Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

敦煌-格尔木铁路沿线风动力环境特征     

鱼燕萍  张克存  安志山  张余 《中国沙漠》2020,40(1):41-48

敦煌-格尔木铁路沿线地形复杂、起沙因素多变、沙源丰富，沙害问题日益严重。目前对其风沙活动规律还未有研究，不利于防沙工作的开展。为此，通过对自北向南的5个观测点（S1、S2、S3、S4、S5）风速和风向的观测、计算和分析，利用平均风速、起沙风况及输沙势对敦格铁路沿线的风动力环境特征进行研究。结果表明：S5、S4和S3的风况对铁路风沙灾害防治意义较大。S5年平均风速、起沙风频率和输沙势最大，春季风沙活动最为强烈，且风向单一、风力强劲，风沙运动方向基本与铁路垂直，沙粒易在铁路附近堆积。S4夏季风沙活动最为强烈；S3春季风沙活动最为强烈，且风向单一，S4和S3的风沙运动方向与铁路夹角小于90°，附近沙源广阔，铁路易受风沙侵蚀，阻碍交通运营。  相似文献   

Earth rotation in the hipparcos reference frame     

J. Vondrak  C. Ron  I. Pešek 《Celestial Mechanics and Dynamical Astronomy》1996,66(1):115-122

New determination of the Earth orientation parameters (EOP), based on optical astrometry observations since the beginning of the century, is now under preparation by the Working group established by Commission 19 of the IAU. The Hipparcos catalog is to define the celestial reference frame in which the new series of EOP are to be described, The novelties of the prepared solution are the higher resolution (5 days) and more parameters estimated from the solution (celestial pole offsets, rheological parameters of the Earth, certain instrumental constants). The mathematical model of the solution is described, and the results based on the observations made with 46 instruments at 29 observatories and a preliminary Hipparcos catalog are presented.  相似文献   

UV Leo: The Binary with the Two Suns     

G. Djurašević  P. Rovithis  H. Rovithis-Livaniou  E. Fragoulopoulou 《Astrophysics and Space Science》2005,296(1-4):311-314

BV light curves of the eclipsing binary UV Leo obtained at the Kryonerion Astronomical Station of the National Observatory of Athens, Greece, are analyzed. The analysis is based on a Roche configuration with two spots on the secondary surface. The elements of the two components of the system are calculated and the spot characteristics are given.  相似文献   

The nature of parallax microlensing events towards the Galactic bulge     

Martin C. Smith  Vasily Belokurov  N. Wyn Evans  Shude Mao  Jin H. An 《Monthly notices of the Royal Astronomical Society》2005,361(1):128-140

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The estimate of the deceleration in the earth's rotation due to the sun     

Milan Burša 《Earth, Moon, and Planets》1992,56(1):57-60

The tidal long-term decrease in the angular velocity of the Earth's rotation has been estimated on the basis of the angular momentum tidal balance in the Earth-Moon-Sun system. The observed (LLR) tidal long-term decrease in the Moon's mean motion, the apparent secular acceleration in the mean longitude of the Sun and the long-term decrease in the 2nd degree zonal geopotential parameter were used.Presented at the XXth General Assembly of the I.A.G., Vienna, August 15, 1991.  相似文献   

Modeling the distribution of aluminum speciation in acid soil solution equilibria with the mineral phase alunite     

S. Bi  S. An  W. Tang  M. Yang  H. Qian  J. Wang 《Environmental Geology》2001,41(1-2):25-36

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Red-violet asymmetry in pearl satellites' birth     

F.Z. Feygin  YU.P. Kurchashov  V.A. Troitskaya  K. Dobeš 《Planetary and Space Science》1985,33(3):271-273

A high resolution numerical sonagram of Pc-1 magnetic record has shown that single narrow lines of Pc-1 spectra produce lower frequency (“red-shifted”) satellite lines more than twice as often as their higher frequency (“violet”) counterparts. The violet satellites usually emerge only when at least two ancestor lines are present simultaneously.  相似文献   

Evidence for interacting loop process in a phase of the May 16, 1981 flare     

B. Vršnak  V. Ruždjak  M. Messerotti  P. Zlobec 《Solar physics》1987,111(1):23-29

The behaviour of the flare in the period of enhancement and maximum of hard X-ray, microwave and decimetric type IV continuum is analysed. The elongation of the H ribbons and microwave source disclose that the energy release site was shifting through a system of loops with a velocity less than 200 km s^-1, and that the energy was carried down the field lines with a velocity of about 1000 km s^-1, implying the thermal conduction front mechanism of energy transport. Several processes of energy release are considered and it is concluded that an explanation in terms of succeeding interactions of neighbouring loops, involving fast reconnection of their poloidal components is in best agreement with the observations.Proceedings of the Second CESRA Workshop on Particle Acceleration and Trapping in Solar Flares, held at Aubigny-sur-Nère (France), 23–26 June, 1986.  相似文献   

Deceleration in the Earth's rotation due to the Sun     

Milan Burša 《Studia Geophysica et Geodaetica》1991,35(3):145-150

Summary The estimate of the tidal long-term decrease in the angular velocity of the Earth's rotation due to the Sun is given as –(0.8±0.3)×10 ^–22 rad s ^–2. It was computed on the basis of the observed total long-term decrease in , of the observed tidal deceleration of the Moon and the observed decrease in the second-degree zonal Stokes geopotential harmonic term. Adopting the estimate given, the product of the Love number and the tidal phase lag angle due to the Sun (in degrees) comes out as 0.53±0.20.

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am a z nuuu u z mu au u, az : –(0,8±0,3) 10 ^–22 a¶rt; ^–2 . ¶rt; ua n a¶rt;a u , n a¶rt;a nuu u ¶rt;z ¶rt;uu u n a¶rt;a u mz az znmuaz naama ma. u num n au, m nu¶rt;u ua a a z u ( za¶rt;a) a z nuua a (0,53±0,20).

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