and depth effects on coral skeletal cadmium-to-calcium ratios (Cd/Ca)     

Kathryn A. Matthews  Andréa G. Grottoli  James E. Palardy 《Geochimica et cosmochimica acta》2008,72(18):4537-4550

Skeletal cadmium-to-calcium (Cd/Ca) ratios in hermatypic stony corals have been used to reconstruct changes in upwelling over time, yet there has not been a systematic evaluation of this tracer’s natural variability within and among coral species, between depths and across environmental conditions. Here, coral skeletal Cd/Ca ratios were measured in multiple colonies of Pavona clavus, Pavona gigantea and Porites lobata reared at two depths (1 and 7 m) during both upwelling and nonupwelling intervals in the Gulf of Panama (Pacific). Overall, skeletal Cd/Ca ratios were significantly higher during upwelling than during nonupwelling, in shallow than in deep corals, and in both species of Pavona than in P. lobata. P. lobata skeletal Cd/Ca ratios were uniformly low compared to those in the other species, with no significant differences between upwelling and nonupwelling values. Among colonies of the same species, skeletal Cd/Ca ratios were always higher in all shallow P. gigantea colonies during upwelling compared to nonupwelling, though the magnitude of the increase varied among colonies. For P. lobata, P. clavus and deep P. gigantea, changes in skeletal Cd/Ca ratios were not consistent among all colonies, with some colonies having lower ratios during upwelling than during nonupwelling. No statistically significant relationships were found between skeletal Cd/Ca ratios and maximum linear skeletal extension, δ¹³C or δ¹⁸O, suggesting that at seasonal resolution the Cd/Ca signal was decoupled from growth rate, coral metabolism, and ocean temperature and salinity, respectively. These results led to the following conclusions, (1) coral skeletal Cd/Ca ratios are independent of skeletal extension, coral metabolism and ambient temperature/salinity, (2) shallow P. gigantea is the most reliable species for paleoupwelling reconstruction and (3) the average Cd/Ca record of several colonies, rather than of a single coral, is needed to reliably reconstruct paleoupwelling events.  相似文献   

The Continuous Plankton Recorder: concepts and history, from Plankton Indicator to undulating recorders   总被引：1，自引：0，他引：1  

P. C. Reid  J. M. Colebrook  J. B. L. Matthews  J. Aiken  Continuous Plankton Recorder Team 《Progress in Oceanography》2003,58(2-4):117

Alister Hardy conceived the Continuous Plankton Recorder (CPR) survey in the 1920s as a means of mapping near-surface plankton in space and time, interpreting the changing fortunes of the fisheries and relating plankton changes to hydrometeorology and climatic change. The seed he planted has grown to become the most extensive long-term survey of marine organisms in the world and the breadth of his vision becomes ever more apparent. The survey has now run for over 70 years and its value increases with every passing decade. Operating from ‘ships of opportunity’ the machines used are robust, reliable and easy to handle. Wherever possible, all the sampling and analytical methods have not been changed to maintain the consistency of the time series. Computerisation and the development of new statistical approaches have increased our ability to handle the large quantities of information generated and enhance the sensitivity of the data analyses. This overview, based on almost 900 papers, recounts the various phases in the history of the survey. It starts with the Indicator Survey (1921–1934), the deployment of the first CPR on the Discovery Expedition (1924–1927) and the early CPR survey in the North Sea (1931–1939). The survey reopened in 1946 after the Second World War and expanded across the North Atlantic to North America from 1959. Taxonomic studies were initiated and an emphasis was placed on patterns of distribution, which were seen to reflect the varying oceanographic conditions. The years 1968–1976 saw further expansion with operations even in the American Great Lakes, publication of a Plankton Atlas and initial evidence for a downward trend in plankton biomass. At about this time electronic instrumentation was attached to CPRs to make additional measurements and work was started on the development of a new generation of undulating Continuous Plankton and Environmental Recorders (CPERs). In 1976 the survey moved to Plymouth. Scientific priorities in the UK changed in the subsequent decade and funding became more difficult to secure even though some of the CPR papers being published at the time are now regarded as classics in plankton ecology. In 1988 the UK Natural Environment Research Council (NERC) decided to close the survey. An international rescue operation led to the creation of the Sir Alister Hardy Foundation for Ocean Science (SAHFOS) in 1990, which has continued with consortium funding from a number of countries, and from 1999 again included NERC. The scientific rationale of the survey has gained credibility as concern over climate change and other anthropogenic effects has grown and as the key role that plankton plays as an indicator of large-scale environmental conditions becomes ever more apparent. Recently, the survey became an integral component of the Global Ocean Observation System (GOOS) and expanded into the North Pacific. It plays a complementary role in many large international and multidisciplinary projects and is providing inspiration, advice and support to daughter surveys elsewhere in the world. At the start of a new millennium, Hardy’s vision from the 1920s is a powerful driving force not just in international biological oceanography, but in global environmental science.  相似文献   

Monitoring the status of a mechanical cable while in operation by means of the acoustic emission method     

Patricio A.A. Laura  James R. Matthews 《Ocean Engineering》1985,12(3):211-219

The mechanical cable is an essential element in towing operations, remote control of equipment, salvage operations, civil engineering applications, etc.Failure of these cables can result in loss of life and loss of equipment worth hundreds of thousands of dollars. Obviously then, sensors that can indicate the condition of these cables so that the risk to their continued use and their remaining safe life can be determined when in operation are very important from the point of view of commercial and military interest.This paper presents a brief review of research into failure mechanisms of various cables and the acoustic emission signatures of the various cables under simulated loading. The development of a specific operational monitor for a towed cable system is also given.  相似文献   

Particle acceleration and the decay of soft X-ray non-thermal line broadening in solar flares     

David Alexander  Sarah A. Matthews 《Solar physics》1994,154(1):157-175

The relationship between the production of -ray emitting particles and non-thermal soft X-ray line broadening is investigated. A model of particle acceleration via the stochastic interaction with MHD turbulence is assumed and the time development of the wave energy density derived under the condition of energy conservation between waves and particles. The inferred numbers and energy distribution of accelerated protons for four -ray flares are used to define the wave energy density and its temporal development. The presence of Alfvén wave turbulence is considered as the source of the non-thermal motions in the ambient plasma. These motions are observed as excess widths in the soft X-ray line emission from these events. The decay of the waves via the particle acceleration process is compared with the observed decays of this non-thermal line broadening. Our results show that both the -ray emission and excess soft X-ray line widths in these flares can be explained by the single physical phenomenon of Alfvén wave turbulence.  相似文献   

The near infrared camera on the W.M. Keck telescope     

K. Matthews  B. T. Soifer 《Experimental Astronomy》1994,3(1-4):77-84

The near infrared camera (NIRC) was used for a science demonstration run on the Keck telescope during 16–24 March 1993. The camera used a 256×256 InSb array manufactured by Santa Barbara Research Corporation. Observations were obtained using narrowband and broad band filters from 1 to 2.4 microns, and grisms with a spectral resolution of 0.6 percent in the J, H and K atmospheric windows. The instrument was fully background limited over the entire wavelength range. The sky background was quite low, reaching 14.3 mag/square arc sec in the broadband K _s filter. The image quality of the camera + telescope was excellent, being seeing limited in the range 0.5–0.9.The science demonstration observations of the NIRC on the Keck Telescope included observations of the most distant galaxy known, 4C41.17 at a redshift z=3.8 and the most luminous object known, the IRAS source FSC10214+4724 at a redshift z=2.29. Observations of the radio galaxy address the problem of the alignment effect in high redshift radio galaxies as well as the environments of such systems. FSC10214+4724 appears to be a merging galaxy that is at least 5×10⁸ years old.Based on observations obtained at the W.M.Keck Observatory, which is operated jointly by the California Institute of Technology and the University of CaliforniaThe W.M. Keck Observatory is operated as a scientific partnership between the California Institute of Technology and the University of California. It was made possible by the generous gift of the W.M. Keck foundation and the support of its president, Howard Keck.  相似文献   

A remote unmanned ELF/VLF goniometer receiver in Antarctica     

J.P. Matthews  A.J. Smith  I.D. Smith 《Planetary and Space Science》1979,27(11):1391-1401

In March 1977 an unmanned ELF/VLF goniometer receiving station was deployed on the Antarctic plateau 110 km south south west of the British Antarctic Survey base at Halley. A UHF Telemetry link enabled the ELF and VLF signals to be monitored and recorded at Halley, simultaneously with data from an identical ELF/VLF receiver at Halley. The remote station was designed for unattended operation with a wind driven generator to recharge its battery. Design considerations and problems encountered are discussed and some preliminary results are presented.  相似文献   

Near-infrared spectrophotometry of the satellites and rings of Uranus     

B.T. Soifer  G. Neugebauer  K. Matthews 《Icarus》1981,45(3):612-617

New spectrophotometry from 1.5 to 2.5 μm is reported for the Uranian satellites Titania, Oberon, and Umbriel. A spectrum of the rings of Uranus from 2.0 to 2.4 μm is also reported. No evidence is found for frost covering the surface of the ring material, consistent with the low albedo of the rings (P_K = 0.03) previously reported by Nicholson and Jones (1980). The surfaces of the satellites are found to be covered by dirty water frost. Assuming albedos of the frost and gray components covering the Uranian satellites to be the same as the light and dark faces of Iapetus, radii are derived that are roughly twice those inferred from the assumption of a visual albedo of 0.5.  相似文献   

Earth-orbit-approaching comets and their theoretical meteor radiants     

Jack D. Drummond 《Icarus》1981,47(3):500-517

Sixteen comets produce recognizable meteor showers that are found in A. F. Cook's (1973, In Evolutionary and Physical Properties of Meteoroids (C. L. Hemenway, P. M. Millman, and A. F. Cook, Eds.), pp. 183–191, U.S. Govt. Printing Office, Washington, D.C.), working list of meteor streams. Of these, five are long period, including one in a parabolic and one in a hyperbolic orbit. The largest Earth-comet orbit miss distance is 0.20 AU for P/Encke and the Northern and Southern Taurids. Using this is an upper limit for meteor showers from comets, all comets which approach the Earth's orbit to within 0.20 AU were extracted from the Catalogue of Cometary Orbits (B. G. Marsden, 1979. 3rd ed., Central Bureau of Astronomical Telegrams, IAU SAO, Cambridge, Mass.). A compilation of such comets is presented by date minimum approach, along with the distance of closest approach and the theoretical geocentric radiants and velocities of possible associated meteor showers. Both pre- and postpperihelion encounters with the Earth's orbit are considered. There are 240 entries for 178 long-period comets, and 36 for 28 short-period comets. It is noted that all short-period comets that have approached the Earth's orbit to within 0.08 AU have produced meteors, except P/Lexell, P/Finlay, P/Denning-Fujikawa, and P/Grigg-Skjellerup. Attention is called to the favorable observing conditions for detecting meteors from P/Grigg-Skjellerup in April 1982, and for the possibility of another great Draconid storm from P/Giacobini-Zinner in October 1985. A comparison is made between observed sporadic meteor rates and the distribution of theoretical radiants throughout the year, from which it is concluded that the currently known comets can account for sporadic meteors. A criterion is developed to test whether or not an observed meteor shower can be associated with a given theoretical radiant. Based on known examples, a qualitative model for comet/meteor relationships is also presented.  相似文献   

Phytoliths as indicators of pedogenesis and paleoenvironmental changes in the Brazilian cerrado     

Miriam Borba-Roschel  Anne Alexandre  Anglica Fortes Drummond Chicarino Varajo  Jean Dominique Meunier  Csar Augusto Chicarino Varajo  Fabrice Colin 《Journal of Geochemical Exploration》2006,88(1-3):172

This paper presents the preliminary results of phytolith analyses of a peat located in the cerrado of the Uberaba municipality, State of Minas Gerais, Brazil. The phytolith soil sequence is discussed by comparison with phytolith assemblages extracted from dominant plants (Cyperaceae and Poaceae). Increasing mean age of phytolith assemblages with depth is assumed. Poaceae Cuneiform bulliform cell, Parallelepiped bulliform cell and Elongate smooth long cell types dominate up to 80 cm, rapidly drop to 42% at 80 cm and regularly decrease from 42% to 2% upwards. Cyperaceae Rondel concave type shows the inverse trend, being dominant in the upper part of the profile. This pattern can be assigned to increasing selective dissolution of the Cyperaceae phytolith type with depth, or/and to a decrease of water stress suffered by the grasses, leading to a decrease of bulliform cell silicification. Soil processes and paleo-environmental changes hypotheses are discussed.  相似文献