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The Neogene Beypazari basin is one of the important coal districts of Central Anatolia with approximately 600 million short tons lignite reserves. The coal-bearing Neogene sediments occurring in the Beypazari basin are divided into seven formations, in ascending order; Çoraklar, Hirka, Akpinar, Çayirhan, Bozbelen and Kirmir Formations with Sariyar Limestone and Teke volcanics.The Çoraklar Formation consists of cross-bedded sandstones, channel-fill conglomerates, mudstones, carbonaceous shales and volcanoclastic pebblestones, which are fluvial in origin. The lower lignite seam occurs in the lower part of the Çoraklar Formation.The upper lignite seam occurs in the uppermost part of the Çoraklar Formation and is overlain by the Hirka Formation with a sharp contact. The Hirka Formation consists mainly of alternating shale, mudstone, bituminous shale, claystone, tuffite and silicified limestone, and they all are apparently of lacustrine origin.The lignite deposite occur in the Çayirhan and Koyunaǧili parts of the Beypazari Neogene basin. The Çayirhan coal field consists of lower and upper lignite seams, but the Koyunaǧili field contains only an upper lignite seam.The lower lignite seam, which does not crop out at the surface, indicates a fluvial origin of the lignite deposits, based on the lateral discontinuity and the lower sulphur content of the lower lignite seam, and the sedimentologic and stratigraphic features of the associated sediments. But the uniform stratigraphic and sedimentologic features, high sulphur content and wide-spread distribution of the upper lignite seam indicate that the upper lignites were deposited probably in a mud-flat facies of playa-lake environment. The lower and upper lignites are completely different in relation to the depositional environment, the geometry and degree of rank in lateral directions.The lateral spreading and geometry of the lower lignite deposits were controlled by channel, floodplain and well-drained marshes of a fluvial system. On the basis of recent drillings and field investigations, the lower lignite deposit has been demonstrated to be a linear spreading parallel to the axis of the channel fills and throughcross beds in clastic sediments of fluvial facies. Therefore, the lower lignite deposits trend along a northeastern direction and is not expected to be as widely spread as the upper lignites. 相似文献
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In the Avnik area of the Bingöl massif the Lower Unit consists of basic to felsic metavolcanics (ca. 450 Ma), intruded by granitoids (ca. 350 Ma). These are unconformably overlain by an Upper Unit of micaschists and Permian marbles; both units have been deformed and metamorphosed in Alpine time. The metavolcanics and granitoids are extensively feldspathized and silicified. The granitoids, and basic-intermediate volcanics, are albitized, while felsic volcanics are K-feldspathized. Metasomatism has severely modified K/Rb and Rb/Sr ratios, but not REE patterns, and is inferred to have occurred at relatively low T. Nametasomatism of the Upper Unit micaschists has produced albite porphyroblasts. Metasomatism postdates formation of the Upper Unit sediments, and is probably related to reaction with sea water that infiltrated the basement of volcanics and granitoids during deposition of these sediments. Rb-Sr whole-rock dating of extensively feldspathized intermediate-felsic metavolcanics gives an age of ca. 90 Ma, which suggests that the most extensive reaction coincided with expulsion of the trapped sea water during the early stages of the Alpine orogeny. The distribution of albitization vs. K-felds-pathization suggests that the type of metasomatism was controlled on a local scale by permeability and grain size, rather than by T variations. 相似文献
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The Miocene borate deposits of western Turkey are associated with extensive medium- to high-K calc-alkali ignimbritic volcanism and a differentiated comagmatic alkaline trachybasalt–trachydacite lava suite. Ignimbritic air-fall and reworked pumiceous clastic materials are intimately associated with lake sediments that host the borate deposits. Local ignimbritic volcanism is considered the primary source of the B for the Kirka borate deposit in this area. Comparison of the geochemical composition of Turkish ignimbrites associated with borates (`fertile' ignimbrites) with those that do not (`barren' ignimbrites), exhibit a number of features that might prove useful in the exploration for borates in similar volcanic domains. In particular, `fertile' ignimbrites are (a) generally a high-K calc-alkali suite, well-evolved and fractionated (K/Rb is low, <200) with a high-silica rhyolitic bulk composition, (b) exhibit a combined high content of B, As, F, Li and Pb, with high B/La (>1) and B/K (>0.001) ratios, and (c) a mildly fractionated REE pattern (LaN/YbN∼2) and large positive Eu anomaly (Eu/Eu*∼0.1). Other apparent discriminants involving both compatible and incompatible elements (relative to major silicate phases) are largely a function of different degrees of partial melting and fractionation. It is suggested that the initial source of the B (and other associated elements) was from LIL-rich fluids released by the progressive dehydration of altered oceanic crust and pelagic sediments in a subduction zone. The absence or presence of sediments in a segmented subduction zone may influence the variable lateral distribution of borates in active margins on a global scale. Once the crust has become enriched in B via previous or contemporary subduction-related calc-alkali magmatism, the effect of tectonic environment, climate and hydrothermal activity influence the local development of the deposits. 相似文献
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S&#;bel Tatar Erkül Hasan Sözb&#;l&#;r Fuat Erkül Cah&#;t Helvaci Yalçin Ersoy Ökmen Sümer 《Island Arc》2008,17(3):394-418
Abstract Triassic granitoids related to Palaeo- and Neo-Tethyan events occur widely in the metamorphic terranes largely affected by the Alpine orogeny. A first recorded unmetamorphosed plutonic body intruded into the Palaeotethyan mélange in western Turkey, called the Karaburun granodiorite, is composed of two small intrusive stocks that were emplaced between 240 and 220 Ma. It is compositionally diverse, ranging from granodiorite and tonalite to diorite. These rocks show heterogeneous compositions with 54 to 65 wt % SiO2 and are calc-alkaline in character. They are also subalkaline with molar ratios of Al2O3/(Na2O + K2O) from 0.74 to 1.00 and are metaluminous. Most samples are diopside-normative (0.36–8.64), with Na2O > K2O. Chondrite normalized rare earth element (REE) patterns show various degrees of light REE (LREE) enrichment, with La N = 57.79 to 99.59 and (La/Yb) N = 5.98–7.85 and Eu negative anomalies (Eu/Eu* = 0.62–0.86). These rocks have coherent patterns in ocean ridge granite (ORG) normalized trace-element plots, marked by variable enrichment in K, Rb, Ba, Th, Ce and depletion in Ta and Nb, similar to I-type granites from subduction zones. In primitive mantle-normalized multi element variation diagrams, the granodiorites show pronounced depletions in the high-field-strength elements (HFSE; Nb, Ta, Zr), Sr, P, and Ti. Trace-element modeling of the Karaburun granodiorite suggests an origin through partial melting of the subduction-modified mantle wedge with minor contribution of crustal components through a process of strong fractional crystallization (FC) combined with slight assimilation-fractional crystallization (AFC). Exposures of typical continental-arc granodiorites in the Karaburun Mélange support the validity of the subduction-accretion model that implies the presence of an active continental margin following closure of the Palaeotethyan Ocean during the Triassic. 相似文献
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