Microbial mass-dependent fractionation of chromium isotopes   总被引：1，自引：0，他引：1  

Eric R. Sikora  Thomas M. Johnson  Thomas D. Bullen 《Geochimica et cosmochimica acta》2008,72(15):3631-3641

Mass-dependent fractionation of Cr isotopes occurs during dissimilatory Cr(VI) reduction by Shewanella oneidensis strain MR-1. Cells suspended in a simple buffer solution, with various concentrations of lactate or formate added as electron donor, reduced 5 or 10 μM Cr(VI) to Cr(III) over days to weeks. In all nine batch experiments, ⁵³Cr/⁵²Cr ratios of the unreacted Cr(VI) increased as reduction proceeded. In eight experiments covering a range of added donor concentrations up to 100 μM, isotopic fractionation factors were nearly invariant, ranging from 1.0040 to 1.0045, with a mean value somewhat larger than that previously reported for abiotic Cr(VI) reduction (1.0034). One experiment containing much greater donor concentration (10 mM lactate) reduced Cr(VI) much faster and exhibited a lesser fractionation factor (1.0018). These results indicate that ⁵³Cr/⁵²Cr measurements should be effective as indicators of Cr(VI) reduction, either bacterial or abiotic. However, variability in the fractionation factor is poorly constrained and should be studied for a variety of microbial and abiotic reduction pathways.  相似文献   

Use of Chemical and Isotopic Tracers to Characterize the Interactions Between Ground Water and Surface Water in Mantled Karst   总被引：6，自引：0，他引：6  

Brian G. Katz  Tyler B. Coplen  Thomas D. Bullen  J. Hal Davis 《Ground water》1997,35(6):1014-1028

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Chromian spinel as a petrogenetic indicator in abyssal and alpine-type peridotites and spatially associated lavas   总被引：70，自引：0，他引：70  

Henry J. B. Dick  Thomas Bullen 《Contributions to Mineralogy and Petrology》1984,86(1):54-76

The composition of chromian spinel in alpine-type peridotites has a large reciprocal range of Cr and Al, with increasing Cr# (Cr/(Cr+Al)) reflecting increasing degrees of partial melting in the mantle. Using spinel compositions, alpine-type peridotites can be divided into three groups. Type I peridotites and associated volcanic rocks contain spinels with Cr#<0.60; Type III peridotites and associated volcanics contain spinels with Cr#>0.60, and Type II peridotites and volcanics are a transitional group and contain spinels spanning the full range of spinel compositions in Type I and Type II peridotites. Spinels in abyssal peridotites lie entirely within the Type I spinel field, making ophiolites with Type I alpine-type peridotites the most likely candidates for sections of ocean lithosphere formed at a midocean ridge. The only modern analogs for Type III peridotites and associated volcanic rocks are found in arc-related volcanic and intrusive rocks, continental intrusive assemblages, and oceanic plateau basalts. We infer a sub-volcanic arc petrogenesis for most Type III alpine-type peridotites. Type II alpine-type peridotites apparently reflect composite origins, such as the formation of an island-arc on ocean crust, resulting in large variations in the degree and provenance of melting over relatively short distances. The essential difference between Type I and Type III peridotites appears to be the presence or absence of diopside in the residue at the end of melting.Based on an examination of co-existing rock and spinel compositions in lavas, it appears that spinel is a sensitive indicator of melt composition and pressure of crystallization. The close similarity of spinel composition fields in genetically related basalts, dunites and peridotites at localities in the oceans and in ophiolite complexes indicates that its composition reflects the degree of melting in the mantle source region. Accordingly, we infer from the restricted range of spinel compositions in abyssal basalts that the degree of mantle melting beneath mid-ocean ridges is generally limited to that found in Type I alpine-type peridotites. It is apparent, therefore, that the phase boundary OL-EN-DI-SP +meltOL-EN-SP+melt has limited the degree of melting of the mantle beneath mid-ocean ridges. This was clearly not the case for many alpine-type peridotites, implying very different melting conditions in the mantle, probably involving the presence of water.  相似文献   

Allowance for Seismic Velocity Gradient in a Horizontally Layered Flat Earth     

K. E. Bullen 《Geophysical Journal International》1965,10(1):45-49

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Using Stable Isotopes of Water and Strontium to Investigate the Hydrology of a Natural and a Constructed Wetland   总被引：3，自引：0，他引：3  

Randall J. Hunt  Thomas D. Bullen  David P. Krabbenhoft  Carol Kendall 《Ground water》1998,36(3):434-443

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ON RAYLEIGH WAVES ACROSS THE PACIFIC OCEAN     

K. E. Bullen 《Geophysical Journal International》1939,4(8):579-582

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The Earth's Core: J.A. Jacobs. Academic Press,London, 1975, 253 pp., UK £8.50.     

K.E. Bullen 《Physics of the Earth and Planetary Interiors》1976,13(1):79-80

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Some International Seismological Summary Reminiscences     

K. E. Bullen 《Geophysical Journal International》1970,20(4):359-365

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Note on Incompressibility-Pressure Gradients in the Earth's Core     

K. E. Bullen 《Geophysical Journal International》1976,44(3):717-718

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AN EARTH MODEL BASED ON A COMPRESSIBILITY-PRESSURE HYPOTHESIS     

K. E. Bullen 《Geophysical Journal International》1961,6(1):50-59

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