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A complexometric titration technique was employed to measure the total capacity of a variety of marine organisms to adsorb Cu2+. Measured adsorption capacities were 0.22 meq g−1 for phytoplankton, 0.3–1.0 meq g−1 for macrophytes, 1.0–2.5 meq g−1 for zooplankton and 0.3 meq g−1 for suspended particulate matter. The capacity of these materials to adsorb Cu2+ was reduced significantly in the presence of Mg2+ at seawater concentrations. Competition between Mgt2+ and Cu2+ for adsorption sites at pH 6 is described by an average conditional equilibrium constant of 103.7. This constant is such that very little Cu2+ may be adsorbed onto particulates and marine phytoplankton in the presence of Mg2+. Further, primary productivity data and estimates of the detrital carbon sedimentation in Long Island Sound suggest that the flux of particulate carbon is insufficient to remove significant amounts of Cu from the water column to sediments by adsorption mechanisms.  相似文献   
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We describe finite-difference approximations to the equations of 2-D electromagnetic induction that permit discrete boundaries to have arbitrary geometrical relationships to the nodes. This allows finite-difference modelling with the flexibility normally ascribed to finite-element modelling. Accuracy is demonstrated by comparison with finite-element computations. We also show that related approximations lead to substantially improved accuracy in regions of steep, but not discontinuous, conductivity gradient.  相似文献   
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Abstract

This paper experimentally investigates the convective planform near critical in a fluid layer whose temperature-dependent viscosity varies from top to bottom by up to a factor of 1500. Convection occurs in three different planforms: rolls, hexagons and squares. The square planform, which appears only for fluids with viscosity variation greater than about 50, replaces the hexagonal convection pattern as the Rayleigh number increases much above critical. The large amplitude of hexagonal convection with strong viscosity variation precludes studying the hexagon-square transition with perturbation methods of the type used to study the hexagon-roll transitions at smaller viscosity variations.  相似文献   
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As the world’s largest importer of marine ornamental species for the aquaria, curio, home décor, and jewelry industries, the United States has an opportunity to leverage its considerable market power to promote more sustainable trade and reduce the effects of ornamental trade stress on coral reefs worldwide. Evidence indicates that collection of some coral reef animals for these trades has caused virtual elimination of local populations, major changes in age structure, and promotion of collection practices that destroy reef habitats. Management and enforcement of collection activities in major source countries such as Indonesia and the Philippines remain weak. Strengthening US trade laws and enforcement capabilities combined with increasing consumer and industry demand for responsible conservation can create strong incentives for improving management in source countries. This is particularly important in light of the March 2010 failure of the parties to the Convention on International Trade in Endangered Species (CITES) to take action on key groups of corals.  相似文献   
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The finite element method has often been used to simulate excavation. When the soil is linearly elastic, the results of excavation should be independent of the number of stages in the excavation process, and lack of such independence indicates an incorrect procedure. The simple direct method described in this paper provides the required independence in the case of linearly elastic materials, and hence can be used for multi-stage excavation in non-linear problems without excessive errors. However methods whose errors increase with the number of stages of excavation are quite unsuitable for non-linear problems. Alternative methods of analysis, errors arising from the inability of the elements to model adequately the stress gradients near the toe of the excavation and excavation adjacent to a diaphragm wall are discussed.  相似文献   
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The sources and composition of mercury in Pacific Ocean rain   总被引:1,自引:0,他引:1  
Here we report measurements of total Hg (HgT), reactive Hg (HgR), and methylmercury (MMHg) in precipitation from the equatorial Pacific Ocean, collected during a cruise in January and February 1990, and from a mid-continental location in the rural temperate lacustrine northcentral Wisconsin environs. The concentrations of HgT (14.4±6.5 pM), HgR (8.9±4.5 pM) and MMHg (<50 fM) found in equatorial Pacific rain were less than the average concentrations found in Wisconsin. In general, the results indicate that although particulate Hg is a small fraction of the total atmospheric Hg burden, it is the major contributor to Hg in precipitation. Furthermore, deposition could be an important source of HgR to the equatorial Pacific Ocean. In contrast, deposition is not a significant source of MMHg to either the equatorial Pacific Ocean or the remote seepage lakes of Wisconsin. This implies that methylated mercury is formedin situ in these systems.  相似文献   
10.
A semi-analytic solution for the migration of dilute reactive contaminant species in a fractured medium having a one-, two- or three-dimensional fracture network is presented. The application of the technique to practical problems is discussed and illustrated by examples. The effects of sorption in the matrix and on the surface of the fractures are considered for a range of parameters. It is demonstrated that the synergistic interaction of the various parameters is such that the effect of changing a single variable may not be immediately obvious and a designer should perform computations for the range of expected parameters to determine the maximum impact. For example, it is shown that it is not necessarily conservative to consider only one-dimensional or only three-dimensional diffusion into the matrix; which of these cases is most critical will depend on the values of other parameters. It is also shown that an effective leachate collection system may significantly reduce the impact of those contaminants which do escape into the fractured media.  相似文献   
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