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Abstract The spatial and temporal variations of atmospheric CO2 at 8–13 km from April 1993 to April 1999 were observed by measuring CO2 mixing ratios in samples collected biweekly from a commercial airliner between Australia and Japan. The CO2 growth rate showed a considerable interannual variation, with a maximum of about 3 ppm yr−1 during late 1997. This variation is related to the El Niño/Southern Oscillation (ENSO) events. A year-to-year change related to the ENSO events was also found in the latitudinal distribution pattern of the CO2 annual mean between 30°N and 30°S. The averaged CO2 seasonal cycle in the Northern Hemisphere gradually decayed toward the equator, and a relatively complicated variation with a double seasonal maximum appeared in the Southern Hemisphere. A significant yearly change of the seasonal cycle pattern was observed in the Southern Hemisphere. The impact of a tropical biomass-burning injection on the upper tropospheric CO2 was estimated on the basis of the CO data from the same airliner observation.  相似文献   
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High concentrations of carbon monoxide (CO) were observed in October 1997 at the upper troposphere of the western tropical Pacific. Transport from the potential sources of CO due to biomass burnings in the tropics was investigated by using a global chemical transport model (CTM) driven by assimilated meteorological data provided from European Centre for Medium-Range Weather Forecasts (ECMWF). A CTM evaluation simulation using water vapor showed that the amount of vertical transport of moisture by large-scale flow was consistent with the precipitation predicted at the convective zone. A series of CTM simulations using 10-day emission periods of an artificial material with lifetime of 60 days indicated that vertical lifting of surface air at the Indonesian archipelago occurred in the concentrated convections west of Sumatra Island. No evidence was found that CO from the Amazon region or Africa significantly contributed to high concentrations in the western tropical Pacific. Transport formed a large-scale anvil below the tropopause by rapid vertical transport and by divergence flow. The average time required for the transport from Kalimantan and Sumatra Island to the point of high CO concentration was about 15 days. High concentrations at an altitude of 10 km in the Southern Hemisphere were transported by large-scale subsidence from the upper tropospheric maximum, which was presumably produced from the sources at Kalimantan and Sumatra Island. Estimated emissions of CO in September and October from Kalimantan and Sumatra were substantially larger than the previous estimates. Omission of chemical reaction was a possible problem for the overestimate, but not significant. The possible problems in the transport were incorrect CTM transport due to insufficient horizontal (2.5×2.5°) and vertical resolution of the CTM, and to inaccuracy in the wind fields at the upper part of the troposphere and a divergent flow pattern in the upper part of the troposphere.  相似文献   
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The bulk composition of the continental crust throughout geological history is thought by most previous workers to be andesitic. This assumption of an andesitic bulk composition led to an early hypothesis by 72 ) that the continental crust was created by arc magmatism. This hypothesis for the origin of continental crust was challenged by several authors because: (i) the mean rate of arc crust addition obtained by 50 ) is too small to account for some certain phases of rapid crustal growth; and (ii) the bulk composition of ocean island arcs, the main contributor to the Archean and early Proterozoic crust, is basaltic rather than andesitic ( 4 ; 49 ). New data from the Northern Izu–Bonin arc are presented here which support the 72 ) hypothesis for the origin of the continental crust by andesitic arc magma. A geological interpretation of P wave crustal structure obtained from the Northern Izu–Bonin arc by 66 ) indicates that the arc crust has four distinctive lithologic layers: from top to bottom: (i) a 0.5–2-km-thick layer of basic to intermediate volcaniclastic, lava and hemipelagite (layer A); (ii) a 2–5-km-thick basic to intermediate volcaniclastics, lavas and intrusive layer (layer B); (iii) a 2–7-km-thick layer of felsic (tonalitic) rocks (layer C); and (iv) a 4–7-km-thick layer of mafic igneous rocks (layer D). The chemical composition of the upper and middle part of the northern Izu–Bonin arc is estimated to be similar to the average continental crust by 73 ). The rate of igneous addition of the Northern Izu–Bonin arc since its initial 45-Ma magmatism was calculated as 80 km3/km per million years. This rate of addition is considered to be a reasonable estimate for all arcs in the western Pacific. Using this rate, the global rate of crustal growth is estimated to be 2.96 km3/year which exceeds the average rate of crustal growth since the formation of the Earth (1.76 km3/year). Based on this estimate of continental growth and the previously documented sediment subduction and tectonic erosion rate (1.8 km3/year, 24 ), several examples of growth curves of the continental crust are presented here. These growth curves suggest that at least 50% of the present volume of the continental crust can be explained by arc magmatism. This conclusion indicates that arc magmatism is the most important contributor to the formation of continental crust, especially at the upper crustal level.  相似文献   
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Simulation of carbon dioxide (CO2) at hourly/weekly intervals and fine vertical resolution at the continental or coastal sites is challenging because of coarse horizontal resolution of global transport models. Here the regional Weather Research and Forecasting (WRF) model coupled with atmospheric chemistry is adopted for simulating atmospheric CO2 (hereinafter WRF-CO2) in nonreactive chemical tracer mode. Model results at horizontal resolution of 27 × 27 km and 31 vertical levels are compared with hourly CO2 measurements from Tsukuba, Japan (36.05°N, 140.13 oE) at tower heights of 25 and 200 m for the entire year 2002. Using the wind rose analysis, we find that the fossil fuel emission signal from the megacity Tokyo dominates the diurnal, synoptic and seasonal variations observed at Tsukuba. Contribution of terrestrial biosphere fluxes is of secondary importance for CO2 concentration variability. The phase of synoptic scale variability in CO2 at both heights are remarkably well simulated the observed data (correlation coefficient >0.70) for the entire year. The simulations of monthly mean diurnal cycles are in better agreement with the measurements at lower height compared to that at the upper height. The modelled vertical CO2 gradients are generally greater than the observed vertical gradient. Sensitivity studies show that the simulation of observed vertical gradient can be improved by increasing the number of vertical levels from 31 in the model WRF to 37 (4 below 200 m) and using the Mellor–Yamada–Janjic planetary boundary scheme. These results have large implications for improving transport model simulation of CO2 over the continental sites.  相似文献   
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