Historical record of heavy metals in a highly contaminated Mediterranean deposit: The Besòs prodelta     

A. Palanques  J. A. Sanchez-Cabeza  P. Masqu  L. Len 《Marine Chemistry》1998,61(3-4)

The Besòs prodelta, located around a highly populated area, receives the discharge of the Besòs River, one of the most contaminated rivers discharging into the Mediterranean sea. The record of heavy metals accumulated in this prodelta is studied to assess the sedimentary behaviour and the history of the anthropogenic heavy metals in the area. dated sediments have allowed the identification of the sedimentation patterns and the elaboration of dated heavy metals and cenospheres profiles, which reflected the evolution of the anthropogenic impact in this marine environment. Sediments accumulated during the 18th and 19th centuries were already affected by a moderate heavy metal contamination. This contamination increased drastically in the sediments accumulated during the last decades. This data is well correlated with the increase in industrialisation, population and energy consumption in the Besòs drainage basin during the last century.  相似文献   

Heavy metals in particulate matter and sediments in the southern Barcelona sedimentation system (North-western Mediterranean)     

Pere Puig  Albert Palanques  Joan A. Sanchez-Cabeza  Pere Masqu 《Marine Chemistry》1999,63(3-4)

Concentrations of selected heavy metals (Cr, Cu, Ni, Pb and Zn) from surface sediments, suspended particulate matter and settling particles in the southern Barcelona continental margin were studied in order to evaluate the environmental impact of the anthropogenic metals discharged by the Llobregat River in this Mediterranean area. The temporal variation of heavy metals discharged by this river onto the continental shelf is clearly related to the river water flow. Part of the fine sediment and associated heavy metals transported by the Llobregat River during periods of low river flow accumulate on the river bed, and they are totally removed and discharged onto the Barcelona continental shelf during sporadic river water flow increases. Metals produce significant anomalies of chromium (×2.5), copper (×3.4) and zinc (×3.7) in the surface sediments of the Llobregat prodelta and tend to be transported along the continental shelf following the mean flow. Metals associated with the finest suspended flocs transferred to the slope are controlled by the shelf-slope density front and are transported along slope by the general geostrophic current, instead of accumulating and becoming concentrated in the slope bottom sediments. Settling particulate matter collected in sediment traps on the Barcelona continental slope offshore of the shelf-slope front shows low heavy metal concentrations except in a few sediment trap samples that are significantly metal-enriched in chromium (×4.5) and zinc (×6.8). This enrichment is associated with very short and sporadic river flow increases and is only recorded inside the Foix submarine canyon, which acts as a preferential conduit for the shelf-slope sediment transfer.  相似文献   

Reconstruction of hydrocarbons accumulation in sediments affected by the oil refinery industry: the case of Tehuantepec Gulf (Mexico)     

Ana Carolina Ruiz-Fernández  Mario Sprovieri  Mauro Frignani  Joan Albert Sanchez-Cabeza  Maria Luisa Feo  Luca Giorgio Bellucci  Libia Hascibe Pérez-Bernal  Michel Preda  María Luisa Machain-Castillo 《Environmental Earth Sciences》2012,67(3):727-742

The Isthmus of Tehuantepec corresponds to the shortest distance (~200?km) between the Gulf of Mexico and the Pacific Ocean in Southern Mexico, and the main economical activity of this region is oil extraction and refining. Polycyclic aromatic hydrocarbons (PAHs) and total petroleum hydrocarbons (TPHs) were determined in a ²¹⁰Pb dated sediment core collected from the continental shelf of Tehuantepec Gulf, in the vicinity of the oil refinery of Salina Cruz, Oaxaca, the main oil refining facility of the country. The sediments were mostly of coarse nature and hence PAHs and TPHs concentrations throughout the core (61?C404???g?g^?1 and 29?C154?mg?kg^?1, respectively) were below international quality benchmarks. Depth profiles of both PAHs and TPHs concentrations showed increasing trends since the early 1900s but the higher values were found from the 1950s to present. PAH congener ratios showed that these contaminants had both petrogenic and pyrolitic sources, although the former has been predominant since the 1970s. The Salina Cruz refinery started operations in 1978 but the oil industry activities in the Tehuantepec Isthmus go back to the beginning of the twentieth century with the operation of Minatitlan refinery in the Gulf of Mexico, and the Gulf of Tehuantepec being the main conduit for oil distribution in the Pacific coast. The observed changes in contaminant distributions described well the oil industry development in the area.  相似文献   

One century sedimentary record of Hg and Pb pollution in the Sagua estuary (Cuba) derived from Pb and Cs chronology     

M. Díaz-Asencio  C.M. Alonso-Hernndez  Y. Bolanos-lvarez  M. Gmez-Batista  V. Pinto  R. Morabito  J.I. Hernndez-Albernas  M. Eriksson  J.A. Sanchez-Cabeza 《Marine pollution bulletin》2009,59(4-7):108

The vertical distribution of Hg and Pb were determined in a sediment core collected from the Sagua estuary (North Cuba) that receives input from the Sagua river, one of the most polluted rivers discharging into the Cuban coastal environment. Depth profiles of metal concentrations were converted to time-based profiles using the ²¹⁰Pb dating method and confirmed with the ¹³⁷Cs fallout peak. The mean mass accumulation rate was estimated to be 0.17 ± 0.04 g cm⁻² y⁻¹ (mean sediment accumulation rate 0.52 ± 0.13 cm y⁻¹) and the core bottom was estimated to date back about 130 years. The historical sedimentary record showed a strong enrichment of mercury concentrations in the past decades, caused by the incomplete treatment of industrial wastes from a chlor-alkali plant with mercury-cell technology in the Sagua river basin. Lead fluxes to sediments showed a gradual increase from the 1920s to present, which agrees with a population increase in Sagua la Grande City. Fluxes of both metals have increased the past 25 years, with values reaching a maximum of 0.5 and 3.9 μg cm⁻² y⁻¹ for Hg and Pb, respectively.  相似文献   

Metal concentrations, fluxes, inventories and chronologies in sediments from Sepetiba and Ribeira Bays: A comparative study     

Franciane de Carvalho Gomes  Jos Marcus Godoy  Maria Luiza D.P. Godoy  Zenildo Lara de Carvalho  Ricardo Tadeu Lopes  Joan Albert Sanchez-Cabeza  Luiz Drude de Lacerda  Julio Cesar Wasserman 《Marine pollution bulletin》2009,59(4-7):123

Three sediment cores were sampled at Sepetiba Bay and four cores at Ribeira Bay, Rio de Janeiro State, Brazil. Sediment accumulation rates and chronologies were obtained from ²¹⁰Pb activity-depth profiles. Sediment accumulation rates in Ribera Bay ranged from 1.2 mm y⁻¹ in the inner bay to 2.6 mm y⁻¹ close to its entrance. In Sepetiba Bay two sediment accumulation rates were observed: a lower rate of 0.35 cm y⁻¹ before the 1960s and 0.76 cm y⁻¹ since then. The cause of this change is due to the construction of the Santa Cecília impoundment (1955) that brings water from the Paraíba do Sul Basin into the Guandu River, which increased its flow from the original 20 m³ s⁻¹ to 160 m³ s⁻¹. Concentration of 44 elements was obtained by ICP-MS after total dissolution of samples from two selected cores. The relative differences between the concentrations of crustal elements, such as Al, Fe and Ti are only about 20% (p < 0.05). Cd and Zn are 15 and four times larger in Sepetiba Bay than in Ribeira Bay, respectively. Other major and minor elements show lower statistically significant differences. The enrichment factors and metal inventories show that Sepetiba Bay can be considered polluted with Bi, Cd, Cr, Cu, Sb and Zn. Particularly, Cd and Zn present concentrations three and four times higher than the Brazilian existing limits.  相似文献   

Mineralogical signatures and sources of recent sediment in a large tropical lake     

Jorge Feliciano Ontiveros-Cuadras  Ana Carolina Ruiz-Fernández  Joan-Albert Sanchez-Cabeza  Libia Hascibe Pérez-Bernal  Michel Preda  Federico Páez-Osuna 《国际泥沙研究》2018,33(2):183-190

Two lead-210 (²¹⁰Pb) dated sediment cores from Chapala Lake were studied to identify the mineral composition of the sediments and to discuss its relation with trace metals. Minerals and trace metals reflected the domain of volcanic rocks (i.e. basalts, rhyolite and andesite) that characterize Chapala Lake and the Lerma River watershed. Redundancy analyses (RDA) were used to identify the sedimentary variables (magnetic susceptibility, organic matter, sand content, and mineral composition) that could be related to elemental composition. Despite the distance between the two cores (7.3 km) and hydrodynamic circulation the RDA showed that the main mechanism that controls the input of mineral species, and, therefore, element distributions in the lacustrine sediment of Chapala Lake, is related to the weathering of volcanic rocks in the Lerma-Chapala watershed, the consequent runoff and transport of fine grained catchment materials, and later in-lake processes. These findings highlight the importance of controlling watershed erosion to contribute to the improvement of the environmental quality of the lake.  相似文献