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Exopolymeric substances (EPS) produced by microorganisms play important roles in various aquatic, porous, and extreme environments. Only recently has their occurrence in sea ice been considered. We used macroscopic and microscopic approaches to study the content and possible ecological role of EPS in wintertime fast ice near Barrow, Alaska (71°20′ N, 156°40′ W). Using Alcian blue staining of melted ice samples, we observed high concentrations of EPS in all samples examined, ranging from 0.79 to 7.71 mg xanthan gum equivalents (XGEQV) l−1. Areal conversions to carbon equivalents yielded 1.5−1.9 g C m−2 ice in March and 3.3−4.0 g C m−2 in May (when the ice was thicker). Although EPS did not correlate with macronutrient or pigment data, the latter analyses indicated ongoing or recent biological activity in the ice within temperature horizons of −11°C to −9°C and warmer. EPS correlated positively with bacterial abundance (although no functional relationship could be deduced) and with dissolved organic carbon (DOC) concentrations. Ratios of EPS/DOC decreased at colder temperatures within the core, arguing against physical conversion of DOC to EPS during freezing. When sea-ice segments were maintained at representative winter temperatures (−5°C,−15°C and −25°C) for 3−14 months, the total EPS content increased significantly at rates of 5−47 μg XGEQV l−1 d−1, similar to published rates of EPS production by diatoms. Microscopic images of ice-core sections at these very cold temperatures, using a recently developed non-invasive method, revealed diatoms sequestered in spacious brine pockets, intact autofluorescent chloroplasts in 47% of the (pennate) diatoms observed, and indications of mucus in diatom-containing pores. The high concentrations of EPS detected in these winter ice cores represent a previously unrecognized form of organic matter that may contribute significantly to polar ocean carbon cycles, not only within the ice but after springtime release into the water column. The EPS present in very high concentrations in the brine of these microhabitats appear to play important buffering and cryoprotectant roles for microorganisms, especially diatoms, against harsh winter conditions of high salinity and potential ice-crystal damage.  相似文献   
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The air–sea ice CO2 flux was measured over landfast sea ice in the Chukchi Sea, off Barrow, Alaska in late May 2008 with a chamber technique. The ice cover transitioned from a cold early spring to a warm late spring state, with an increase in air temperature and incipient surface melt. During melt, brine salinity and brine dissolved inorganic carbon concentration (DIC) decreased from 67.3 to 18.7 and 3977.6 to 1163.5 μmol kg−1, respectively. In contrast, the salinity and DIC of under-ice water at depths of 3 and 5 m below the ice surface remained almost constant with average values of 32.4±0.3 (standard deviation) and 2163.1±16.8 μmol kg−1, respectively. The air–sea ice CO2 flux decreased from +0.7 to −1.0 mmol m−2 day−1 (where a positive value indicates CO2 being released to the atmosphere from the ice surface). During this early to late spring transition, brought on by surface melt, sea ice shifted from a source to a sink for atmospheric CO2, with a rapid decrease of brine DIC likely associated with a decrease in the partial pressure of CO2 of brine from a supersaturated to an undersaturated state compared to the atmosphere. Formation of superimposed ice coincident with melt was not sufficient to shut down ice–air gas exchange.  相似文献   
3.
This study shows the assessment of radiation hazard parameters due to terrestrial radionuclides in the soil around artisanal gold mining for addressing the issue of natural radioactivity in mining areas. Hence, the levels 238U, 232Th, 40K and 226Ra in soil (using gamma spectrometry), 222Rn in soil and 222Rn in air were determined. Radiation hazard parameters were then computed. These include absorbed dose D, annual effective dose E, radium equivalent activity Raeq, external hazard Hex, annual gonadal dose equivalent hazard index AGDE and excess lifetime cancer risk ELCR due to the inhalation of radon (222Rn) and consumption of radium (226Ra) in vegetation. Uranium (238U), thorium (232Th) and potassium (40K) averages were, respectively, 26, 36 and 685 Becquerel per kilogram (Bq kg?1). Soil radon (4671 Bq m?3) and radon in air (14.77 Bq m?3) were found to be less than worldwide data. Nevertheless, the average 40K concentration was 685 Bq kg?1. This is slightly higher than the United Nations Scientific Committee on the Effects of Atomic Radiation average value of 412 Bq kg?1. The obtained result indicates that some of the radiation hazard parameters seem unsavory. The mean value of absorbed dose rate (62.49 nGy h?1) was slightly higher than average value of 57 nGy h?1 (~?45% from 40K), and that of AGDE (444 μSv year?1) was higher than worldwide average reported value (300 μSv year?1). This study highlights the necessity to launch extensive nationwide radiation protection program in the mining areas for regulatory control.  相似文献   
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Zusammenfassung Im Rahmen neuerer Untersuchungen an Mineralen der Olivingruppe wurde die Struktur von Monticellit (MgCaSiO4) neu bestimmt und verfeinert. Die im Jahre 1927 vonBrown undWest bestimmte Struktur ließ sich im wesentlichen bestätigen. In 13 Verfeinerungszyklen, nach der Methode der kleinsten Quadrate auf einer Rechenanlage des Typs IBM 7094 durchgeführt, ließ sich der R-Faktor von 0,439 auf 0,068 für 345 hkl-Reflexe herabdrücken.Ein Vergleich der Atomabstände und Winkel mit bereits bekannten Daten des Olivins und Fayalits zeigte eine bemerkenswerte Übereinstimmung.
Summary As part of a detailed study of minerals of the olivine group the structure of monticellit (MgCaSiO4) was redetermined and refined. The structure, as given byBrown andWest (1927) was found to be fundamentally correct. Thirteen cycles of leastsquares refinement on the IBM 7094 computer reduced the disagreement factor, R, for 345 hkl reflections from an initial value of 0.439 to a final value of 0.068.A comparison of atomic distances and bond angles with previously determined data of olivine and fayalite showed remarkable agreement.


Herrn Professor Dr.F. Machatschki zum 70. Geburtstag gewidmet.  相似文献   
6.
This study was conducted primarily to measure and map radon activity concentration in soil gas and to understand the effect of geology and lithology and meteorology on radon concentration. Portable radon meter has been used for the measurement of soil gas radon at 30 different locations around Uro and Korn area in eastern Nuba Mountain South Kordofan State. The results indicate that the activity concentrations of 222Rn in soil gas fall within the range of 20–1,359 Bq/m3 with geometric mean of 102.80 Bq/cm3. The obtained data show that samples around Uro have anomaly of 222Rn concentrations than the sample around Korn. The reason could be attributed to differences in the geological structure, lithology and climate parameters. GIS predicative map has shown that the elevated levels of radon concentration were measured in North study area. Upon comparing the results with global data, it was found that the obtained values are far below the reported range of India, Slovenia, Portugal and Syria. However, the range of 222Rn concentrations in the soil observed in this study is significantly high relative to similar data reported from Libya. The regression analysis has shown that no correlation was noted between radon concentrations, climatic parameters and trace element.  相似文献   
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8.
Sediment-laden sea ice is widespread over the shallow, wide Siberian Arctic shelves, with off-shelf export from the Laptev and East Siberian Seas contributing substantially to the Arctic Ocean's sediment budget. By contrast, the North American shelves, owing to their narrow width and greater water depths, have not been deemed as important for basin-wide sediment transport by sea ice. Observations over the Chukchi and Beaufort shelves in 2001/02 revealed the widespread occurrence of sediment-laden ice over an area of more than 100,000 km2 between 68 and 74°N and 155 and 170°W. Ice stratigraphic studies indicate that sediment inclusions were associated with entrainment of frazil ice into deformed, multiple layers of rafted nilas, indicative of a flaw-lead environment adjacent to the landfast ice of the Chukchi and Beaufort Seas. This is corroborated by buoy trajectories and satellite imagery indicating entrainment in a coastal polynya in the eastern Chukchi Sea in February of 2002 as well as formation of sediment-laden ice along the Beaufort Sea coast as far eastward as the Mackenzie shelf. Moored upward-looking sonar on the Mackenzie shelf provides further insight into the ice growth and deformation regime governing sediment entrainment. Analysis of Radarsat Synthetic Aperture (SAR) imagery in conjunction with bathymetric data help constrain the water depth of sediment resuspension and subsequent ice entrainment (>20 m for the Chukchi Sea). Sediment loads averaged at 128 t km–2, with sediment occurring in layers of roughly 0.5 m thickness, mostly in the lower ice layers. The total amount of sediment transported by sea ice (mostly out of the narrow zone between the landfast ice edge and waters too deep for resuspension and entrainment) is at minimum 4×106 t in the sampling area and is estimated at 5–8×106 t over the entire Chukchi and Beaufort shelves in 2001/02, representing a significant term in the sediment budget of the western Arctic Ocean. Recent changes in the Chukchi and Beaufort Sea ice regimes (reduced summer minimum ice extent, ice thinning, reduction in multi-year ice extent, altered drift paths and mid-winter landfast ice break-out events) have likely resulted in an increase of sediment-laden ice in the area. Apart from contributing substantially to along- and across-shelf particulate flow, an increase in the amount of dirty ice significantly impacts (sub-)ice algal production and may enhance the dispersal of pollutants.  相似文献   
9.
Based on snow- and ice-thickness measurements at >11 000 points augmented by snow- and icecore studies during 4 expeditions from 1986 - 92 in the Weddell Sea, we describe characteristics and distribution patterns of snow and meteoric ice and assess their importance for the mass balance of sea ice. For first-year ice (FY) in the central and eastern Weddell Sea, mean snow depth amounts to 0.16 m (mean ice thickness 0.75 m) compared to 0.53 m (mean ice thickness 1.70 m) for second-year ice (SY) in the northwestern Weddell Sea. Ridged ice retains a thicker snow cover than level ice, with ice thickness and snow depth negatively correlated for the latter, most likely due to aeolian redistribution. During the different expeditions, 8, 15, 17 and 40% of all drill holes exhibited negative freeboard. As a result of flooding and brine seepage into the snow pack, snow salinities averaged 4‰. Through 18O measurements the distribution of meteoric ice (i.e. precipitation) in the sea-ice cover was assessed. Roughly 4% of the total ice thickness consist of meteoric ice (FY 3%, SY 5%). With a mean density of 290 kg/m3, the snow cover itself contributes 8% to total ice mass (7% FY, 11% SY). Analysis of 18O in snow indicates a local maximum in accumulation in the 65 to 75^S latitude zone. Hydrogen peroxide in the snow has proven useful as a temporal tracer and for identification of second-year floes. Drawing on accumulation data from stations at the Weddell Sea coast, it becomes clear that the onset of ice growth is important for the evolution of ice thickness and the interaction between ice and snow. Loss of snow to leads due to wind drift may be considerable, yet is reduced owing to metamorphic processes in the snow column. This is confirmed by a comparison of accumulation data from coastal stations and from snow depths over sea ice. Temporal and spatial accumulation patterns of snow are shown to be important in controlling the sea-ice cover evolution.  相似文献   
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