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1.
The passivation of calcite by acid mine water. Column experiments with ferric sulfate and ferric chloride solutions at pH 2 总被引:2,自引:1,他引:1
Josep M. Soler Marco Boi Jos Luis Mogolln Jordi Cama Carlos Ayora Peter S. Nico Nobumichi Tamura Martin Kunz 《Applied Geochemistry》2008,23(12):3579-3588
Column experiments, simulating the behavior of passive treatment systems for acid mine drainage, have been performed. Acid solutions (HCl or H2SO4, pH 2), with initial concentrations of Fe(III) ranging from 250 to 1500 mg L−1, were injected into column reactors packed with calcite grains at a constant flow rate. The composition of the solutions was monitored during the experiments. At the end of the experiments (passivation of the columns), the composition and structure of the solids were measured. The dissolution of calcite in the columns caused an increase in pH and the release of Ca into the solution, leading to the precipitation of gypsum and Fe–oxyhydroxysulfates (Fe(III)–SO4–H+ solutions) or Fe–oxyhydroxychlorides (Fe(III)–Cl–H+ solutions). The columns worked as an efficient barrier for some time, increasing the pH of the circulating solutions from 2 to 6–7 and removing its metal content. However, after some time (several weeks, depending on the conditions), the columns became chemically inert. The results showed that passivation time increased with decreasing anion and metal content of the solutions. Gypsum was the phase responsible for the passivation of calcite in the experiments with Fe(III)–SO4–H+ solutions. Schwertmannite and goethite appeared as the Fe(III) secondary phases in those experiments. Akaganeite was the phase responsible for the passivation of the system in the experiments with Fe(III)–Cl–H+ solutions. 相似文献
2.
Masao Komazawa Hitoshi Morikawa Kajuro Nakamura Junpei Akamatsu Keiichi Nishimura Sumio Sawada Ayfer Erken Akin Onalp 《Soil Dynamics and Earthquake Engineering》2002,22(9-12):829-836
The 1999 Kocaeli earthquake brought serious damage to downtown of Adapazari. To study why strong motions were generated at the town, a bedrock structure was investigated on the basis of Bouguer gravity anomaly, and SPAC and H/V analyses of microseisms. It was revealed that, the basin consists of three narrow depressions of bedrock with very steep edges, extending in E–W or NE–SW directions along the North Anatolia faults, and the depth to bedrock reaches 1000 m or more. Downtown of Adapazari is located 1–2 km apart from the basin-edge. It is considered that, the specific configuration of bedrock amplifies ground motions at the downtown area by focusing of seismic waves and/or interference between incident S-waves and surface-waves secondarily generated at the basin-edge. Studying 3D bedrock structure is an urgent issue for microzoning an urban area in a sedimentary basin. 相似文献
3.
Hiroshi Kobayashi Keiichi Tamura Shunsuke Tanimoto 《Soil Dynamics and Earthquake Engineering》2002,22(9-12):1135-1141
In order to improve seismic design technology of bridges, it is necessary to evaluate the vibration characteristics of a bridge–soil system that consists of soil, foundation structure, pier and superstructure. However, there have been few experimental studies on seismic behavior of bridge–soil system. In this paper, we conducted the hybrid vibration experiment on seismic behavior of bridge–soil system, and examined the applicability of hybrid vibration experiment to study seismic response of bridge–soil system. Based on the experiment results, seismic response of bridge was quantitatively studied. 相似文献
4.
Takeshi Kuramochi Jusen Asuka Hanna Fekete Kentaro Tamura Niklas Höhne 《Climate Policy》2016,16(8):1029-1047
This article assesses Japan's carbon budgets up to 2100 in the global efforts to achieve the 2?°C target under different effort-sharing approaches based on long-term GHG mitigation scenarios published in 13 studies. The article also presents exemplary emission trajectories for Japan to stay within the calculated budget.The literature data allow for an in-depth analysis of four effort-sharing categories. For a 450?ppm CO2e stabilization level, the remaining carbon budgets for 2014–2100 were negative for the effort-sharing category that emphasizes historical responsibility and capability. For the other three, including the reference ‘Cost-effectiveness’ category, which showed the highest budget range among all categories, the calculated remaining budgets (20th and 80th percentile ranges) would run out in 21–29 years if the current emission levels were to continue. A 550?ppm CO2e stabilization level increases the budgets by 6–17 years-equivalent of the current emissions, depending on the effort-sharing category. Exemplary emissions trajectories staying within the calculated budgets were also analysed for ‘Equality’, ‘Staged’ and ‘Cost-effectiveness’ categories. For a 450?ppm CO2e stabilization level, Japan's GHG emissions would need to phase out sometime between 2045 and 2080, and the emission reductions in 2030 would be at least 16–29% below 1990 levels even for the most lenient ‘Cost-effectiveness’ category, and 29–36% for the ‘Equality’ category. The start year for accelerated emissions reductions and the emissions convergence level in the long term have major impact on the emissions reduction rates that need to be achieved, particularly in the case of smaller budgets.Policy relevanceIn previous climate mitigation target formulation processes for 2020 and 2030 in Japan, neither equity principles nor long-term management of cumulative GHG emissions was at the centre of discussion. This article quantitatively assesses how much more GHGs Japan can emit by 2100 to achieve the 2?°C target in light of different effort-sharing approaches, and how Japan's GHG emissions can be managed up to 2100. The long-term implications of recent energy policy developments following the Fukushima nuclear disaster for the calculated carbon budgets are also discussed. 相似文献
5.
This work presents the results of geochemical (LA-ICP-MS) study of minerals of peridotites from ophiolite complexes of the Polar Urals to clarify the nature of these formations. The distribution of trace and rare earth elements in clinopyroxenes testifies that there were three types of the mantle substratum, which formed in different geodynamic settings. Two types of primary peridotites were formed upon partial melting of the mantle at different-depth levels in the subduction zone. The first type is represented by lherzolites and diopside harzburgites, formed at partial melting under the spinel facies conditions; the second type is represented by diopside harzburgites, formed under polybaric partial melting under the garnet and spinel facies conditions. In the suprasubduction zone, peridotites experienced fluid-induced partial melting that resulted in crystallization of harzburgites. All types of harzburgites were transformed by ascending melts and fluids (refertilization) and high-temperature hydration with the formation of amphibole. These processes are recorded in variations in the REE spectra of minerals. 相似文献
6.
Kosuke Tamura Dustin T. Duncan Jessica Athens Marc Scott Michael RientiJr. Jared Aldstadt Laurie M. Brotman Brian Elbel 《GeoJournal》2018,83(4):775-782
Sedentary behavior and lack of physical activity are key modifiable behavioral risk factors for chronic health problems, such as obesity and diabetes. Little is known about how sedentary behavior and physical activity among adolescents spatially cluster. The objective was to detect spatial clustering of sedentary behavior and physical activity among Boston adolescents. Data were used from the 2008 Boston Youth Survey Geospatial Dataset, a sample of public high school students who responded to a sedentary behavior and physical activity questionnaire. Four binary variables were created: (1) TV watching (>2 h/day), (2) video games (>2 h/day), (3) total screen time (>2 h/day); and (4) 20 min/day of physical activity (≥5 days/week). A spatial scan statistic was utilized to detect clustering of sedentary behavior and physical activity. One statistically significant cluster of TV watching emerged among Boston adolescents in the unadjusted model. Students inside the cluster were more than twice as likely to report >2 h/day of TV watching compared to respondents outside the cluster. No significant clusters of sedentary behavior and physical activity emerged. Findings suggest that TV watching is spatially clustered among Boston adolescents. Such findings may serve to inform public health policy-makers by identifying specific locations in Boston that could provide opportunities for policy intervention. Future research should examine what is linked to the clusters, such as neighborhood environments and network effects. 相似文献
7.
Natural Hazards - Foreigners tend to be vulnerable to disasters due to religious and cultural differences. In Japan, Muslim foreign residents, who are minorities, likely face difficulties in terms... 相似文献
8.
Climatic Change - The objective of this study is to assess the global impact of sea level rise and to evaluate the effectiveness of adaptation. Global areas of inundation due to sea level rise are... 相似文献
9.
Geophysical analysis of zonal tidal signals in length of day 总被引:5,自引:0,他引:5
Benjamin Fong Chao James B. Merriam Yoshiaki Tamura 《Geophysical Journal International》1995,122(3):765-775
10.