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1.
Paolo Ferla  Carmelina Meli   《Lithos》2007,99(3-4):266-288
Tourmalinite and tourmaline-rich rocks associated with Fe-carbonate–graphite phyllite, strata-bound polymetallic sulphide deposits, metabasite and marble were studied, for information on the mechanism of tourmaline formation in the pre-Hercynian low-grade metamorphic sequence of the Mandanici Unit in the Peloritani Mountains of Sicily, southern Italy. The major and trace element compositions of the tourmaline rocks suggest the existence of a sedimentary protolith with pre-metamorphic black shale and bedded chert. Boron was interpreted to be accumulated in a restricted sedimentary basin, between platform carbonate formations, with abundant organic matter and Fe–Al–Ti-rich laterite–bauxite soil-derived clastic supply, under a continental volcano-tectonic extensional regime accompanied by a local convective hydrothermal system along faults. Petrographic, crystal–chemical and δ11B isotopic data are compatible with a model of marine sediment dewatering at temperatures below 200 °C, which caused the removal of boron from clay. Metamorphism led to the development of tourmaline in an Al–Ti-rich environment, in equilibrium with other minerals such as ilmenite, albite and muscovite. The upper temperature of metamorphism (almost 375 °C), estimated on the basis of δ11B, fits geothermometric results from Δ13Ccarbonate–graphite on associated rocks. The estimated value of δ11B in the tourmalinite protolith, − 7.5‰ , is also compatible with continental-derived Al-rich sediments.  相似文献   
2.
On the basis of Jeans equations we study some dynamical properties of a sample of E galaxies considered as oblate and prolate spheroids. Although the results emphasize the anisotropy as the dominant dynamical factor both for oblate and prolate configurations, the sample contains some oblate galaxies apparently isotropic consistent with full rotational support. Comparisons of the mass-to-luminosity ratios obtained from our models with ratios derived from recent evolutionary synthesis models do not seem to leave room for nonluminous matter within the ranges (of the order of one de Vaucouleurs' radius) of the kinematical observations. Such comparisons suggest that a flatter than the classical Salpeter IMF would lead to better agreement with the dynamical results obtained within the framework of our models.  相似文献   
3.
We report the results of four soil H2 surveys carried out in 2000–2003 at Poás volcano, Costa Rica, to investigate the soil H2 distribution and evaluate the diffuse H2 emission as a potential surveillance tool for Poás volcano. Soil gas H2 contents showed a wide range of concentration from 0.2 to 7,059 ppmV during the four surveys. Maps of soil gas H2 based on Sequential Gaussian Simulation showed low H2 concentration values in the soil atmosphere (<0.7 ppmV) for most of the study area, whereas high soil gas H2 values were observed inside the active crater of Poás. A significant increase in soil gas H2 concentration was observed inside the active crater during 2001 and 2002 with respect to year 2000, followed by a decrease in 2003. The observed spatial and temporal variations of soil H2 concentration have been well correlated with seismicity, microgravimetry and fumarolic chemistry changes which occurred during this study. These observations evidence changes in the shallow magmatic-hydrothermal system of Poás, and it might be related to a potential magmatic intrusion during the period 1998–2004. Therefore, monitoring diffuse H2 emission of Poás has become an important geochemical tool for the monitoring of its volcanic activity.  相似文献   
4.
A shaking table testing program was undertaken with the main objective of providing basic information for the calibration of analytical models, and procedures for determining seismic response of typical stone masonry temples of the 16–18th centuries stone masonry construction in Mexico. A typical colonial temple was chosen as a prototype. A model at a 1:8 geometric scale was built with the same materials and techniques as the prototype, and was subjected to horizontal and vertical motions of increasing intensities. The maximum applied intensity corresponded to a base shear force of about 58 of the total building weight. Vertical component of the base motion significantly affected the response and increased the damage of the model. Damage patterns were similar to those observed in actual temples. Damping coefficients of the response ranged from 7 for undamaged state, reached about 14 for severe damage. The main features of the measured response were compared with those computed using a nonlinear, finite element model; for the latter, a constitutive law developed for plain concrete was adopted for reproducing cracking and crushing of the irregular stone masonry. Observed damage patterns as well as measured response could be reproduced with reasonable accuracy by the analytical simulation, except for some local vibrations, as those at the top of the bell towers. It can be concluded that the simple constitutive law adopted for the simulation was able to reproduce the experimental response with reasonable level of accuracy. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
5.
Significant changes in the diffuse emission of carbon dioxide were recorded in a geochemical station located at El Hierro, Canary Islands, before the occurrence of several seismic events during 2004. Two precursory CO2 efflux increases started thirteen and nine days before two seismic events of magnitude 2.3 and 1.7, which took place near El Hierro Island, Canary Islands, on March 23 and April 15, reaching a maximun value of 51.1 and 46.2 g m−2 d−1, respectively, five and eight days before the two seismic events. Other similar increases started thirteen and five days before the occurrence of two seismic events of magnitude 1.3 and 1.5 which took place on October 15 and 21 respectively, reaching the maximum values four and one day before the earthquakes. These changes were not related to variations in atmospheric or soil parameters. The Material Failure Forecast Method (FFM), which analyzes the rate of precursory phenomena, was successfully applied to forecast the first seismic event that took place in El Hierro Island in 2004.  相似文献   
6.
The Fe3+/Fetot of all Fe-bearing minerals has been analysed by Mössbauer spectroscopy in a suite of biotite-rich to biotite-free graphitic metapelite xenoliths, proxies of an amphibolite-granulite transition through progressive biotite melting. Biotite contains 9 to 16% Fe3+/Fetot, whereas garnet, cordierite and ilmenite are virtually Fe3+ -free (0–1% Fe3+/Fetot) in all samples, regardless of biotite presence. Under relatively reducing conditions (graphite-bearing assemblages), biotite is the only carrier of Fe3+ during high-temperature metamorphism; therefore, its disappearance by melting represents an important event of iron reduction during granulite formation, because haplogranitic melts usually incorporate small amounts of ferric iron. Iron reduction is accompanied by the oxidation of carbon and the production of CO2, according to the redox reaction:
Depending on the nature of the peritectic Fe-Mg mineral produced (garnet, cordierite, orthopyroxene), the CO2 can either be present as a free fluid component, or be completely stored within melt and cordierite. The oxidation of graphite by iron reduction can account for the in situ generation of CO2, implying a consequential rather than causal role of CO2 in some granulites and migmatites. This genetic model is relevant to graphitic rocks more generally and may explain why CO2 is present in some granulites although it is not required for their formation.  相似文献   
7.
Abstract

Close-range hyperspectral images are a promising source of information in plant biology, in particular, for in vivo study of physiological changes. In this study, we investigate how data fusion can improve the detection of leaf elements by combining pixel reflectance and morphological information. The detection of image regions associated to the leaf structures is the first step toward quantitative analysis on the physical effects that genetic manipulation, disease infections, and environmental conditions have in plants. We tested our fusion approach on Musa acuminata (banana) leaf images and compared its discriminant capability to similar techniques used in remote sensing. Experimental results demonstrate the efficiency of our fusion approach, with significant improvements over some conventional methods.  相似文献   
8.
9.
Reported herein are the results of eight soil CO2 efflux surveys performed from 2006 to 2011 at Timanfaya Volcanic Field (TVF), Lanzarote Island with the aim of evaluating the long- and short-term temporal variations of the diffuse CO2 emission. Soil CO2 efflux values ranged from non-detectable up to 34.2 g m−2 d−1, with the highest values measured in September 2008. Conditional sequential Gaussian simulations (sGs) were applied to construct soil CO2 efflux distribution maps and to estimate the total CO2 output from the studied area at the TVF. Soil CO2 efflux maps showed a high spatial and temporal variability. Total CO2 emission rates ranged between 41 and 518 t d−1, February 2011 (winter) being the season when maximum diffuse CO2 emission rates were observed. To investigate the influence of external variables on the soil CO2 efflux, a geochemical station (LZT01) was installed at TVF to measure continuously the soil CO2 efflux between July 2010 and March 2012 Since external factors such as barometric pressure, rainfall, soil water content, soil and air temperatures, and wind speed influence strongly the observed soil CO2 effluxes, multiple regression analysis was applied to the time series recorded by the automatic geochemical station LZT01 to remove the contribution of these external factors. The influence of meteorological variables on soil CO2 efflux oscillations accounts for 13% of total variance, with barometric pressure, rainfall and/or soil water content having the most influence in the control of the soil CO2 efflux. These observations along with the results from the eight soil gas surveys performed at TVF indicate that the short and long-term trends in the diffuse CO2 degassing are mainly controlled by environmental factors.  相似文献   
10.
The present work reports the results of 15 studies of diffuse CO2 degassing performed at Teide Volcano crater (Canary Island, Spain) and the chemical and isotopic compositions of fluids discharged from a fumarolic field located at the top of the volcano as measured between 1991 and 2010. A higher contribution of magmatic gases accompanied by enhanced total diffuse CO2 emissions were observed in relation with a seismic crisis that occurred in Tenerife Island between 2001 and 2005, with the main peak of seismic activity between April and June 2004. A significant pulse in total diffuse CO2 emission was observed at the crater of Teide (up to 26.3?t day?1) in 2001. In December 2003, the chemical composition of the Teide fumarole changed significantly, including the appearance of SO2, an increase in the HCl and CO concentrations and in the C2H6/C2H4 and C3H8/C3H6 ratios, and a decrease in the H2S, CH4, and C6H6 concentrations and in the gas/steam ratio. A few months after a drastic decrease in seismic activity, the SO2, HCl, and CO concentrations and the C2H6/C2H4 and C3H8/C3H6 ratios strongly decreased, whereas the CH4 and C6H6 concentrations and the gas/steam ratios increased. According to the trends shown by both the geochemical parameters and the seismic signals late in the observation period, the risk of a rejuvenation of volcanic activity at Teide is considered to be low. The associated temporal changes in seismic activity and magmatic degassing indicate that geophysical and fluid geochemistry signals in this system are related. Future monitoring programs aimed at mitigating volcanic hazard on Tenerife Island should involve coupled geophysical and geochemical studies.  相似文献   
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