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Detailed studies on the copper and zinc distribution in metalliferous sediments from the Atlantis II Deep (Red Sea) demonstrate that beside chalcopyrite and sphalerite appreciable amounts of copper and zinc are found in X-ray amorphous copper and zinc sulfides not previously described. Only low contents of copper and zinc are present in nontronites, hydroxides and carbonates.  相似文献   
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Stable isotopes in the water molecule (2H or D and 18O), carbon, and nitrogen are useful tracers and integrators of processes in plant ecohydrological systems across scales. Over the last few years, there has been growing interest in regional to continental scale synthesis of stable isotope data with a view to elucidating biogeochemical and ecohydrological patterns. Published datasets from the humid tropics, however, are limited. To be able to contribute to bridging the “data gap” in the humid tropics, here, we publish a relatively novel and unique suite of δ13C, δ15N, δ2H, and δ18O isotope data from three sites across a moisture gradient and contrasting land use in Puerto Rico. Plant tissue (xylem and leaf) samples from two species of mahogany (Swietenia macrophylla and Swietenia mahagoni) and soil samples down to 60 cm in the soil profile were collected in relatively “wet” (July 2012) and “dry” (February 2013) periods at two sites in northeastern (Luquillo) and southwestern (Susua) Puerto Rico. The same sampling suite is also being made available from a highly urbanized site in the capital San Juan. Leaf samples taken in July 2012 and February 2013 were analyzed for δ13C and δ15N; all xylem and bulk soil samples were analyzed for δ2H and δ18O. Soil samples taken in July 2012 were analyzed for δ13C and δ15N. Leaf δ15N and δ13C dataset showed patterns that are possibly associated with site differences. While spatial patterns were also apparent in soil δ15N and δ13C dataset, the positively linear δ15N –δ13C relationship tends to weaken with site moisture. Soil depth and site moisture patterns were also observed in the δ2H and δ18O datasets of bulk soil and xylem samples. The purpose of these datasets is to provide baseline information on soil–plant water (δ2H and δ18O, N = 319), δ13C (N = 272), and δ15N (N = 269) that may be useful in a wide range of research questions from ecohydrological relations to biogeochemical patterns in soils and vegetation.  相似文献   
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Recent work has shown evidence of ecohydrological separation whereby plants appear to use a less mobile soil water pool that does not mix with more mobile soil water, groundwater, and streamflow. Although many elements of this two water worlds hypothesis remain to be tested and challenged, one key question is “how old might the less mobile water used by plants be?” Such a question is methodologically difficult to answer: stable isotope tracing makes it difficult to resolve any water age older than a few years since the signal gets so damped. Tritium—a useful radiogenic isotope and age dating tool, is now difficult to use in natural systems because most bomb tritium has washed out of soil profiles. Here, we leverage new data from an unusually deep, homogenous soil profile that preserves the mid‐1960s tritium bomb signal. We sample the Fuji apple trees (Malus pumila Mil) growing on this site that have root systems that penetrate over 15 m and utilize water from within the bomb peak soil water distribution (extracted via cryogenic extraction). Our data show that water used by these trees is on average 29 years old. Bayesian mixing analysis suggests that 40 ± 30% of fruit tissue water came from depths between 4 and 9 m within the soil profile (36 ± 9 years old); 60 ± 29% was equally divided between 0 and 4 m and 9–15 m ranges (13 ± 5 years old). These findings suggest that trees can use quite old less mobile water, highlighting the separation in ages between more mobile soil water and water in transit in sap flow .  相似文献   
4.
Water transpired by trees has long been assumed to be sourced from the same subsurface water stocks that contribute to groundwater recharge and streamflow. However, recent investigations using dual water stable isotopes have shown an apparent ecohydrological separation between tree‐transpired water and stream water. Here we present evidence for such ecohydrological separation in two tropical environments in Puerto Rico where precipitation seasonality is relatively low and where precipitation is positively correlated with primary productivity. We determined the stable isotope signature of xylem water of 30 mahogany (Swietenia spp.) trees sampled during two periods with contrasting moisture status. Our results suggest that the separation between transpiration water and groundwater recharge/streamflow water might be related less to the temporal phasing of hydrologic inputs and primary productivity, and more to the fundamental processes that drive evaporative isotopic enrichment of residual soil water within the soil matrix. The lack of an evaporative signature of both groundwater and streams in the study area suggests that these water balance components have a water source that is transported quickly to deeper subsurface storage compared to waters that trees use. A Bayesian mixing model used to partition source water proportions of xylem water showed that groundwater contribution was greater for valley‐bottom, riparian trees than for ridge‐top trees. Groundwater contribution was also greater at the xeric site than at the mesic–hydric site. These model results (1) underline the utility of a simple linear mixing model, implemented in a Bayesian inference framework, in quantifying source water contributions at sites with contrasting physiographic characteristics, and (2) highlight the informed judgement that should be made in interpreting mixing model results, of import particularly in surveying groundwater use patterns by vegetation from regional to global scales. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   
5.
The role of microorganisms in the transfer of carbon of marine systems is very important in open oligotrophic oceans. Here, we analyze the picoplankton structure, the heterotrophic bacterioplankton activity, and the predator-prey relationships between heterotrophic bacteria and nanoflagellates during two large scale cruises in the Central Atlantic Ocean (∼29°N to ∼40°S). Latitud cruises were performed in 1995 between March-April and October-November. During both cruises we crossed the regions of different trophic statuses; where we measured different biological variables both at the surface and at the deep chlorophyll maximum (DCM). The concentration of chlorophyll a varied between 0.1 and 0.8 mg m−3, the abundance of heterotrophic bacteria varied between <1.0 × 105 and >1.0 × 106 cells ml−1, and that of heterotrophic nanoflagellates between <100 and >1.0 × 104 cells ml−1. The production of heterotrophic bacteria varied more than three orders of magnitude between <0.01 and 24 μgC L−1 d−1; and the growth rates were in the range <0.01-2.1 d−1. In the Latitud-II cruise, Prochlorococcus ranged between <103 and >3 × 105 cells ml−1, Synechococcus between <100 and >1.0 × 104 cells ml−1, and picoeukaryotes between <100 and >104 cells ml−1.Two empirical models were used to learn more about the relationship between heterotrophic bacteria and nanoflagellates. Most bacterial production was ingested when this production was low, the heterotrophic nanoflagellates could be controlled by preys during Latitud-I cruise at the DCM, and by predators in the surface and in the Latitud-II cruise. Our results were placed in context with others about the structure and function of auto- and heterotrophic picoplankton and heterotrophic nanoplankton in the Central Atlantic Ocean.  相似文献   
6.
本文利用锆石和磷灰石裂变径迹方法探讨了班韦乌卢地块泛非期以来的主要构造演化时间.为研究班韦乌卢地块的构造活动,本文从班韦乌卢地块中部卡帕图地区的沉积盖层姆波罗科索群的姆巴拉组、萨马组和卡布韦卢马组中采集多件新鲜的岩石样品,并获得5件锆石和2件磷灰石样品裂变径迹分析结果.5件锆石裂变径迹年龄介于575±35~380±22 Ma之间,其峰值年龄组为600~572 Ma和420~390 Ma.2件磷灰石裂变径迹年龄介于59±6~27±4 Ma之间,其峰值年龄组为99~80 Ma和19~11 Ma.它们的峰值年龄组分别对应的主要时代为新元古代的埃迪卡拉纪、早泥盆世、晚白垩世和中新世.对比区域上已有的年龄数据可知,南部非洲地区新元古代的埃迪卡拉纪、早泥盆世和晚白垩世的构造活动是一个区域性的构造事件,仅中新世(19~11 Ma)的构造活动在区域上的表现尚不明确.综合前人成果资料,自泛非构造运动以来,班韦乌卢地块至少经历600~572 Ma、488~441 Ma、420~390 Ma、375~293 Ma、99~80 Ma及19~11 Ma六个构造事件.班韦乌卢地块泛非期以来的构造演化研究程度很低,此次研究成果可为今后在该地区的深入研究提供重要参考.  相似文献   
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Studies on urban and periurban agriculture in Zambia have not adequately tackled land use practices in relation to problems associated with wastewater irrigated farming. This study investigated land use practices in two wastewater irrigated farming areas in the industrial towns of Mufulira and Kafue respectively in the Copperbelt and Lusaka provinces of Zambia. Drawing on data from field interviews and focus group discussions, as well as laboratory analysis of the heavy metal content in the wastewater used for irrigation in farm plots at both sites, the study outlines the problems associated with wastewater irrigated farming, including the vulnerability context of those whose livelihoods depend on insecure access to vacant land for informal farming. The findings also confirm the heavy metal contamination of the wastewater used for farming, as well as seepage into the surrounding environment, from mining and industrial enterprises located amidst residential areas. The characteristics of mixed land use, high crop diversification, multiple cropping systems and multiple livelihood practices found in these areas of informal farming are similar to those noted in periurban farming in other developing economy contexts. Given that wastewater irrigated crop farming forms part of the livelihood portfolio among the majority of periurban populations, these preliminary results reinforce the need for municipal authorities to improve scrutiny of land use regulation, raise awareness among informal farmers of the hazards associated with using domestic sewage wastewater and untreated industrial effluents, and ensure improve treatment of the wastewater used for human consumption.  相似文献   
9.
Plant source water identification using stable isotopes is now a common practice in ecohydrological process investigations. Notwithstanding, little critical evaluation of the approaches for source apportionment have been conducted. Here, we present a critical evaluation of the main methods used for source apportionment between vadose and saturated zone water: simple mass balance and Bayesian mixing models. We leverage new isotope stem water samples from a diverse set of tree species in a strikingly uniform terrain and soil conditions at the Christchurch Botanic Garden, New Zealand. Our results show that using δ2H alone in a simple, two‐source mass balance approach leads to erroneous results, particularly an apparent overestimation of groundwater contribution to xylem. Alternatively, using both δ2H and δ18O in a Bayesian inference framework improves the source water estimates and is more useful than the simple mass balance approach, particularly when soil and groundwater contributions are relatively disproportionate. We suggest that plant source water quantification methods should take into consideration the possible effects of 2H/1H fractionation. The Bayesian inference approach used here may be less sensitive to 2H/1H fractionation effects than simple mass balance methods.  相似文献   
10.
Federal regulations governing the disposal of high-level radioactive waste in deep, geologic repositories require an assessment of performance over thousands of years. Because of the long regulatory period involved and the complex nature of the events and processes of interest, prediction of the performance of the disposal system will inevitably include uncertainties. These uncertainties come from a variety of sources, and some are quantifiable and others are not. This paper discusses these uncertainties and outlines approaches for their treatment. Recommendations for the potential resolution of current limitations in the treatment of uncertainties in performance assessment are made. Some general issues, as well as a suggested approach for incorporating expert judgment into quantitative performance assessment analysis, are discussed also.This paper was presented (by title) at Emerging Concepts, MGUS-87 Conference, Redwood City, California, 13–15 April 1987.  相似文献   
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