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When selecting produced water treatment technologies, one should focus on reducing the major contributors to the total environmental impact. These are dispersed oil and semi-soluble hydrocarbons, alkylated phenols, and added chemicals. Experiments with produced water have been performed offshore on the Statoil operated platforms Gullfaks C and Statfjord B. These experiments were designed to find how much of the environmentally relevant compounds were dissolved in the water phase and not associated to the dispersed oil in the produced water. Results show that the distribution between the dispersed oil and the water phase varies highly for the different components groups. For example the concentration of PAHs and the C6-C9 alkylated phenols is strongly correlated to the content of dispersed oil. Therefore, the technologies enhancing the removal of dispersed oil have a higher potential for reducing the environmental impact of the produced water than previously considered. 相似文献
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The chemical composition and toxicity of a water soluble fraction (WSF) of oil versus the underlying water after in situ burning (ISB), has been studied in a laboratory experiment. A system for allowing water sampling after ISB was developed. Seawater samples and oil were collected prior to and immediately after ISB, and chemical analysis was conducted. The chemical characterization of the water showed that the disappearance of water soluble oil components during ISB was insignificant. Acute toxicity tests with the marine copepod Calanus finmarchicus and Microtox® bioassay was performed to establish LC50/EC50 values of the water. The results were compared with regular WAF systems with unburned weathered oil, and indicated no increase in toxicity in the underlying water after ISB. 相似文献
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Subsurface video footage can be used as a successful identification tool for various marine organisms; however, processing of such information has proven challenging. This study tests the use of automated software to assist with photo-identification of the great white shark Carcharodon carcharias in the region of Gansbaai, on the south coast of South Africa. A subsurface photo catalogue was created from underwater video footage. Single individuals were identified by using pigmentation patterns. From this catalogue, two images of the head for each individual were inserted into automated contour-recognition software (Interactive Individual Identification System Beta Contour 3.0). One image was used to search the database, the other served as a reference image. Identification was made by means of a contour, assigned using the software to the irregular border of grey and white on the shark's head. In total, 90 different contours were processed. The output provided ranks, where the first match would be a direct identification of the individual. The method proved to be accurate, in particular for high-quality images where 88.24% and 94.12%, respectively, were identified by two independent analysts as first match, and with all individuals identified within the top 10 matches. The inclusion of metadata improved accuracy and precision, allowing identification of even low-quality images. 相似文献
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A large-scale field experiment took place in the marginal ice zone in the Barents Sea in May 2009. Fresh oil (7000 L) was released uncontained between the ice floes to study oil weathering and spreading in ice and surface water. A detailed monitoring of oil-in-water and ice interactions was performed throughout the six-day experiment. In addition, meteorological and oceanographic data were recorded for monitoring of the wind speed and direction, air temperature, currents and ice floe movements. The monitoring showed low concentrations of dissolved hydrocarbons and the predicted acute toxicity indicated that the acute toxicity was low. The ice field drifted nearly 80 km during the experimental period, and although the oil drifted with the ice, it remained contained between the ice floes. 相似文献
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Two major river systems operated in southern and eastern England throughout the Pleistocene: the river Thames and the Solent river. Both rivers are axial streams of comparable size draining major basinal structures comprising similar Tertiary and Mesozoic rocks. Although the modem Thames flows broadly W-E in the London Basin, upstream of Reading it flows from the north to drain the south Midlands. It was diverted to its present course through London by glaciation in the Anglian (Elsterian) before which it flowed across East Anglia into the southem North Sea. The Solent river no longer exists since most of its course was drowned by eustatic sea-level rise during the Flandrian Stage (Holocene). Previously, it flowed eastwards across SE Dorset and S Hampshire as an extension of the modem river Frome in the Hampshire Basin. During periods of low sea-level (cold stages) it was a tributary of the 'Channel River'. Fluvial aggradations provide evidence of the former courses of these substantial rivers and their tributaries. The facies and sedimentary structures indicate that the bulk of the deposits in both systems accumulated in braided river environments under periglacial climates. Fossiliferous sediments provide biostratigraphical frameworks. During temperate periods the rivers adopted singlethread courses. Evolution of both rivers reflect their responses to climatic change, local geological structure and long-term tectonic activity. Both rivers are undoubtedly of considerable antiquity, their records potentially extend from the Early Pleistocene or Late Pliocene, but they may have originated in the early Tertiary. 相似文献
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Composition of the water accommodated fractions as a function of exposure times and temperatures 总被引：1，自引：0，他引：1
The water accommodated fractions (WAFs) of nine oils in seawater have been studied. The oils range from light condensate to heavy crude, and include one highly biodegraded oil and one very wax rich oil. This study has identified large variations in the chemical composition of WAFs, depending on oil type, temperature, and mixing time. Experiments at different temperatures (2-13 °C) showed that it takes longer time to reach equilibrium at the lowest temperatures, and that this varies for the different oil types. Oils with higher pour point (wax rich oils) need a longer time to establish WAF in equilibrium than oils with lower pour points (naphthenic oils). At 13 °C a mixing time of 48 h, as recommended in standard procedures, seems to be sufficient for asphalthenic and paraffinic oils. The results demonstrated that for WAF prepared from an unknown oil, or at lower temperatures, different mixing times should be tested. Since the WAF often is used in toxicity testing, the toxicity might be underestimated if the mixing time is too short. 相似文献
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