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Rodrigo de Freitas Lagoon, located in the Rio de Janeiro City, receives several types of polluted discharges. The knowledge of the sediment microfauna correlated with heavy metal and organic matter concentrations could supply important data about the conditions of the lagoon. The benthic foraminiferal assemblage presented larger diversity and more abundant samples in the lagoon entrance than in the inner area. The Ammonia tepida - Elphidiumexcavatum foraminiferal assemblage is characterized by dwarf, corroded and weak organisms. Agglutinated species were found only near the entrance. Low abundance values and sterility of five samples in the inner area (north/northeast) can be caused by high levels of heavy metals and organic matter. A. tepida shows negative correlation with increasing heavy metals values. PAHs and coprostanol high indexes, and the absence or low presence of microfauna in samples around the lagoon margin confirm illegal flows from gas stations and domestic sewage.  相似文献   
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As karst systems are natural windows to the underground, speleology, combined with geological surveys, can be useful tools for helping understand the geological evolution of karst areas. In order to enhance the reconstruction of the structural setting in a gypsum karst area (Vena del Gesso, Romagna Apennines), a detailed analysis has been carried out on hypogeal data. Structural features (faults, fractures, tectonic foliations, bedding) have been mapped in the ”Grotta del Re Tiberio” cave, in the nearby gypsum quarry tunnels and open pit benches. Five fracture systems and six fault systems have been identified. The fault systems have been further analyzed through stereographic projections and geometric-kinematic evaluations in order to reconstruct the relative chronology of these structures. This analysis led to the detection of two deformation phases. The results permitted linking of the hypogeal data with the surface data both at a local and regional scale. At the local scale, fracture data collected in the underground have been compared with previous authors’ surface data coming from the quarry area. The two data sets show a very good correspondence, as every underground fracture system matches with one of the surface fracture system. Moreover, in the cave, a larger number of fractures belonging to each system could be mapped. At the regional scale, the two deformation phases detected can be integrated in the structural setting of the study area, thereby enhancing the tectonic interpretation of the area (e.g., structures belonging to a new deformation phase, not reported before, have been identified underground). The structural detailed hypogeal survey has, thus, provided very useful data, both by integrating the existing information and revealing new data not detected at the surface. In particular, some small structures (e.g., displacement markers and short fractures) are better preserved in the hypogeal environment than on the surface where the outcropping gypsum is more exposed to dissolution and recrystallization. The hypogeal geological survey, therefore, can be considered a powerful tool for integrating the surface and log data in order to enhance the reconstruction of the deformational history and to get a three-dimensional model of the bedrock in karst areas.  相似文献   
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A new maturity parameter determined on both oil and bitumen samples, the asphaltene Tmax, is proposed and discussed. This parameter could be very useful to address the maturity of the source rock. The asphaltene Tmax is measured by programmed Rock-Eval pyrolysis, using a modified temperature program. Some phases of the experimental procedure, such as the asphaltene preparation and the Rock-Eval measurement substratum choice, are crucial in order to achieve reliable data. Laboratory simulations were carried out in order to assess the possible effects of both primary and secondary migration on asphaltene Tmaxin the expelled oil: the original value of the asphaltene Tmax in the bitumen is not substantially modified and it is very close to that measured on kerogen. Examples of the determination of asphaltene Tmax on many samples, collected from different areas and with different organic matter composition, are given. Results show that Tmax values from oil asphaltenes are reasonable indicators of source rock maturity.  相似文献   
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A new method for analysis of acidic polar compounds, is described and discussed. It allows the simultaneous quantification of carboxylic acids, phenols and carbazoles and combines accuracy with a short turnaround time, a requirement strictly necessary for industrial applications. Routinely use of this methodology (more than 50 applications in many different sedimentary basins) has supplied many important pieces of information about oil origin, maturity, biodegradation and, in particular, has allowed to define a molecular migration index (MMI), based on relative abundance of phenol and alkyl phenols. The combination of well-established geochemical tools focused on saturated and aromatic fractions (such as biomarkers, compound specific isotope ratio analysis, and GC fingerprinting) with this methodology results in the definition of an integrated interpretative sequence. This last enhances the quality of interpretations through cross-checks and permits a better exploitation of oil samples by using also their less explored fraction, i.e. the polar compounds. Application results of this methodology are only shortly mentioned in this paper, which is mainly focused on analytical aspects. The results will be more extensively discussed in a future publication.  相似文献   
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