Experimental silicate mineral/melt partition coefficients for beryllium and the crustal Be cycle from migmatite to pegmatite   总被引：1，自引：0，他引：1  

Joseph M Evensen  David London 《Geochimica et cosmochimica acta》2002,66(12):2239-2265

Partition coefficients (D_Be^mineral/melt) for beryllium between hydrous granitic melt and alkali feldspars, plagioclase feldspars, quartz, dark mica, and white mica were determined by experiment at 200 MPa H₂O as a function of temperature (650-900°C), activity of Be in melt (trace levels to beryl saturation), bulk composition, and thermal run direction. At trace levels, Be is compatible in plagioclase of An₃₁ (1.84 at 700°C) and muscovite (1.35 at 700°C) but incompatible in biotite (0.39-0.54 from 650-800°C), alkali feldspar (0.38-0.19 from 680-850°C), quartz (0.24 at 800°C), and albite (0.10 at 750°C). The partition coefficients are different at saturation of the melt in beryl: lower in the case of plagioclase of An₃₁ (0.89 at 700°C), muscovite (0.87 at 700°C), biotite (0.18-0.08 from 675-800°C), alkali feldspar (0.18-0.14 from 680-700°C), and quartz (0.17-0.08 from 750-800°C), but higher in the case of albite (0.37 at 750°C).With other data sources, these new partition coefficients were utilized to track, first, the distribution of Be between aluminous quartzofeldspathic source rocks and their anatectic melts, and second, the dispersion or concentration of Be in melt through igneous crystal fractionation of different magma types (e.g., S-type, I-type) up to beryl-saturated granitic pegmatites and, finally, into their hydrothermal aureoles. Among the rock-forming minerals, cordierite, calcic oligoclase, and muscovite (in this order) control the fate of Be because of the compatibility of Be in these phases. In general, beryl-bearing pegmatites can arise only after extended crystal fractionation of large magma batches (to F, fraction of melt remaining, ≤0.05); granitic magmas that originate from cordierite-bearing protoliths or that contain large modal quantities of calcic oligoclase will not achieve beryl saturation at any point in their evolution.  相似文献   

Trace-element partitioning at conditions far from equilibrium: Ba and Cs distributions between alkali feldspar and undercooled hydrous granitic liquid at 200 MPa     

George B. Morgan  David London 《Contributions to Mineralogy and Petrology》2003,144(6):722-738

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一个高分辨对流层物质交换模式   总被引：2，自引：1，他引：2       下载免费PDF全文

雷孝恩  J.S.Chang 《气象学报》1993,51(1):75-86

在区域酸沉积模式(RADM)基础上,设计了一个高分辨对流层(TL)物质交换模式(EM3)。EM3在以下五个方面明显不同于RADM:第一,增加行星边界层(PBL)的垂直网格层次;第二、TL内考虑分层的垂直涡旋扩散系数型;第三,使用TL内分层的水平涡旋扩散系数型;第四,采用包含有植物冠层垂直结构影响的新干沉积速度型;第五,使用数值扩散小的二阶矩守恒平流格式.用EM3和RADM对OSCAR Ⅳ实例作对比模拟,结果表明EM3能更好地预测出TL内的三维物质分布规律,在同样条件下,两模式预测的PBL低层中心浓度比值均大于1.8,最大值可大于3。  相似文献   

Numerical study on dry deposition processes in canopy layer     

Lei Xiaoen  Julius S. Chang 《大气科学进展》1992,9(4):491-500

A coupling model between the canopy layer (CL) and atmospheric boundary layer (ABL) for the study of dry deposition velocity is developed. The model consists of six parts: chemical species conservation equation including absorptive factor; the species uptake action including detailed vertical variation of absorptive element in CL; momen-tum exchange in CL which is represented by a first-order closure momentum equation with an additional larger-scale diffusive term; momentum exchange in ABL which is described by a complete set of the ABL turbulent statistic parameters; absorptivity (or solubility or reflection) at the surface including effects of the physical and chemi-cal characters of the species, land type, seasonal and diurnal variations of the meteorological variables; and deposition velocity derived by distributions of the species with height in CL. Variational rules of the concentration and deposi-tion velocity with both height and time are simulated with the model for both corn and forest canopies. Results pre-dicted with the bulk deposition velocity derived in the paper consist well with experimental data.  相似文献   

Further studies of ozone and sunspots     

London  Julius  Oltmans  Samuel 《Pure and Applied Geophysics》1973,106(1):1302-1307

Pure and Applied Geophysics -  相似文献   

Isoseismals of the strongest Friuli aftershocks of September 1976     

Vít Kárník  Dana Procházková  Zdeňka Schenková  Julius Drimmel  Dieter Mayer-Rosa  Dragutin Cvijanovic  Vladimir Kuk  Andelka Miloševič  Francesco Giorgetti  Reviewer J. Janský 《Studia Geophysica et Geodaetica》1978,22(4):411-414

Summary Isoseismal maps of the three strongest Friuli aftershocks of September 1976 were compiled using the contributions from European countries within the shaken area. The characteristic features of the macroseismic fields are discussed.  相似文献   

Dynamics of pelagic variables in two contrasting coastal systems in the western Hokkaido coast off Otaru port,Japan     

Julius I. Agboola  Mario Uchimiya  Isao Kudo  Kazuo Kido  Masato Osawa 《Estuarine, Coastal and Shelf Science》2010,86(3):477-484

Human impact on adjacent coastal waters, leading to alteration in nutritional environment and hence affecting phytoplankton biomass (Chlorophyll a), will probably be enhanced by the nearby presence of ports. The main goal of this study is to assess the influence of nearby presence of port on phytoplankton biomass build-up and the physical–chemical environmental characteristics in two contrasting coastal systems (Otaru port, S-IN and an exposed coastal area, S-OUT) in the western Hokkaido coast off Otaru port, Japan. Sampling was conducted on “bi-weekly and monthly” basis during the period of September 2006–December 2007 and data comprising 11 pelagic variables were obtained. In most instance, phytoplankton biomass, nutrients' (NH₄, NO₃, PO₄, and Si(OH)₄) concentrations and nutrients' molar ratios were higher at the Otaru port location. Physical parameters (temperature, salinity, hydrogen ion concentration (pH), photosynthetically active radiation (PAR) and dissolved oxygen, (DO)) were not significantly different (P > 0.05) between the two locations. With the exception of salinity, pH and DIC, all variables measured showed significant variation (P < 0.05) with season. While the coefficient of variation (CV) of physical parameters and phytoplankton biomass were relatively higher in Otaru port location (S-IN), the exposed coastal location (S-OUT) showed a higher variation in chemical parameters. Other variables showed different patterns between the two locations. We conclude that ports, due to its activities and restricted circulation favour high nutrient loading and phytoplankton biomass build-up in adjacent coastal systems, thus, suggesting the need for continuous field observation data in order to advance our knowledge on possible future human impact on coastal environment and the need to monitor and control port activities.  相似文献   

Experiments on the kinetics of partial melting of a leucogranite at 200 MPa H<Subscript>2</Subscript>O and 690–800°C: compositional variability of melts during the onset of H<Subscript>2</Subscript>O-saturated crustal anatexis     

Antonio?Acosta-VigilEmail author  David?London  George?B.?Morgan 《Contributions to Mineralogy and Petrology》2006,151(5):539-557

We have experimentally investigated the kinetics of melting of an aplitic leucogranite (quartz+sodic plagioclase of ≈Ab₉₀+K-feldspar+traces of biotite) at 690, 740, and 800°C, all at 200 MPa H₂O. Leucogranite cylinders, 3.5 mm in diameter and 7 mm in length, were run in the presence of excess H₂O using cold-seal pressure vessels for 11–2,925 h. At 690 and 740°C and any experimental time, and 800°C and short run times, silicate glass (melt at run conditions) occurs as interconnected films along most of the mineral boundaries and in fractures, with the predominant volume occurring along quartz/feldspars boundaries and quartz/plagioclase/K-feldspar triple junctions. Glass film thickness is roughly constant throughout a given experimental charge and increases with experimental temperature and run duration. The results indicate that H₂O-saturated partial melting of a quartzo-feldspathic protolith will produce an interconnected melt phase even at very low degrees (<5 vol%) of partial melting. Crystal grain boundaries are therefore completely occluded with melt films even at the lowest degrees of partial melting, resulting in a change in the mechanism of mass transport through the rock from advection of aqueous vapor to diffusion through silicate melt. At 690 and 740°C the compositions of glasses are homogeneous and (at both temperatures) close to, but not on, the H₂O-saturated 200 MPa haplogranite eutectic; glass compositions do not change with run duration. At 800°C glasses are heterogeneous and plot away from the minimum, although their molar ratios ASI (=mol Al₂O₃/CaO+Na₂O+K₂O) and Al/Na are constant throughout the entire charge at any experimental time. Glass compositions within individual 800°C experiments form linear trends in (wt%) normative quartz–albite–orthoclase space. The linear trends are oriented perpendicular to the 200 MPa H₂O haplogranite cotectic line, reflecting nearly constant albite/orthoclase ratio versus variable quartz/feldspar ratio, and have endpoints between the 800°C isotherms on the quartz and feldspar liquidus surfaces. With increasing experimental duration the trends migrate from the potassic side of the minimum toward the bulk rock composition located on the sodic side, due to more rapid (and complete) dissolution of K-feldspar relative to plagioclase. The results indicate that partial melting at or slightly above the solidus (690–740°C) is interface reaction-controlled, and produces disequilibrium melts of near-minimum composition that persist metastably for up to at least 3 months. Relict feldspars show no change in composition or texture, and equilibration between melt and feldspars might take from a few to tens of millions of years. Partial melting at temperatures well above the solidus (800°C) produces heterogeneous, disequilibrium liquids whose compositions are determined by the diffusive transport properties of the melt and local equilibrium with neighboring mineral phases. Feldspars recrystallize and change composition rapidly. Partial melting and equilibration between liquids and feldspars might take from a few to tens of years (H₂O-saturated conditions) at these temperatures well above the solidus.  相似文献   

A preliminary investigation of siliceous microfossil succession in late Quaternary sediments from Lake Baikal, Siberia     

M. L. Julius  E. F. Stoermer  S. M. Colman  T. C. Moore 《Journal of Paleolimnology》1997,18(2):189-206

Siliceous microfossil assemblage succession was analyzed in a 100 m sediment core from Lake Baikal, Siberia. The core was recovered from the lake's central basin at a water depth of 365 m. Microfossil abundance varied greatly within the intervals sampled, ranging from samples devoid of siliceous microfossils to samples with up to 3.49 × 10¹¹ microfossils g^-1 sediment. Fluctuations in abundance appear to reflect trends in the marine ¹⁸O record, with peak microfossil levels generally representing climate optima. Microfossil taxa present in sampled intervals changed considerably with core depth. Within each sample a small number of endemic diatom species dominated the assemblage. Changes in dominant endemic taxa between sampled intervals ranged from extirpation of some taxa, to shifts in quantitative abundance. Differences in microfossil composition and the association of variations in abundance with climate fluctuations suggest rapid speciation in response to major climatic excursions.  相似文献   

Die morphologischen Wirkungen des Eiszeitklimas im gletscherfreien Gelbiet     

Julius Büdel 《International Journal of Earth Sciences》1944,34(7-8):482-519

Ohne Zusammenfassung  相似文献