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1.
Giada Iacono Marziano Burkhard C. Schmidt Daniela Dolfi 《Journal of Volcanology and Geothermal Research》2007
Equilibrium and disequilibrium degassing of a volatile phase from a magma of K-phonolitic composition was investigated to assess its behavior upon ascent. Decompression experiments were conducted in Ar-pressurized externally heated pressure vessels at superliquidus temperature (1050 °C), in the pressure range 10–200 MPa using pure water as fluid phase. All experiments were equilibrated at 200 MPa and then decompressed to lower pressures with rates varying from 0.0028 to 4.8 MPa/s. Isobaric saturation experiments were performed at the same temperature and at 900–950 °C to determine the equilibrium water solubility in the pressure range 30–250 MPa. The glasses obtained from decompression experiments were analyzed for their dissolved water content, vesicularity and bubble size distribution. All decompressed samples presented a first event of bubble nucleation at the capsule–melt interface. Homogeneous bubble nucleation in the melt only occurred in fast-decompressed experiments (4.8 and 1.7 MPa/s), for ΔP ≅ 100 MPa. For these decompression rates high water over-saturations were maintained until a rapid exsolution was triggered at ΔP > 150 MPa. For slower rates (0.0028, 0.024, 0.17 MPa/s) the degassing of the melt took place by diffusive growth of the bubbles nucleating at the capsule–melt interface. This process sensibly reduced water over-saturation in the melt, preventing homogeneous nucleation to occur. For decompression rates of 0.024 and 0.17 MPa/s low water over-saturations were attained in the melt, gradually declining toward equilibrium concentrations at low pressures. A near-equilibrium degassing path was observed for a decompression rate of 0.0028 MPa/s. Experimental data combined with natural pumice textures suggest that both homogeneous and heterogeneous bubble nucleations occurred in the phonolitic magma during the AD 79 Vesuvius plinian event. Homogeneous bubble nucleation probably occurred at a depth of ∼ 3 km, in response to a fast decompression of the magma during the ascent. 相似文献
2.
Stefano Silvestri Salvador Ivorra Laura Di Chiacchio Tomaso Trombetti Dora Foti Giada Gasparini Luca Pieraccini Matt Dietz Colin Taylor 《地震工程与结构动力学》2016,45(1):69-89
According to Eurocode 8, the seismic design of flat‐bottom circular silos containing grain‐like material is based on a rough estimate of the inertial force imposed on the structure by the ensiled content during an earthquake: 80% of the mass of the content multiplied by the peak ground acceleration. A recent analytical consideration of the horizontal shear force mobilised within the ensiled material during an earthquake proposed by some of the authors has resulted in a radically reduced estimate of this load suggesting that, in practice, the effective mass of the content is significantly less than that specified. This paper describes a series of laboratory tests that featured shaking table and a silo model, which were conducted in order to obtain some experimental data to verify the proposed theoretical formulations and to compare with the established code provisions. Several tests have been performed with different heights of ensiled material – about 0.5 mm diameter Ballotini glass – and different magnitudes of grain–wall friction. The results indicate that in all cases, the effective mass is indeed lower than the Eurocode specification, suggesting that the specification is overly conservative, and that the wall–grain friction coefficient strongly affects the overturning moment at the silo base. At peak ground accelerations up to around 0.35 g, the proposed analytical formulation provides an improved estimate of the inertial force imposed on such structures by their contents. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
3.
Frenzilli G Bocchetti R Pagliarecci M Nigro M Annarumma F Scarcelli V Fattorini D Regoli F 《Marine environmental research》2004,58(2-5):609-613
Harbours can be considered as model environments for developing and validating field monitoring procedures and to investigate mechanistic relationships between different biological responses. In this study several biomarkers were investigated in marine mussels caged for 4 weeks (June-July 2001) into an industrialized harbour of NW Italy. Organisms were collected at different time-intervals to better characterize the sensitivity, temporal variations and interactions of analysed responses. Besides single antioxidants the total oxyradical scavenging capacity (TOSC) assay was used to analyse the capability of the whole antioxidant system to neutralize specific forms of radicals: these data were further integrated by measurement of DNA integrity, oxidized bases and the impairment of lysosomal membrane stability in haemocytes. Results showed a biphasic trend for single antioxidants and TOSC, with an increase during the first 2 weeks of exposure to the polluted site followed by a progressive decrease up to a severe depletion in the final part of the experiment. 相似文献
4.
Valeriano Parravicini Carla Morri Giada Ciribilli Monica Montefalcone Giancarlo Albertelli Carlo Nike Bianchi 《Estuarine, Coastal and Shelf Science》2009,81(3):359-367
The performances of two commonly used non-destructive sampling procedures for rocky benthic assemblages (i.e. photography and visually assessed quadrats) were compared. A damaging human activity, date mussel (Lithophaga lithophaga) harvesting (DMH), was chosen. Directly impacted sites were compared with reference conditions (controls). Both visual quadrats and photography were equally able to detect differences between impacted situations and controls. However, visual quadrats showed high variability among replicates and estimated higher species richness for controls, while photography did so for impacts. Pooling photos in a ‘sum photo quadrat’ showed that differences between the two methods are due to sampling unit size rather than sampling procedure itself. As a small sampling unit is unavoidable with photography, visual quadrats should be preferred in investigating shallow rocky reefs for their larger size; however, longer working time underwater with quadrats does not allow for numerous replicates. Pooling many photos to reach sampling sizes comparable with those of quadrats may be a valid alternative to reconcile image resolution and areal coverage. 相似文献
5.
Giada Frenzilli Raffaella Bocchetti Massimiliano Pagliarecci Marco Nigro Francesca Annarumma Vittoria Scarcelli Daniele Fattorini Francesco Regoli 《Marine environmental research》2004,58(2-5):609
Harbours can be considered as model environments for developing and validating field monitoring procedures and to investigate mechanistic relationships between different biological responses. In this study several biomarkers were investigated in marine mussels caged for 4 weeks (June–July 2001) into an industrialized harbour of NW Italy. Organisms were collected at different time-intervals to better characterize the sensitivity, temporal variations and interactions of analysed responses. Besides single antioxidants the total oxyradical scavenging capacity (TOSC) assay was used to analyse the capability of the whole antioxidant system to neutralize specific forms of radicals: these data were further integrated by measurement of DNA integrity, oxidized bases and the impairment of lysosomal membrane stability in haemocytes. Results showed a biphasic trend for single antioxidants and TOSC, with an increase during the first 2 weeks of exposure to the polluted site followed by a progressive decrease up to a severe depletion in the final part of the experiment. 相似文献
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7.
This paper concerns the hydromechanical stability of partially saturated soils during wetting. The response of a loose silty sand is numerically/theoretically investigated with the main aim of identifying both triggering mechanisms and predisposing factors to instability. This latter is testified by both a rapid increase in the pore water pressure and an unexpected loss of numerical convergence. The study has been conducted at different scales from laboratory tests to boundary value problems, and in both cases, the controllability theory has been employed to both interpret and justify the numerical results. 相似文献
8.
Michele Palermo Stefano Silvestri Giada Gasparini Tomaso Trombetti 《Bulletin of Earthquake Engineering》2013,11(5):1467-1491
This paper gives a new insight into the linear dynamic behavior of one-storey eccentric systems, with particular attention devoted to provide a comprehensive physically-based formulation of the maximum corner displacement magnification, which involves three contributions (translational response, torsional response and their combination). It is shown that the largest magnifications, which mainly occur for the class of torsionally-flexible systems, are due to the translational contribution which is caused by the shift of the fundamental period of the eccentric system with respect to that of the equivalent not-eccentric system. A simplified method for the estimation of the maximum corner displacement under seismic excitation, based on the physical properties of the eccentric system, is finally proposed. 相似文献
9.
Priscille Lesne Bruno Scaillet Michel Pichavant Giada Iacono-Marziano Jean-Michel Beny 《Contributions to Mineralogy and Petrology》2011,162(1):133-151
Experiments were conducted to determine the water solubility of alkali basalts from Etna, Stromboli and Vesuvius volcanoes,
Italy. The basaltic melts were equilibrated at 1,200°C with pure water, under oxidized conditions, and at pressures ranging
from 163 to 3,842 bars. Our results show that at pressures above 1 kbar, alkali basalts dissolve more water than typical mid-ocean
ridge basalts (MORB). Combination of our data with those from previous studies allows the following simple empirical model
for the water solubility of basalts of varying alkalinity and fO2 to be derived:
\textH 2 \textO( \textwt% ) = \text H 2 \textO\textMORB ( \textwt% ) + ( 5.84 ×10 - 5 *\textP - 2.29 ×10 - 2 ) ×( \textNa2 \textO + \textK2 \textO )( \textwt% ) + 4.67 ×10 - 2 ×\Updelta \textNNO - 2.29 ×10 - 1 {\text{H}}_{ 2} {\text{O}}\left( {{\text{wt}}\% } \right) = {\text{ H}}_{ 2} {\text{O}}_{\text{MORB}} \left( {{\text{wt}}\% } \right) + \left( {5.84 \times 10^{ - 5} *{\text{P}} - 2.29 \times 10^{ - 2} } \right) \times \left( {{\text{Na}}_{2} {\text{O}} + {\text{K}}_{2} {\text{O}}} \right)\left( {{\text{wt}}\% } \right) + 4.67 \times 10^{ - 2} \times \Updelta {\text{NNO}} - 2.29 \times 10^{ - 1} where H2OMORB is the water solubility at the calculated P, using the model of Dixon et al. (1995). This equation reproduces the existing database on water solubilities in basaltic melts to within 5%. Interpretation of
the speciation data in the context of the glass transition theory shows that water speciation in basalt melts is severely
modified during quench. At magmatic temperatures, more than 90% of dissolved water forms hydroxyl groups at all water contents,
whilst in natural or synthetic glasses, the amount of molecular water is much larger. A regular solution model with an explicit
temperature dependence reproduces well-observed water species. Derivation of the partial molar volume of molecular water using
standard thermodynamic considerations yields values close to previous findings if room temperature water species are used.
When high temperature species proportions are used, a negative partial molar volume is obtained for molecular water. Calculation
of the partial molar volume of total water using H2O solubility data on basaltic melts at pressures above 1 kbar yields a value of 19 cm3/mol in reasonable agreement with estimates obtained from density measurements. 相似文献
10.
The carbonate fraction in carbonatitic Italian lamprophyres 总被引：1，自引：0，他引：1
Alkaline and ultramafic lamprophyres represent the majority of pre-Pleistocene alkaline mafic magmatic activity in Italy and have been described from several localities. The age of magmatism ranges from Triassic to Lower Oligocene. Some contain appreciable amounts of carbonate. The primary carbonate of the Italian carbonatitic lamprophyres is mainly Sr- or Mn-rich calcite that occurs mostly as immiscible ocelli or as groundmass. Its textural occurrence, composition, and relationship with co-precipitating silicate phases is taken as evidence of an igneous origin. Low BaO and REE contents in the carbonate are explained by early crystallization of essential mica and subordinate apatite. Whole rock analyses and isotopic data (Rukhlov, A.S., Bell, K., Vichi, G., Stoppa, F., submitted for publication. The heterogeneous deep mantle: the Sr, Pb and Nd isotopic evidence from Early Cretaceous alkaline lamprophyres of Southern Tuscany, Italy. Lithos.) suggest a mantle origin for these rocks and rule out contamination in either high or low pressure regimes. The bulk compositions of the carbonatitic lamprophyres have high HFSE / LILE and LREE / HREE ratios and although the abundances of these elements are generally lower than for carbonatites s.s., they are comparable with the abundances in other ‘carbonate-free’ Italian lamprophyres and Italian carbonatites, suggesting similar mantle sources. Moreover, the age of the Italian lamprophyres, ranging from Middle Triassic to Lower Oligocene, is much greater than the Pleistocene age of Italian carbonatites and indicates that the source remained similar over a long time span. 相似文献