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Progress in the introduction of coulometry for the analysis of total carbon dioxide (TCO2) in marine waters is described. An extractor—stripper removes CO2 that is measured coulometrically by the quantity of electricity (coulombs) used to electrogenerate OH? ions for the titration of the acid formed by the reaction of CO2 and ethanolamine. The equivalence point is detected photometrically with thymolphthalein as the indicator, and Faraday's Law relates coulombs to equivalents of titrant generated and CO2 determined so that there are no standard curves needed or titrants to standardize or store. Accuracy was determined by adding gelatin capsules containing 100–1500 μg C of pure CaCO3 into the stripper, and accuracies of better than ± 1 μg C were achieved. The best precision for natural seawater (± 1 standard error) of ± 0.5 μmol l?1 was found for 17 samples of Bermuda coastal waters having a mean TCO2 of 2007.2 μmol l?1 (0.05% CV). Sources of error and precautions are discussed. This method, which has been used successfully at sea, can be used to study a variety of marine phenomena involving TCO2.  相似文献   
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Lithostratigraphical and lithofacies approaches used to interpret glacial sediments often ignore deformation structures that can provide the key to environment of formation. We propose a classification of deformation styles based on the geometry of structures rather than inferred environment of formation. Five styles are recognised: pure shear (P), simple shear (S), compressional (C), vertical (V) and undeformed (U). These dictate the first letter of the codes; the remaining letters conveying the evidence. This information can be used to reconstruct palaeostress fields and to infer physical properties of sediments when they deformed. Individual structures are not diagnostic of particular environments but the suite of structures, their relative scale, stratigraphical relationships, and orientation relative to palaeoslopes and to palaeoice‐flow directions can be used to infer the environment in which they formed. This scheme is applied at five sites in west Wales. The typical succession is interpreted as subglacial sediments overlain by meltout tills, flow tills and sediment flows. Paraglacial redistribution of glacial sediments is widespread. Large‐scale compressional deformation is restricted to sites where glaciers readvanced. Large‐scale vertical deformation occurs where water was locally ponded near the ice margin. There is no evidence for glaciomarine conditions. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   
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We report on the analysis of a ∼60-ks XMM–Newton observation of the bright, narrow emission line quasar PG1211+143. Absorption lines are seen in both European Photon Imaging Camera and Reflection Grating Spectrometer spectra corresponding to H- and He-like ions of Fe, S, Mg, Ne, O, N and C. The observed line energies indicate an ionized outflow velocity of ∼24 000 km s−1. The highest energy lines require a column density of   N H∼ 5 × 1023 cm−2  , at an ionization parameter of  log ξ∼ 3.4  . If the origin of this high-velocity outflow lies in matter being driven from the inner disc, then the flow is likely to be optically thick within a radius of ∼130 Schwarzschild radii, providing a natural explanation for the big blue bump (and strong soft X-ray) emission in PG1211+143.  相似文献   
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Coronal loops on the Sun and nearby stars are investigated using observations at 20 cm wavelength with high resolution in time and frequency. Observations of the dwarf M star AD Leonis with high time resolution using the Arecibo Observatory have resulted in the discovery of a quasi-periodic train of circularly polarized spikes with a mean periodicity of 32 ± 5 ms and a total duration of 150 ms. The individual spikes had rise times of 5 ms, leading to an upper limit to the linear size L 1.5 × 108 cm for the spike emitter. This size is only 0.005 of the estimated radius of AD Leonis. Provided that the emitter is symmetric, it has a brightness temperature of T B 1016 K, suggesting a coherent burst mechanism such as an electron-cyclotron maser. Coronal oscillations might modulate the maser output, producing the quasi-periodic spikes. Observations at closely spaced wavelengths, or high frequency resolution, using the Very Large Array have revealed narrow-band structure (v/v 0.01) in solar bursts and in the slowly-varying radiation of the dwarf M star YZ Canis Minoris. The narrow-band emission cannot be explained by continuum emission processes, but it might be attributed to electron-cyclotron maser radiation. Maser action at the second or first harmonic of the gyrofrequency implies magnetic field strengths of 250 and 500 G, respectively. Thus, observations with high resolution in time and frequency suggest coherent processes in the coronae of the Sun and dwarf M stars. The scientific potential of these discoveries may be best fulfilled by the construction of a solar-stellar synthesis radiotelescope.Proceedings of the Workshop on Radio Continua during Solar flares, held at Duino (Trieste), Italy, 27–31 May, 1985.  相似文献   
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The Scandinavian Caledonides have been viewed as resulting from either a single Silurian (i.e. Scandian) event or from polycyclic orogenies involving several collisions on the margin of Baltica. Early studies of the Kalak Nappe Complex (KNC) in Finnmark, Arctic Norway, led to the hypothesis of an Early Cambrian-Early Ordovician (520-480 Ma) Finnmarkian Orogeny, though the nature of this tectonic event remains enigmatic. In this contribution we have employed in situ UV laser ablation Ar-Ar dating of fine-grained phyllite and schist from the eastern Caledonides of Arctic Norway to investigate the presence of pre-Scandian tectonometamorphic events. U-Th-Pb detrital zircon and whole rock Sm-Nd analyses have been used to test the regional stratigraphic correlations of these metasedimentary rocks. These results indicate that the Berlevåg Formation within the Tanafjord Nappe, previously assumed to be part of the KNC, was deposited after 1872 Ma and prior to a low temperature hydrothermal event at 555 ± 15 Ma. It has a likely provenance on the Baltica continent, lacks any Grenville-Sveconorwegian detrital zircons, and thus cannot be part of the KNC which contains abundant detritus in this age range. Instead the Berlevåg Formation is interpreted as part of the Laksefjord Nappe Complex, which structurally underlies the KNC. Laser-ablation argon-argon dating also shows that late Caledonian (i.e. Scandian) tectonometamorphism affected both the KNC and its immediate footwall at c. 425 ± 15 Ma. This is corroborated by a step-heating argon-argon muscovite age of 424 ± 3 Ma which is interpreted as dating cooling. However, within two samples from the KNC, an earlier (Middle-Late Cambrian) metamorphic event is also recorded. A biotite-grade schist yielded an Ar-Ar inverse isochron age of 506 ± 17 Ma from whole rock surfaces, in which the mineral domains are too fine-grained to date individually. An early generation of muscovite from a coarser-grained amphibolite-facies sample yielded an inverse isochron of 498 ± 13 Ma. Both isochron ages have atmospheric argon intercept values. Previous studies have documented similar Cambrian ages in the Caledonian nappes below the KNC. These results suggest correlative tectonometamorphic events in the eastern KNC and its footwall at c. 500 Ma. This Cambrian event may reflect the arrival of the Kalak Nappe Complex as a previously constructed exotic mobile belt onto the margin of Baltica. Combined with recent studies from the western Kalak Nappe Complex, the results do not support the traditional constraint on the Finnmarkian Orogeny sensu stricto. However they vindicate classic tectonic models involving a Cambrian accretion event.  相似文献   
8.
溴是一种在自然水体中都含有的元素,通常以B r-的形式存在。目前最常用的水净化方式就是向水中通入臭氧以杀灭细菌;而臭氧分解的副产物即为B r-转换成的B rO3-,这是一种公认的致癌物质。本实验室曾使用阴离子交换高效液相色谱(HPLC)与等离子体质谱(ICP-MS)联用分析B rO3-和B r-,方法虽能有效地将这两种溴形态分离,但分析每个样品需8 m in。本文试图建立新的方法缩短分析时间,并验证该方法应用于实际水样分析时测定其他含溴化合物的能力。1实验部分1.1高效液相色谱分析条件表1列出了等度淋洗和梯度淋洗两种模式下HPLC的分析条件,完成形态的分离。等度淋洗和梯度淋洗在分析中显示出不同  相似文献   
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This paper examines how narratives of history are organized spatially at historical sites and memorial spaces, especially in urban settings and in places invested with a sense of collective memory. Much recent research has focused on landscape, memory, and place and how relationships of political and social power influence the representation of historical events in public spaces. Although the meaning of such sites may be hotly contested for long periods of time, we focus here on narrative theory and the related, but unexplored, issue of how such historical stories are configured on the ground at actual historical sites. We identify a number of narrative strategies which are frequently used to configure historical stories in space. Declamatory strategies using markers presenting a snapshot of an event are common, but sequential and non-sequential linear strategies are also used, as are thematic strategies that cross-cut space and time to present complex historical stories at various spatial scales. Examples are drawn from a range of historical sites in North America, Europe and Israel.  相似文献   
10.
Atmospheric densities derived from the spin decay of Explorer 6 are used to study the corpuscular heating effect at low and middle latitudes near the time of sunspot maximum. The dependence of atmospheric temperature on ap is found to be quite similar to the recently revised curve of Jacchia et al., which applies to later times in the sunspot cycle, but also at low and middle latitudes. Both curves are very different from those found by polar satellites in orbits of low eccentricity. Averaging ap over half a day instead of delaying it by a quarter day improves the fit of the models to the data.  相似文献   
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