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1.
It is often desirable or necessary to store collected seawater samples prior to analysis for dissolved inorganic nutrients. It is therefore important to establish preservation and storage techniques that will ensure sample integrity and will not alter the precision or accuracy of analysis. We have performed a series of experiments on the storage of nutrient samples collected at the oligotrophic North Pacific benchmark Station ALOHA, using both standard autoanalyses and low-level techniques. Our results reveal that for oligotrophic oceanic waters, the immediate freezing of an unfiltered water sample in a clean polyethylene bottle is a suitable preservation method. This procedure is simple, it avoids potentially contaminating sample manipulations and chemical additions, and it adequately preserves the concentrations of nitrate + nitrite, soluble reactive phosphate, and soluble reactive silicate within a single water sample.  相似文献   
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The Budyko framework characterizes landscape water cycles as a function of climate. We used this framework to identify regions with contrasting hydroclimatic change during the past 50 years in Sweden. This analysis revealed three distinct regions: the mountains, the forests, and the areas with agriculture. Each region responded markedly different to recent climate and anthropogenic changes, and within each region, we identified the most sensitive subregions. These results highlight the need for regional differentiation in climate change adaptation strategies to protect vulnerable ecosystems and freshwater resources. Further, the Budyko curve moved systematically towards its water and energy limits, indicating augmentation of the water cycle driven by changing vegetation, climate and human interactions. This finding challenges the steady state assumption of the Budyko curve and therefore its ability to predict future water cycles. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   
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A plot of median grain size against quartile deviation (after Buller and McManus) can be used to distinguish mudflow deposits. A characteristic envelope for poorly sorted streamflow deposits is also defined. Unlike most other sediment transport mechanisms, mudflows appear to deposit sediments with sorting independent of median grain size.  相似文献   
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The proper identification and removal of outliers in the combination of rates of vertical displacements derived from GPS, tide gauges/satellite altimetry, and GRACE observations is presented. Outlier detection is a necessary pre-screening procedure in order to ensure reliable estimates of stochastic properties of the observations in the combined least-squares adjustment (via rescaling of covariance matrices) and to ensure that the final vertical motion model is not corrupted and/or distorted by erroneous data. Results from this study indicate that typical data snooping methods are inadequate in dealing with these heterogeneous data sets and their stochastic properties. Using simulated vertical displacement rates, it is demonstrated that a large variety of outliers (random scattered and adjacent, as well as jointly influential) can be dealt with if an iterative re-weighting least-squares adjustment is combined with a robust median estimator. Moreover, robust estimators are efficient in areas weakly constrained by the data, where even high quality observations may appear to be erroneous if their estimates are largely influenced by outliers. Four combined models for the vertical motion in the region of the Great Lakes are presented. The computed vertical displacements vary between  − 2 mm/year (subsidence) along the southern shores and 3 mm/year (uplift) along the northern shores. The derived models provide reliable empirical constraints and error bounds for postglacial rebound models in the region.  相似文献   
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The obduction of an ophiolite sheet onto the eastern Pelagonian carbonate platform complex of the Hellenides began during the Late Bathonian and ended with the final emplacement of the ophiolite during Valanginian time. The early stages of obduction caused subaerial exposure of the platform, recorded by an unconformity of Callovian age, which is marked by laterites overlying folded and faulted, karstic substrates. The laterites have distinct ophiolitic geochemical signatures, indicating that emergent ophiolite had been undergoing lateritic weathering. This unconformity coincides with widespread western Tethyan, Callovian gaps, indicating that the obduction in the Hellenides was probably related to far-reaching plate tectonic processes. Resumed gravitational pull and rollback of the subducted, oceanic leading edge of the temporarily exposed ophiolite. Platform drowning continued into Tithonian–Valanginian time, documented initially by reefal carbonates and then by below-CCD, carbonate-free radiolarian cherts and shales. Subsequently, siliciclastic turbidites, which apparently originated from uplifted Variscan basement, were deposited together with and over the radiolarite as the ophiolite nappe sheet advanced. The nappe substrate underwent tectonic deformations of varying intensity, while polymictic mélange and syntectonic sedimentary debris accreted beneath the ophiolite and at the nappe front. The provenience of the ophiolite nappe complexes of northern Evvoia most probably has to be looked for in the Vardar ocean.  相似文献   
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Reducing fossil fuel supply is necessary to meet the Paris Agreement goal to keep warming ‘well below 2°C’, yet the Agreement is silent on the topic of fossil fuels. This article outlines reasons why it is important that Parties to the Agreement find ways to more explicitly address the phasing out of fossil fuel production under the UNFCCC. It describes how countries aiming to keep fossil fuel supply in line with Paris goals could articulate and report their actions within the current architecture of the Agreement. It also outlines specific mechanisms of the Paris Agreement through which issues related to the curtailment of fossil fuel supply can be addressed. Mapping out a transition away from fossil fuels – and facilitating this transition under the auspices of the UNFCCC process – can enhance the ambition and effectiveness of national and international climate mitigation efforts.

Key policy insights

  • The international commitment to limit global average temperature increases to ‘well below 2°C’ provides a strong rationale for Parties to the Paris Agreement and the UNFCCC to pursue a phase-down in fossil fuel production, not just consumption.

  • Several countries have already made commitments to address fossil fuel supply, by agreeing to phase down coal or oil exploration and production.

  • Integrating these commitments into the UNFCCC process would link them to global climate goals, and ensure they form part of a broader global effort to transition away from fossil fuels.

  • The Paris Agreement provides a number of new opportunities for Parties to address fossil fuel production.

  相似文献   
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Galactic cosmic rays consist of primary and secondary particles. Primary cosmic rays are thought to be energized by first order Fermi acceleration processes at supernova shock fronts within our Galaxy. The cosmic rays that eventually reach the Earth from this source are mainly protons and atomic nuclei, but also include electrons. Secondary cosmic rays are created in collisions of primary particles with the diffuse interstellar gas. They are relatively rare but carry important information on the Galactic propagation of the primary particles. The secondary component includes a small fraction of antimatter particles, positrons and antiprotons. In addition, positrons and antiprotons may also come from unusual sources and possibly provide insight into new physics. For instance, the annihilation of heavy supersymmetric dark matter particles within the Galactic halo could lead to positrons or antiprotons with distinctive energy signatures. With the High-Energy Antimatter Telescope (HEAT) balloon-borne instrument, we have measured the abundances of positrons and electrons at energies between 1 and 50 GeV. The data suggest that indeed a small additional antimatter component may be present that cannot be explained by a purely secondary production mechanism. Here we describe the signature of the effect and discuss its possible origin.  相似文献   
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LandStar is a differential global positioning service (DGPS) that provides 24-h real-time positioning for various applications on land, water, and air in North America, Australia, New Zealand, Europe, and Africa. Its focus is on real-time applications requiring a submeter positioning capability such as agriculture, forestry, Geospatial Information Systems (GIS), survey/mapping, and land/vehicular navigation. LandStar uses a Wide Area Network of reference stations to derive DGPS corrections to model the variation of GPS error sources over a large area. These model parameters are used by the Virtual Reference Station processors to calculate standard corrections that are available for all predefined locations in the network. The corrections are transmitted to the user by L-band satellite communication in the standard RTCM SC104 DGPS correction format. This article investigates the performance of the LandStar Mk III system under various operational conditions and assesses its performance in both static and kinematic modes. Four field tests were conducted during 12 months that tested the sysem in clear static and kinematic conditions as well as suboptimal environments associated with low and heavy foliage conditions. Both the accuracy and availability of the system under these conditions is investigated, with an emphasis on whether the above variables are caused by the LandStar system differential corrections, the GPS measurements, or a combination of both. ? 1999 John Wiley & Sons, Inc.  相似文献   
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