Kinetic studies of lead(II) uptake by the seagrass Zostera muelleri in water by radiotracing,atomic absorption spectrometry and electrochemical techniques     

Alan M Bond  Julie R Bradbury  Henry A Hudson  John S Garnham  Peter J Hanna  Stanley Strother 《Marine Chemistry》1985,16(1):1-9

Evidence was found that uptake of lead from seawater in both model and natural systems by the leaves of the seagrass Zostera muelleri does occur for live, dead and scraped leaves at all the lead concentrations tested. Positive uptake of lead was measured using the three analytical techniques of radio-tracer, differential pulse anodic stripping voltammetry and atomic absorption spectrometry; similar uptake profiles were obtained for each technique. Profiles always showed an initial rapid uptake phase followed by a gradual transition to a plateau phase at which an approximate equilibrium between lead attached to seagrass and free ionic lead in seawater was reached. The presence of active lead uptake processes was indicated in experiments which attempted to remove lead from leaves by a chelating agent.  相似文献   

Frequency distributions and correlations of solar X-ray flare parameters   总被引：3，自引：0，他引：3  

Norma B. Crosby  Markus J. Aschwanden  Brian R. Dennis 《Solar physics》1993,143(2):275-299

We have determined frequency distributions of flare parameters from over 12000 solar flares recorded with the Hard X-Ray Burst Spectrometer (HXRBS) on the Solar Maximum Mission (SMM) satellite. These parameters include the flare duration, the peak counting rate, the peak hard X-ray flux, the total energy in electrons, and the peak energy flux in electrons (the latter two computed assuming a thick-target flare model). The energies were computed above a threshold energy between 25 and 50 keV. All of the distributions can be represented by power laws above the HXRBS sensitivity threshold. Correlations among these parameters are determined from linear regression fits as well as from the slopes of the frequency distributions. Variations of the frequency distributions were investigated with respect to the solar activity cycle.Theoretical models for the frequency distribution of flare parameters depend on the probability of flaring and the temporal evolution of the flare energy build-up. Our results are consistent with stochastic flaring and exponential energy build-up, with an average build-up time constant that is 0.5 times the mean time between flares. The measured distributions of flares are also consistent with predicted distributions of flares from computer simulations of avalanche models that are governed by the principle of self-organized criticality.  相似文献   

Optimal Compensation and Implementation for Adaptive Optics Systems     

Douglas P. Looze  Markus Kasper  Stefan Hippler  Orhan Beker  Robert Weiss 《Experimental Astronomy》2003,15(2):67-88

This paper develops a compensation algorithm based on Linear–Quadratic–Gaussian (LQG) control system design whose parameters are determined (in part) by a model of the atmosphere. The model for the atmosphere is based on the open-loop statistics of the atmosphere as observed by the wavefront sensor, and is identified from these using an auto-regressive, moving average (ARMA) model. The (LQG) control design is compared with an existing compensation algorithm for a simulation developed at ESO that represents the operation of MACAO adaptive optics system on the 8.2 m telescopes at Paranal, Chile. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

First VLTI observations of Mira stars     

Andrea Richichi  Markus Wittkowski 《Astrophysics and Space Science》2003,286(1-2):219-224

We present first observations of Mira stars obtained at the Very Large Telescope Interferometer (VLTI) at 2 microns, equipped with the VINCI instrument, using different baselines with both the test siderostats and the 8.2 m unit telescopes. These observations, collected in the course of the VLTI commissining program, have targeted so far about sixty cool giant stars. In this talk, we list and describe the measurements obtained for 14 Mira stars, many of them representing first-time determinations of the visibility. In particular, we devote special attention to a study of Mira itself, for which very accurate determinations of the visibility at several baseline lenghts and orientations could be obtained. We find that a two-component model is more consistent with the data than a single stellar disc. Further observations are needed for a better understanding of this source. The VLTI will constitute an ideal instrument for such studies in the future. In particular it will permit detailed investigations of southern AGB stars, such as accurate measurements of surface structureparameters (diameters, diameter variations, asymmetries, center-to-limbvariations, special features like hot spots) and of circumstellar envelopes. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Relationship between footwall composition,crustal contamination,and fluid–rock interaction in the Platreef,Bushveld Complex,South Africa     

Julie Pronost  Chris Harris  Christian Pin 《Mineralium Deposita》2008,43(8):825-848

In the northern limb of the 2.06-Ga Bushveld Complex, the Platreef is a platinum group elements (PGE)-, Cu-, and Ni-mineralized zone of pyroxenite that developed at the intrusion margin. From north to south, the footwall rocks of the Platreef change from Archaean granite to dolomite, hornfels, and quartzite. Where the footwall is granite, the Sr-isotope system is more strongly perturbed than where the footwall is Sr-poor dolomite, in which samples show an approximate isochron relationship. The Nd-isotope system for samples of pyroxenite and hanging wall norite shows an approximate isochron relationship with an implied age of 2.17 ± 0.2 Ga and initial Nd-isotope ratio of 0.5095. Assuming an age of 2.06 Ga, the ɛNd values range from −6.2 to −9.6 (ave. −7.8, n = 17) and on average are slightly more negative than the Main Zone of the Bushveld. These data are consistent with local contamination of an already contaminated magma of Main Zone composition. The similarity in isotope composition between the Platreef pyroxenites and the hanging wall norites suggests a common origin. Where the country rock is dolomite, the Platreef has generally higher plagioclase and pyroxene δ ¹⁸O values, and this indicates assimilation of the immediate footwall. Throughout the Platreef, there is considerable petrographic evidence for sub-solidus interaction with fluids, and the Δ _{plagioclase–pyroxene} values range from −2 to +6, which indicates interaction at both high and low temperatures. Whole-rock and mineral δD values suggest that the Platreef interacted with both magmatic and meteoric water, and the lack of disturbance to the Sr-isotope system suggests that fluid–rock interaction took place soon after emplacement. Where the footwall is granite, less negative δD values suggest a greater involvement of meteoric water. Consistently higher values of Δ _{plagioclase–pyroxene} in the Platreef pyroxenites and hanging wall norites in contact with dolomite suggest prolonged interaction with CO₂-rich fluid derived from decarbonation of the footwall rocks. The overprint of post crystallization fluid–rock interaction is the probable cause of the previously documented lack of correlation between PGE and sulfide content on the small scale. The Platreef in contact with dolomite is the focus of the highest PGE grades, and this suggests that dolomite contamination played a role in PGE concentration and deposition, but the exact link remains obscure. It is a possibility that the CO₂ produced by decarbonation of assimilated dolomite enhanced the process of PGE scavenging by sulfide precipitation.  相似文献   

Belemnites from the lower middle Cenomanian of Hoppenstedt, northern Germany: significance and integrated correlation     

Markus Wilmsen  Michel Rabe 《Cretaceous Research》2008,29(5-6):936

The belemnite species Praeactinocamax primus (Arkhangelsky, 1912) and Belemnocamax boweri Crick, 1910 are described from the Cenomanian of the abandoned limestone quarry section of Hoppenstedt (Sachsen-Anhalt, northern Germany). They co-occur in the upper part of a prominent tripartite bioclastic limestone bed associated with the ammonite Acanthoceras rhotomagense, indicating the primus Event of the lower middle Cenomanian A. rhotomagense ammonite Zone. An integrated stratigraphical calibration including carbon stable isotope correlation to southern England suggests that the belemnite event horizon at Hoppenstedt occupies exactly the same chronostratigraphical position as elsewhere, highlighting the strictly isochronous character of the primus Event across northwestern Europe. Furthermore, stratigraphical gaps in the Hoppenstedt succession are evaluated.  相似文献   

Controlling geological and hydrogeological processes in an arsenic contaminated aquifer on the Red River flood plain,Vietnam   总被引：1，自引：0，他引：1  

Flemming Larsen  Nhan Quy Pham  Nhan Duc Dang  Dieke Postma  Søren Jessen  Viet Hung Pham  Thao Bach Nguyen  Huy Duc Trieu  Luu Thi Tran  Hoan Nguyen  Julie Chambon  Hoan Van Nguyen  Dang Hoang Ha  Nguyen Thi Hue  Mai Thanh Duc  Jens Christian Refsgaard 《Applied Geochemistry》2008

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Benthic photosynthesis in submerged Wadden Sea intertidal flats   总被引：3，自引：1，他引：3  

Markus Billerbeck  Hans Ry  Katja Bosselmann  Markus Huettel 《Estuarine, Coastal and Shelf Science》2007,71(3-4):704-716

In this study we compare benthic photosynthesis during inundation in coarse sand, fine sand, and mixed sediment (sand/mud) intertidal flats in the German Wadden Sea. In situ determinations of oxygen-, DIC- and nutrient fluxes in stirred benthic chamber incubations were combined with measurements of sedimentary chlorophyll, incident light intensity at the sediment surface and scalar irradiance within the sediment. During submergence, microphytobenthos was light limited at all study sites as indicated by rapid response of gross photosynthesis to increasing incident light at the sea floor. However, depth integrated scalar irradiance was 2 to 3 times higher in the sands than in the mud. Consequently, gross photosynthesis in the net autotrophic fine sand and coarse sand flats during inundation was on average 4 and 11 times higher than in the net heterotrophic mud flat, despite higher total chlorophyll concentration in mud. Benthic photosynthesis may be enhanced in intertidal sands during inundation due to: (1) higher light availability to the microphytobenthos in the sands compared to muds, (2) more efficient transport of photosynthesis-limiting solutes to the microalgae with pore water flows in the permeable sands, and (3) more active metabolic state and different life strategies of microphytobenthos inhabiting sands.  相似文献   

The Western European PSSA—Testing a unique international concept to protect imperilled marine ecosystems     

Markus Detjen 《Marine Policy》2006

Particularly Sensitive Sea Areas (PSSAs) are a tool designed to protect vulnerable marine areas from vessel-source pollution through measures approved by the governing body, the International Maritime Organisation. Recent developments triggered by the proposal to designate, amongst others, a large part of the Western European Atlantic a PSSA have brought the instrument to a decisive stage. Although the proposal appears to be lawful, its implications for the concept, which this paper seeks to assess, are questionable. The significance of the instrument is at risk if it is overused. As a consequence, new protective mechanisms should be contemplated.  相似文献   

A new titanium-bearing calcium aluminosilicate phase: II. Crystallography and crystal chemistry of grains formed in slowly cooled melts with bulk compositions of calcium- aluminum-rich inclusions     

David J. Barber  John R. Beckett  Julie M. Paque  Edward Stolper 《Meteoritics & planetary science》1994,29(5):682-690

Abstract The crystallography and crystal chemistry of a new calcium-titanium-aluminosilicate mineral (UNK) observed in synthetic analogs to calcium-aluminum-rich inclusions (CAIs) from carbonaceous chondrites was studied by electron diffraction techniques. The unit cell is primitive hexagonal or trigonal, with a = 0.790 ± 0.002 nm and c = 0.492 ± 0.002 nm, similar to the lattice parameters of melilite and consistent with cell dimensions for crystals in a mixer furnace slag described by Barber and Agrell (1994). The phase frequently displays an epitactic relationship in which melilite acts as the host, with (0001)_UNK | (001)_mel and <10T0>_UNK | <100>_mel. If one of the two space groups determined by Barber and Agrell (1994) for their sample of UNK is applicable (P3ml or P31m), then the structure is probably characterized by puckered sheets of octahedra and tetrahedra perpendicular to the c-axis with successive sheets coordinated by planar arrays of Ca. In this likely structure, each unit cell contains three Ca sites located in mirror planes, one octahedrally coordinated cation located along a three-fold axis and five tetrahedrally coordinated cations, three in mirrors and two along triads. The octahedron contains Ti but, because there are 1.3–1.9 cations of Ti/formula unit, some of the Ti must also be in tetrahedral coordination, an unusual but not unprecedented situation for a silicate. Tetrahedral sites in mirror planes would contain mostly Si, with lesser amounts of Al while those along the triads correspondingly contain mostly Al with subordinate Ti. The structural formula, therefore, can be expressed as with Si + Ti = 4. Compositions of meteoritic and synthetic Ti-bearing samples of the phase can be described in terms of a binary solid solution between the end-members Ca₃TiAl₂Si₃O₁₄ and Ca₃Ti(AlTi)(AlSi₂)O₁₄. A Ti-free analog with a formula of Ca₃Al₂Si₄O₁₄ synthesized by Paque et al. (1994) is thought to be related structurally but with the octahedral site being occupied by Al, that is   相似文献