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1.
乙酰褐藻酸丙二酯的制备与表征 总被引：1，自引：0，他引：1
为了改变褐藻酸丙二酯的溶解性,本文以氢碘酸为催化剂,将褐藻酸丙二酯与乙酐反应,制备了乙酰褐藻酸丙二酯。生成物不溶于水,可溶于多种中等极性的有机溶剂。本文用IR,~1H-NMR,HGPC对其进行了表征,并对反应条件对产率的影响进行了探讨。 相似文献
2.
通过对惠民南坡前中生代断裂的平面分布和三维地震剖面特征的分析,识别出了一组在平面上相互平行,在剖面上具有负花状构造的北北西向走滑断裂带。通过对负花状构造的形态及其卷入地层特征的分析,认为该组断裂带经历过两期不同性质的走滑运动,在中生代经历了较强的左行张性走滑,在新生代经历了较弱的右行压性走滑。其演化过程与鲁西地块上北北西向走滑断层的演化过程一致,均属于郯庐断裂区域性走滑作用所形成的帚状构造体系的一部分,郯庐断裂在中生代的左行走滑和新生代的右行走滑是控制其发展演化的主要因素。 相似文献
3.
PGE geochemistry of Jiding ophiolite in Tibet and its constraint on mantle processes 总被引：3，自引：0，他引：3
XIA Bin CHEN Genwen MEI Houjun GUO Lingzhi XIAO Xuchang YU Hengxiang QI Liang WANG Guoqiang Zhong Zhihong 《中国科学D辑(英文版)》2001,44(11):1019-1028
The total PGE amount (σPGE) of mantle peridotite in the Jiding ophiolite is slightly higher than that of the primitive mantle,
but the PGE contents of basalt are higher than those of the mid-ocean ridge basalt (MORB), with obviously lower Pd/Ir ratios.
The accumulates, dyke swarm and basalts show remarkable negative Pt and positive Rh anomalies, resulting in the special N-type
PGE patterns. Mantle peridotite and crustal rocks have similar distribution patterns. It is proposed that the PGE distribution
patterns in the Jiding ophiolite are closely related with a higher degree of partial melting of the mantle in this region.
Magmatic crystallization-differentiation led to PGE fractionation, thus making the contents of PGE in the accumulates decrease
in the ascending direction. The higher content of Au in the Jiding ophiolite is the result of metasomatic alteration at later
stages. Pt-Pd fractionation indicates that both the PGEs are controlled by their alloy and sulfide phases. Positive Rh anomalies
seem to be related with higher oxygen fugacity in the melts. 相似文献
4.
狮吼山矿区是江西省内规模最大的矽卡岩型硫铁多金属矿床,伴生W、Cu、Au多种成矿元素,成矿作用与矿区出露的茶山迳复式花岗岩体有关。岩体主要包括茶山迳似斑状黑云母二长花岗岩和莲湖细粒二长花岗岩两期,为研究成矿岩体的侵位时代、岩石成因及与成矿的关系,本次工作进行了U-Pb锆石定年、岩相学和岩石地球化学等测试分析。结果表明：岩体具有高硅、高钾、富铝的特征,属高钾钙碱性系列花岗岩;轻重稀土元素分馏明显,均为右倾型,弱Eu负异常,以富集Cs、Rb、Th、U、Pb,亏损Ba、Nb、Sr、和Ti等元素为主要特征,属于低Ba-Sr壳源花岗岩类;锆石具较好晶形,具典型岩浆锆石特征,利用LA-ICP-MS进行U-Pb测年,获得谐和年龄为（162.4±0.6）Ma（MSWD=1.8）,加权平均年龄为（162.4±1.4）Ma（MSWD=1.4）,谐和年龄与加权平均年龄在误差范围内高度一致,表明茶山迳复式岩体侵位于燕山早期中侏罗世;综合考虑岩体矿物组合、主微量元素及高分异特征,认为其成因分类应属于S型花岗岩;对比中国花岗岩成矿元素平均含量,茶山迳两期花岗岩均具有较高的W、Mo、Bi、Pb等成矿元素含量,可同时为成矿作用提供热源、流体及物质。 相似文献
5.
The sandstone-type Cu deposits in the Chuxiong Basin occur in the Cretaceous Gaofengsi Formation and the Maotoushan Formation and the orebodies are stratoid and lenticular in form, structurally controlled by their stratigraphical position. Ore structures are dominated by impregnated and striped ones. In addition, it has been observed that copper mineralization is controlled by water-discharge and deformation structures. Orebodies are commonly seen on the gently inclined limbs of the anticline, with the involution front. Copper mineralization shows a distinct zonation. S, Pb isotope and REE data suggest that the copper would stem from the country rocks and the sulfur largely from the lower strata. During diagenesis oxidized Cu-bearing brines derived from the upper parts and reduced brines from the lower parts are involved in metallogenetic reactions in the stress neutral plane, which is the key to the formation of copper deposits in the Chuxiong Basin.
相似文献6.
The sandstone-type Cu deposits in the Chuxiong Basin occur in the Cretaceous Gaofengsi Formation and the Maotoushan Formation and the orebodies are stratoid and lenticular in form, structurally controlled by their stratigraphical position. Ore structures are dominated by impregnated and striped ones. In addition, it has been observed that copper mineralization is controlled by water-discharge and deformation structures. Orebodies are commonly seen on the gently inclined limbs of the anticline, with the involution front. Copper mineralization shows a distinct zonation. S, Pb isotope and REE data suggest that the copper would stem from the country rocks and the sulfur largely from the lower strata. During diagenesis oxidized Cu-bearing brines derived from the upper parts and reduced brines from the lower parts are involved in metallogenetic reactions in the stress neutral plane, which is the key to the formation of copper deposits in the Chuxiong Basin. 相似文献
7.
介绍了建立高阶引力理论（该理论用以修正爱因斯坦广义相对论）的物理背景,并讨论了暗物质问题。对几种主要高阶引力理论及其解作了评述,并尝试在不必假定暗物质存在的情况下,用高阶引力理论解决有关星系旋转曲线的困难。但令人遗憾的是,至今还没有一个理论取得完全的成功。指出了解决这一问题面临的困难,并建议寻找新的高阶引力理论。 相似文献
8.
About three quarters of superlarge porphyry copper deposits throughout the world occur along the eastern Pacific basin rim, most of which were formed during the Mesozoic-Cenozoic. Porphyry copper deposits often occur in the upper parts of a subduction zone and in a within-plate orogenic belt. Some porphyry copper deposits are inconsistent with plate subduction with respect to their formation time, and most of them in the world are associated with tensional environment. Metallogenic porphyries originated from the mantle, and the involvement of the lower-crust or oceanic crust materials have played an important role. Based on the geochemical characteristics and tectonic settings of the ore-bearing porphyries in the Gandise and Yulong metallogenic zones, it is proposed that delamination may be the important mechanism of formation of porphyry copper deposits. 相似文献
9.
本数据集综合应用岩性-构造-矿化蚀变专项填图、遥感、物探、化探、钻探等多种方法进行数据采集,完成路线调查长度520.65 km,采集水系沉积物样品2 047件,遥感数据解译面积461 km2,化学分析样167件。重点对燕山早期成矿岩浆岩、含矿建造、控岩控矿构造,以及矿化蚀变标志等进行了调查划分,明确区内银金多金属矿主要成矿地质体为燕山早期花岗闪长岩,控岩控矿构造为北东向逆冲断裂及其次级裂隙。在此基础上,编制了1：50 000银坑幅建造构造图,利用数字化填图系统（DGSS）创建了区内矿产地质图数据库,全面汇编了重要建造构造、地质界线、断裂、岩浆岩等图层属性库;完善了银坑式中低温岩浆期后热液矿床找矿预测模型,突出了区内矿产与建造构造之间的成因联系。 相似文献
10.
前人对河台金矿中的假玄武玻璃早有报道,但是因为未认识到其与成矿的关系而被忽视。在前人发现的糜棱岩中假玄武玻璃的基础上,本次研究又发现了三种其他岩性中的假玄武玻璃。河台金矿中的假玄武玻璃呈黑色脉状、网脉状和树枝状贯穿于糜棱岩化片岩、糜棱岩、混合岩和矿体中。本研究结合野外宏观特征和室内的岩相学微观特征,运用粉晶X射线衍射、全岩地球化学和Ar-Ar同位素等实验分析手段,比较了河台金矿不同地质体中假玄武玻璃岩脉的特征。研究发现假玄武玻璃脉体中存在树枝状微晶结构和碎屑颗粒的港湾结构,同时也含有碎裂成因的石英、长石,表明其成因以同震断层的摩擦熔融为主,并伴随有少量碎裂化。通过计算得出假玄武玻璃样品中结晶态的各类矿物含量为石英53.3%、伊利石20.5%、高岭石17.3%、钾长石8.9%。假玄武玻璃与围岩都具有富SiO_2和Al_2O_3,富K_2O贫Na_2O,低MgO和Fe_2O_3~T的地球化学特征。两者的稀土元素配分型式也非常相似,都显示轻稀土富集和中等程度的负Eu异常(δEu=0.51～0.71)。假玄武玻璃的显微构造和地球化学特征指示其主要是由围岩原地熔融形成的,形成深度在6～18 km。我们认为河台金矿的假玄武玻璃可以指示云开大山抬升过程中伴随着地震的发生,同时,假玄武玻璃脉体在空间上切穿矿体,因此假玄武玻璃的40Ar/39Ar年龄123.3±1.0 Ma可以作为河台金矿的成矿年龄上限。 相似文献