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Santschi Peter H. Honeyman Bruce D. Quigley Matthew S. 《Aquatic Sciences - Research Across Boundaries》1993,55(4):230-239
In 1975 Paul Schindler produced the first oceanic trace metal scavenging model to explicitly include the role of surface chemistry as a control on trace metal water column residence times. The eighteen years that have elapsed since the publication of Schindler's seminal paper have seen the development of a variety of oceanic scavenging models; yet, the fundamental insight of his Zero-order Model remains the benchmark. This paper describes the role of Paul Schindler's work on surface chemistry in providing a framework for the current generation of trace element scavenging models. 相似文献
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Thorium(IV) sorption onto hematite (-Fe2O3) was examined as a function of pH and ionic strength. Sorption behaved Langmuirian over an eleven order of magnitude range in adsorption densities, : 10–12 to 10–1 moles Th sorbed per mole hematite sites, indicating that the overall free energy of Th adsorption is independent of adsorption density. Modeling of Th sorption was conducted with the Triple Layer Model of Davis and Leckie; reactions considered included solution-phase hydroxy and carbonato complexes of thorium, and carbonate/hematite surface complexes. The entire Th sorption isotherm can be modeled with a single surface complex formation reaction
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Robert F. Holub P. Smrz G. Reimer P. Hopke J. Hovorka B. Honeyman 《Environmental Geology》2002,41(8):984-985
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