The variability of rainfall-dependent streamflow at catchment scale modulates many ecosystem processes in wet temperate forests. Runoff in small mountain catchments is characterized by a quick response to rainfall pulses which affects biogeochemical fluxes to all downstream systems. In wet-temperate climates, water erosion is the most important natural factor driving downstream soil and nutrient losses from upland ecosystems. Most hydrochemical studies have focused on water flux measurements at hourly scales, along with weekly or monthly samples for water chemistry. Here, we assessed how water and element flows from broad-leaved, evergreen forested catchments in southwestern South America, are influenced by different successional stages, quantifying runoff, sediment transport and nutrient fluxes during hourly rainfall events of different intensities. Hydrograph comparisons among different successional stages indicated that forested catchments differed in their responses to high intensity rainfall, with greater runoff in areas covered by secondary forests (SF), compared to old-growth forest cover (OG) and dense scrub vegetation (CH). Further, throughfall water was greatly nutrient enriched for all forest types. Suspended sediment loads varied between successional stages. SF catchments exported 455 kg of sediments per ha, followed by OG with 91 kg/ha and CH with 14 kg/ha, corresponding to 11 rainfall events measured from December 2013 to April 2014. Total nitrogen (TN) and phosphorus (TP) concentrations in stream water also varied with rainfall intensity. In seven rainfall events sampled during the study period, CH catchments exported less nutrients (46 kg/ha TN and 7 kg/ha TP) than SF catchments (718 kg/ha TN and 107 kg/ha TP), while OG catchments exported intermediate sediment loads (201 kg/ha TN and 23 kg/ha TP). Further, we found significant effects of successional stage attributes (vegetation structure and soil physical properties) and catchment morphometry on runoff and sediment concentrations, and greater nutrients retention in OG and CH catchments. We conclude that in these southern hemisphere, broad-leaved evergreen temperate forests, hydrological processes are driven by multiple interacting phenomena, including climate, vegetation, soils, topography, and disturbance history. 相似文献
The Very Large Telescope Interferometer [1,13] will be operated in air which will introduce small optical path fluctuations due to internal turbulence [4,6] and dispersion effects. Both may contribute to fringe contrast decrease. Longitudinal dispersion effects can be corrected by inserting an appropriate glass of variable thickness in one arm of the interferometer [3,5,11,12]. This paper presents a new method applied to VLTI in order to select the optimum glass, according to both the observing wavelength and the spectral bandpath, and to calculate its thickness. Results are presented in terms of improvement on the fringe contrast. 相似文献
In the north of France, high registers of nickel are sometimes recorded within the chalk aquifer. In a confined context, the
presence of pyrite in the covering clays or in the marcasite nodules encrusted in the clay may constitute a natural source
of trace metals. With an objective of sanitary control, the limits of chemical contents regulating the quality of water destined
for human consumption have been lowered by the European Framework Directive in the field of water policy (2000/60/EC). As
a result, nickel limits have been reduced from 50 to 20 μg/l. The analyses, carried out on three water catchment fields in
our area of study, were centred on variable parameters (Eh, O2(d), pH, Conductivity, T°), major elements (SO4, NO3) and metals (Fe, Ni, Mn, Co). The acquired data enabled us to identify from one hand, the conditions which are presented
within the site, special thanks to the evolution of nitrate and iron contents and on the other hand, the natural origin (geological)
of nickel for two of the three sites studied based essentially on the evaluation of the Nickel/Cobalt ratio. Thus, on the
first site, the evolution of nickel content and nitrate content showed the influence of the phenomenon of denitrification
on the re-mobilisation of the nickel. Whereas on the second site, a high variation of total iron content and oxygen dissolved
in solution highlighted a particular phenomenon of oxidation of the pyrite through molecular oxygen. Finally, the correlation
with the sulphates clearly showed behaviour of the nickel, once released, that was entirely dependent on the phenomenon of
adsorption on the iron and manganese hydroxides. 相似文献
These last 10 years, numerical models of mantle convection have emphasized the role of the 670 km endothermic phase change in generating avalanches that trigger catastrophic mass transfers between upper and lower mantle. On the other hand, scientists have emphasized the concomitance of large-scale worldwide geophysical and tectonic events, which could find their deep thermal roots in the huge mass transfers induced by the avalanches. In particular, the paleontological records show two periods of length of day (l.o.d.) shortening between 420 and 360, and 200 and 80 Myr BP. This last event is synchronous with a strong true polar wander and a global warming of the upper mantle. In order to study the potential effects of the avalanche on the main component of the Earth’s rotation, the Liouville equation has been solved and the l.o.d. evolution has been calculated from the perturbations of the inertia tensor. The results show that the inertia tensor of the Earth’s is mainly sensitive to the global transfers through the 670 km discontinuity. The l.o.d. perturbations will be synchronous with the global thermal effects of the avalanche. These theoretical results allow proposing a self-consistent physical mechanism to explain periods of the Earth’s rotation acceleration. Within this context, the l.o.d. shortening during the Cenozoic and Cretaceous brings one more clue to the possible participation of a mantle avalanche in generating the concomitant large scale events which have occurred during this very particular period of the Earth’s history. 相似文献
In Portugal, few studies have been made of the historical floods of the RiverTagus (the longest in the Iberian Peninsula). This fact led to the study of theLower Tagus (Santarém region) using written historical documents,cartographic documents and hydrological data, consisting mainly of waterlevel records. With the support of the historical documents and the analysisof all the maps, it was possible to verify that the human intervention has beenfundamental in the morphological changes of the Tagus' channel. It becameaware that the river changed from a braided to a single channel with alternatebars. From the hydrological data, return periods for the floods were determined,using the Pearson Type 3 distribution. The selection of the most important floods,from 1855 to 1998, enabled to build a ``flood hazard scale' for this region. 相似文献
This paper reports on the petrology and geochemistry of a diamondiferous peridotite xenolith from the Premier diamond mine in South Africa.
The xenolith is altered with pervasive serpentinisation of olivine and orthopyroxene. Garnets are in an advanced state of kelyphitisation but partly fresh. Electron microprobe analyses of the garnets are consistent with a lherzolitic paragenesis (8.5 wt.% Cr2O3 and 6.6 wt.% CaO). The garnets show limited variation in trace element composition, with generally low concentrations of most trace elements, e.g. Y (<11 ppm), Zr (<18 ppm) and Sr (<0.5 ppm). Garnet rare earth element concentrations, when normalised against the C1 chondrite of McDonough and Sun (Chem. Geol. 120 (1995) 223), are characterised by a rare earth element pattern similar to garnet from fertile lherzolite.
All diamonds recovered are colourless. Most crystals are sharp-edged octahedra, some with minor development of the dodecahedral form. A number of crystals are twinned octahedral macles, while aggregates of two or more octahedra are also common. Mineral inclusions are rare. Where present they are predominantly small black rosettes believed to consist of sulfide. In one instance a polymineralic (presumably lherzolitic) assemblage of reddish garnet, green clinopyroxene and a colourless mineral is recognised.
Infrared analysis of the xenolith diamonds show nitrogen contents generally lower than 500 ppm and variable nitrogen aggregation state, from 20% to 80% of the ‘B’ form. When plotted on a nitrogen aggregation diagram a well defined trend of increasing nitrogen aggregation state with increasing nitrogen content is observed. Carbon isotopic compositions range from −3.6 ‰ to −1.3 ‰. These are broadly correlated with diamond nitrogen content as determined by infrared spectroscopy, with the most negative C-isotopic compositions correlating with the lowest nitrogen contents.
Xenolith mantle equilibration temperatures, calculated from nitrogen aggregation systematics as well as the Ni in garnet thermometer are on the order of 1100 to 1200 °C.
It is concluded that the xenolith is a fertile lherzolite, and that the lherzolitic character may have resulted from the total metasomatic overprinting of pre-existing harzburgite. Metasomatism occurred prior to, or accompanied, diamond growth. 相似文献
Since the discovery of shatter cones (SCs) near the village of Agoudal (Morocco, Central High Atlas Mountains) in 2013, the absence of one or several associated circular structures led to speculation about the age of the impact event, the number, and the size of the impact crater or craters. Additional constraints on the crater size, age, and erosion rates are obtained here from geological, structural, and geophysical mapping and from cosmogenic nuclide data. Our geological maps of the Agoudal impact site at the scales of 1:30,000 (6 km2) and 1:15,000 (2.25 km2) include all known occurrences of SCs in target rocks, breccias, and vertical to overturned strata. Considering that strata surrounding the impact site are subhorizontal, we argue that disturbed strata are related to the impact event. Three types of breccias have been observed. Two of them (br1‐2 and br2) could be produced by erosion–sedimentation–consolidation processes, with no evidence for impact breccias, while breccia (br1) might be impact related. The most probable center of the structure is estimated at 31°59′13.73?N, 5°30′55.14?W using the concentric deviation method applied to the orientation of strata over the disturbed area. Despite the absence of a morphological expression, the ground magnetic and electromagnetic surveys reveal anomalies spatially associated with disturbed strata and SC occurrences. The geophysical data, the structural observations, and the area of occurrence of SCs in target rocks are all consistent with an original size of 1.4–4.2 km in diameter. Cosmogenic nuclide data (36Cl) constrain the local erosion rates between 220 ± 22 m Ma?1 and 430 ± 43 m Ma?1. These erosion rates may remove the topographic expression of such a crater and its ejecta in a time period of about 0.3–1.9 Ma. This age is older than the Agoudal iron meteorite age (105 ± 40 kyr). This new age constraint excludes the possibility of a genetic relationship between the Agoudal iron meteorite fall and the formation of the Agoudal impact site. A chronolgy chart including the Atlas orogeny, the alternation of sedimentation and erosion periods, and the meteoritic impacts is presented based on all obtained and combined data. 相似文献
Olivine in kimberlites can provide unique insights into magma petrogenesis, because it is the most abundant xenocrystic phase and a stable magmatic product over most of the liquid line of descent. In this study we examined the petrography and chemistry of olivine in kimberlites from different tectonic settings, including the Slave craton, Canada (Ekati: Grizzly, Koala), the Brasilia mobile belt (Limpeza-18, Tres Ranchos-04), and the Kaapvaal craton, South Africa (Kaalvallei: Samada, New Robinson). Olivine cores display a wide range of compositions (e.g., Mg# = 78–95). The similarity in olivine composition, resorption of core zones and inclusions of mantle-derived phases, indicates that most olivine cores originated from the disaggregation of mantle peridotites, including kimberlite-metasomatised lithologies (i.e. sheared lherzolites and megacrysts). Olivine rims typically show a restricted range of Mg#, with decreasing Ni and increasing Mn and Ca contents, a characteristic of kimberlitic olivine worldwide. The rims host inclusions of groundmass minerals, which implies crystallisation just before and/or during emplacement. There is a direct correlation between olivine rim composition and groundmass mineralogy, whereby high Mg/Fe rims are associated with carbonate-rich kimberlites, and lower Mg/Fe rims are correlated with increased phlogopite and Fe-bearing oxide mineral abundances. There are no differences in olivine composition between explosive (Grizzly) and hypabyssal (Koala) kimberlites. Olivine in kimberlites also displays transitional zones and less common internal zones, between cores and rims. The diffuse transitional zones exhibit intermediate compositions between cores and rims, attributed to partial re-equilibration of xenocrystic cores with the ascending kimberlite melt. In contrast, internal zones form discrete layers with resorbed margins and restricted Mg# values, but variable Ni, Mn and Ca concentrations, which indicates a discrete crystallization event from precursor kimberlite melts at mantle depths. Overall, olivine exhibits broadly analogous zoning in kimberlites worldwide. Variable compositions for individual zones relate to different parental melt compositions rather than variations in tectonic setting or emplacement mechanism.
Zusammenfassung An vier Proben aus dem Augen- und Flasergneiskomplex in Großvenedigergebiet (Hohe Tauern) wurden Rb–Sr-Altersbestimmungen durchgeführt. Die Biotit-Alterswerte lagen bei zirka 20 M. J. Sie sind der alpidischen Tauernkristallisation zuzuordnen. Eine Gesamtgesteinsisochrone von drei typischen Augen- und Flasergranitgneisen ergab 246 M. J. und wird als Bildungsalter eines magmatischen Granitkörpers interpretiert. Es muß daher zur Perm-Zeit in den westlichen Hohen Tauern ein ausgedehnter Granitmagmatismus angenommen werden. Auf die Schwierigkeiten, dieses Ereignis in das derzeitige geologische-Entstehungsbild einzuordnen, wurde hingewiesen.
Rubidium-strontium age determinations on biotite-muscovite-gneisses (Augen-and Flaser-gneisses) from the Northern Grossvenediger region (Tauern, Austrian Alps)
Summary Rb–Sr ages were determined for 4 samples from the Augen- and Flaser-gneiss complex of the Grossvenediger region, Hohe Tauern, Austria. The biotite ages of 20 m. y. may be attributed to the Tauern-crystallization of Alpidic age. A total rock isochrone of 246 m. y. based on 3 typical Augen- and Flaser-granite gneisses is interpreted as the age of a granite body. Thus extensive granite magmatism is assumed to have prevailed in the western part of the Hohe Tauern during the Permian. There are, however, difficulties in correlating this event with the present picture of the geologic evolution in this region.
