Trace elements contamination of agricultural soils affected by sulphide exploitation (Iberian Pyrite Belt,Sw Spain)   总被引：1，自引：0，他引：1  

María López  Isabel González  Antonio Romero 《Environmental Geology》2008,54(4):805-818

Agricultural soils of the Riotinto mining area (Iberian Pyrite Belt) have been studied to assess the degree of pollution by trace elements as a consequence of the extraction and treatment of sulphides. Fifteen soil samples were collected and analysed by ICP-OES and INAA for 51 elements. Chemical analyses showed an As–Cu–Pb–Zn association related with the mineralisation of the Iberian Pyrite Belt. Concentrations were 19–994 mg kg⁻¹ for As, 41–4,890 mg kg⁻¹ for Pb, 95–897 mg kg⁻¹ for Zn and of 27–1,160 mg kg⁻¹ for Cu. Most of the samples displayed concentrations of these elements higher than the 90th percentile of the corresponding geological dominium, which suggests an anthropogenic input besides the bedrock influence. Samples collected from sediments were more contaminated than leptosols because they were polluted by leachates or by mining spills coming from the waste rock piles. The weathering of the bedrock is responsible for high concentrations in Co, Cr and Ni, but an anthropogenic input, such as wind-blown dust, seems to be indicative of the high content of As, Cu, Pb and Zn in leptosols. The metal partitioning patterns show that most trace elements are associated with Fe amorphous oxy-hydroxides, or take part of the residual fraction. According to the results obtained, the following mobility sequence is proposed for major and minor elements: Mn, Pb, Cd, > Zn, Cu > Ni > As > Fe > Cr. The high mobility of Pb, Cu and Zn involve an environmental risk in this area, even in soils where the concentrations are not so high.  相似文献   

Usefulness of geological,mineralogical, chemical and chemometric analytical techniques in exploitation and profitability studies of iron mines and their associated elements     

M. Dolores Petit-Dominguez  M. Isabel Rucandio  Almudena Galan-Saulnier  Rosario Garcia-Gimenez 《Journal of Geochemical Exploration》2008

Due to the high number of variables involved in mine profitability studies, it is often very difficult to establish connections among them in order to provide a blend of market saleable quality products. In this sense, analytical chemistry together with chemometry are essential and indispensable disciplines to tackle these studies. The aim of this work was to demonstrate the utility of these disciplines to carry out optimization studies of iron mines. For this purpose, one of the most important iron mines of the Iberian Peninsula was chosen, sited in the mountain range of Sierra Menera, near the location of Ojos Negros (Teruel, Spain). Geological, mineralogical and chemical composition of 148 samples was analyzed, corresponding to different depths of three drill holes (named TE1, TE2 and TE3). In particular, aspects concerning to chemical composition are very important, since the mean contents of certain elements, such as phosphorus, sodium and potassium, should be restricted to the established limits to prevent that companies can drive back the raw material if they do not fulfil the necessary requirements. On the other hand, the large number of analysed samples drove us to use a statistical processing of the data. Among other aspects, it provides a way to find possible connections among a high number of variables and classify samples into compositional groups sharing similar composition, in order to limit the mineralised area and to obtain enough information about the amount of those chemical elements associated to iron ores. Data obtained from all these analytical techniques were in good agreement and provide a methodology that can be of wide interest applied to different geological studies.  相似文献   

Spatially resolved spectroscopic observations of Jupiter during the 1987 opposition     

F. Moreno  A. Molina 《Earth, Moon, and Planets》1989,46(3):207-219

Spectroscopic observations in the spectral region 6000–6600 » of major belts and zones of Jupiter have been carried out at Calar Alto Observatory (Spain) during the 1987 opposition, in support to the International Jupiter Watch Program. More than a hundred long-slit, medium resolution spectra have been taken at the coudé focus of the 1.52 m telescope. The longitudinal and latitudinal distribution of the equivalent widths of the methane and ammonia absorption bands at 6190 » and 6450 » have been investigated. Unlike the CH₄-6190 » band, the longitudinal distribution in the NH₃-6450 » band shows asymmetries in some of the Jovian regions analyzed, being the absorption greater at West than at East limbs. These results are interpreted in terms of inhomogeneous scattering models by the simultaneous variation of the NH₃ cloud optical thickness and its altitude level. The north-south scans show little latitudinal dependence on absorption in both methane and ammonia bands, although some relationship could be established between the absorption and relative continuum reflectivity variation.

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Resumen Se presentan los resultados obtenidos de las observaciones espectroscópicas de las principales zonas y cinturones de Júpiter realizadas durante la oposición de 1987 como una contribución al International Jupiter Watch Program. Las observaciones fueron llevadas a cabo haciendo uso del foco coudé del telescopio de 1.52 m del observatorio hispanoalemán de Calar Alto (España), habiéndose obtenido algo más de cien espectros, de resolución media, en la región espectral de 6000–6600 ». Se exponen los resultados de las anchuras equivalentes de las bandas de absorción del metano en 6190 » y del amoniaco en 6450 », estudiándose, al mismo tiempo, la distribución tanto longitudinal como latitudinal de las mismas. Mientras que los resultados para la banda del metano presentan un comportamiento simétrico en todas las regiones analizadas, las anchuras equivalentes para la banda NH₃-6450 » presentan un comportamiento asimétrico en algunas regiones del planeta, con una mayor absorción hacia el limbo del oeste que hacia el del este. Los resultados son interpretados en base a un modelo de scattering no homogéneo, variando, simultáneamente, el espesor óptico y la altitud de la nube de amoniaco. Los espectros tomados en la dirección norte-sur, aunque presentan una dependencia latitudinal pequeña en la absorción de las bandas mencionadas, sugieren una relación entre la absorción y las variaciones de reflectividad en el continuo.

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Also at Departamento de Física Aplicada, Facultad de Ciencias, Universidad de Granada, Campus Universitario Fuentenueva, Granada, Spain.  相似文献   

Avian and mammalian bone taphonomy in southern continental Patagonia: A comparative approach   总被引：1，自引：0，他引：1  

Isabel Cruz   《Quaternary International》2008,180(1):30

In southern Patagonia, the occurrence of large seabird nesting colonies condition the features of the regional bone record, which is characterized by a large amount of bird remains, despite their small body size. Bird and mammal bones have remarkably different taphonomic histories in this region: mammal remains are less damaged by carnivores and resist weathering for long periods, whereas bird bones show a greater initial destruction by carnivore activities and faster deterioration by weathering. A comparison of these results with results from research conducted in several African parks (particularly Amboseli) shows that differences in both records are mainly due to differences in community composition and predator–prey dynamics in both ecosystems. Furthermore, while in both ecosystems bird bones weather more rapidly than mammal bones, destruction by this process is more rapid in Patagonia. Overall, the analysis reinforces the need to generate specific models to understand taphonomic histories of archaeofaunal assemblages from Patagonia.  相似文献   

Projecting land-use change processes in the Sierra Norte of Oaxaca, Mexico     

Leticia Gmez-Mendoza  Ernesto Vega-Pea  M. Isabel Ramírez  Jos Luis Palacio-Prieto  Leopoldo Galicia 《Applied geography (Sevenoaks, England)》2006,26(3-4):276-290

The objective of study was to explore short-term trends of processes that determine land-use change in Sierra Norte of Oaxaca (SNO), Mexico. Land use and land cover changes (LULCC) were estimated in a complex mosaic of vegetation in the SNO from 1980 to 2000, and projected them to 2020 through a Markovian model. SNO is highly vulnerable to climatic change according to a 2050 GCM scenario. However, 3% annual rate of tropical and temperate forest deforestation from agriculture and livestock encroachment, suggest the threat from land-use change is higher than that from climatic change for this study site. Productive land-use strategies are needed to reduce such high deforestation rates for tropical regions. Controlling deforestation would also reduce short-term effects of CO₂ emissions to the atmosphere. Because of the necessity to evaluate anthropogenic ecosystem changes, it is imperative to separate short-term influences such as deforestation, from long-term influences such as climatic change.  相似文献   

Pseudodynamic tests on rubber base isolators with numerical substructuring of the superstructure and strain‐rate effect compensation     

F. J. Molina  G. Verzeletti  G. Magonette  Ph. Buchet  V. Renda  M. Geradin  A. Parducci  M. Mezzi  A. Pacchiarotti  L. Federici  S. Mascelloni 《地震工程与结构动力学》2002,31(8):1563-1582

A pseudodynamic testing procedure has been applied by which the seismic response of a base‐isolated building is obtained by using as specimen the isolators, while the superstructure is numerically simulated. The procedure also takes advantage of the continuous pseudodynamic testing capabilities of the ELSA laboratory, which increase the accuracy of the results and reduce the strain‐rate effect of the rubber bearings. A simple proportional correction of the measured forces compensates the remaining strain‐rate effect due to the unrealistic speed of the test. The correction factor is obtained by means of a characterizing test on the specific rubber isolators. The developed method has been successfully applied to the prediction of the seismic response of a base‐isolated four‐storey building submitted to several specified accelerograms. The results for those earthquakes as well as the effects of some changes of the parameters of the system are discussed. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

Study of weathering processes developed on old piedmont surfaces in Western Spain: new contributions to the interpretation of the “Raña” profiles     

E. Molina Ballesteros  M. Cantano Martín   《Geomorphology》2002,42(3-4)

The Hercynian basement of the Iberian Peninsula was uplifted by the Alpine orogeny during the Tertiary. It gave rise to a set of block mountains and tectonic grabens, one of which is the Ciudad Rodrigo Basin. It is located in Western Spain and forms a westward extension of the great Tertiary Duero Basin. The sediments filling this graben are of continental origin, their ages ranging from Palaeogene to Quaternary. Morphologically, the southern part of this basin forms a set of piedmont surfaces (the “Raña” surfaces) appearing above the terrace system of the present rivers. This paper examines the weathering processes developed over these old piedmont surfaces using micromorphological, XR diffraction, scanning electron microscopy (SEM) and microporosity techniques.The Raña sediments are rich in quartzite pebbles and gravel within a clayey matrix. Once deposited, these materials underwent important in situ weathering processes under somewhat hydromorphic conditions, of which hydrolysis, ferrolysis and xerolysis were the most important. All these processes gave rise to: (1) transformation of most of the clasts of shists and slates into a matrix causing the destruction of the original sedimentary structures and a relative concentration of the resistant lithologies (quartzites and quartz); (2) important changes in the clay fraction, leading to a predominance of kaolinite in the upper levels of the profiles, (3) release of elements from primary minerals, Fe being one of the most important, and (4) redistribution of matter, mainly clay and Fe oxyhydroxides, within the profiles.The coexistence of seasonal periods with pF higher than 4.2 repeated over a long time, together with poor internal and external drainage conditions, are the cause of the special features displayed by Raña deposits.  相似文献   

Cyclic tests on large‐scale models of existing bridge piers with rectangular hollow cross‐section     

A. V. Pinto  J. Molina  G. Tsionis 《地震工程与结构动力学》2003,32(13):1995-2012

Cyclic tests on two large‐scale models of existing bridge piers with rectangular hollow cross‐section were performed in the ELSA laboratory. The prototype structure is an existing reinforced concrete highway bridge constructed in Austria in 1975. The piers presented several seismic deficiencies and consequently they showed poor hysteretic behaviour and limited deformation capacity as well as undesirable failure modes that do not comply with the requirements of modern codes for seismic‐resistant structures. Experimental data are compared to numerical and empirical predictions. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

Paleomagnetism of the Cretaceous Morelos and Mezcala Formations, southern Mexico     

Roberto S Molina Garza  Harald N Bhnel  Teodoro Hernndez 《Tectonophysics》2003,361(3-4):301-317

A paleomagnetic study of platform-facies carbonate rocks of the mid-Cretaceous Morelos Formation and deep-water carbonate rocks of the overlying Upper Cretaceous Mezcala Formation, sampled at Zopilote canyon, in Guerrero State, southern Mexico, indicates that their characteristic magnetization was acquired contemporaneously with folding of these rocks during the Late Cretaceous Laramide orogeny. The remanence carrier is interpreted to be magnetite, although other mineral phases of high coercivity carry recent secondary overprints. The overall mean is of Dec=323.1° and Inc=36.5° (k=162.7; α₉₅=2.7°; N=18 sites; 64% unfolding). Comparison with the North America reference direction indicates that this area has experienced a small, yet statistically significant, counterclockwise direction of 19.2±4.0°. Similar rotations are documented in other localities from southern Mexico; rotations are linked to mid-Tertiary deformation associated with the left-lateral strike-slip fault system that accommodated motion of the Chortis and Xolapa blocks.  相似文献   

Seismic tests on reinforced concrete and steel frames retrofitted with dissipative braces     

F. J. Molina  S. Sorace  G. Terenzi  G. Magonette  B. Viaccoz 《地震工程与结构动力学》2004,33(15):1373-1394

Seismic tests have been conducted on two 3‐storey structures protected with pressurized fluid‐viscous spring damper devices. One of the structures was a reinforced concrete frame with clay elements in the slabs, while the other one was a steel frame with steel/concrete composite slabs. The spring dampers were installed through K bracing in between the floors. The tests were performed by means of the pseudodynamic method, which allowed the use of large and full‐size specimens, and by implementing a specific compensation strategy for the strain‐rate effect at the devices. The test results allowed the verification of the adequacy of the attachment system as well as the comparison of the behaviour of the unprotected buildings with several protected configurations, showing the benefits of the application of the devices and the characteristics of their performance. The response of the protected structures was always safer than that of the unprotected ones mainly due to a significant increase of equivalent damping. The increase in the damping ratio depends on the level of deformation. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献