排序方式： 共有7条查询结果，搜索用时 15 毫秒
1
1.
Hiroshi Tsuno Atsuyuki Ohta Hiroyuki Kagi Noboru Imai Hiroaki Tao Masaharu Nomura 《Geostandards and Geoanalytical Research》2006,30(1):55-62
The oxidation states of chromium in GSJ JSO-2 (artificially contaminated soil) and three other geochemical reference materials (GSJ JSO-1, JLS-1 and JMS-1) were observed using X-ray near edge structure (XANES). For comparison, other artificially contaminated soil materials (mimic-JSO-2) were prepared by adding Cr(VI) into JSO-1. Their oxidation states of chromium were determined using XANES. The chromium contents were 1118 μg g-1 for JSO-2, 1352 μg g-1 for mimic-JSO-2 and 69-113 μg g-1 for the other reference materials. Most chromium was present as hexavalent in mimic-JSO-2. No hexavalent species were detected in other samples. These results for chromium oxidation state in JSO-2 and mimic-JSO-2 obtained with XANES resembled those obtained from a chemical extraction method. The present JSO-2 has no trace of Cr(VI), although Cr(VI) was added as a major species during preparation. On the other hand, the content of Cr(VI) obtained in mimic-JSO-2 agreed with the original Cr(VI) content. A time-elapse study showed that Cr(VI) contents in mimic-JSO-2 decreased gradually to 70% of the original abundance during 240-day preservation in dry conditions. Moreover, the abundance of Cr(VI) decreased markedly to 15% after 240 days in the wet mimic-JSO-2 containing 20% m/m of water. These experiments suggested that soil humidity enhanced the reduction of Cr(VI) and that Cr(VI) was reduced even in dry conditions. Consequently, it is reasonable to infer that Cr(VI) doped into JSO-2 was completely reduced to Cr(III) during the preservation period of 5 years. The certification of the long-term stability of the chemical form in reference materials will be much more important in future. 相似文献
2.
We have experimentally investigated melting phase relation of a nominally anhydrous, carbonated pelitic eclogite (HPLC1) at
2.5 and 3.0 GPa at 900–1,350°C in order to constrain the cycling of sedimentary carbon in subduction zones. The starting composition
HPLC1 (with 5 wt% bulk CO2) is a model composition, on a water-free basis, and is aimed to represent a mixture of 10 wt% pelagic carbonate unit and
90 wt% hemipelagic mud unit that enter the Central American trench. Sub-solidus assemblage comprises clinopyroxene + garnet + K-feldspar + quartz/coesite + rutile + calcio-ankerite/ankeritess. Solidus temperature is at 900–950°C at 2.5 GPa and at 900–1,000°C at 3.0 GPa, and the near-solidus melt is K-rich granitic.
Crystalline carbonates persist only 50–100°C above the solidus and at temperatures above carbonate breakdown, carbon exists
in the form of dissolved CO2 in silica-rich melts and as a vapor phase. The rhyodacitic to dacitic partial melt evolves from a K-rich composition at near-solidus
condition to K-poor, and Na- and Ca-rich composition with increasing temperature. The low breakdown temperatures of crystalline
carbonate in our study compared to those of recent studies on carbonated basaltic eclogite and peridotite owes to Fe-enrichment
of carbonates in pelitic lithologies. However, the conditions of carbonate release in our study still remain higher than the
modern depth-temperature trajectories of slab-mantle interface at sub-arc depths, suggesting that the release of sedimentary
carbonates is unlikely in modern subduction zones. One possible scenario of carbonate release in modern subduction zones is
the detachment and advection of sedimentary piles to hotter mantle wedge and consequent dissolution of carbonate in rhyodacitic
partial melt. In the Paleo-NeoProterozoic Earth, on the other hand, the hotter slab-surface temperatures at subduction zones
likely caused efficient liberation of carbon from subducting sedimentary carbonates. Deeply subducted carbonated sediments,
similar to HPLC1, upon encountering a hotter mantle geotherm in the oceanic province can release carbon-bearing melts with
high K2O, K2O/TiO2, and high silica, and can contribute to EM2-type ocean island basalts. Generation of EM2-type mantle end-member may also
occur through metasomatism of mantle wedge by carbonated metapelite plume-derived partial melts. 相似文献
3.
We have investigated melting relations in the Fe–O–S ternary system in the pressure range of 15–27 GPa and 1873 K. Subsolidus
phase relations are Fe, Fe3S2, and FeO up to 17 GPa and Fe, Fe3S, and FeO above this pressure. The eutectic temperature slightly decreases from ambient pressure to 17 GPa, whereas increases
above this pressure. The eutectic temperature in this study is 100 K lower than that in the Fe–S binary system. The oxygen
content in the Fe–O–S eutectic liquid drops when the coexisting solid phases changes from FeS to Fe3S2. The cotectic lines in the ternary phase diagram lie close to the Fe–FeS binary axis. The isothermal sections indicate that
oxygen solubility in the Fe–O–S liquid increases with increasing temperature, and with increasing sulfur content. The solubility
of sulfur in the solid Fe has a maximum value at the eutectic temperature, and decreases with increasing temperature. Our
results could have important implications for formation and composition of the Martian core. 相似文献
4.
Rare earth element (REE) concentrations in the carbonate lattice of four species of coral have been analyzed and compared with the dissolved REE in ambient seawaters. The corals were from two areas of different salinity, marine (34-34.5) and bay (33-34). The measurement of REE in coral was carried out with inductively coupled plasma mass spectrometry (ICP-MS) after meticulous washing of coral samples, digestion with acetic acid and preconcentration of REE. The concentrations of REE in the two ambient seawaters were quite different, being ten-times higher in the bay area and enriched in light REE. However, the average distribution coefficients (D’s) were almost identical in the two areas. Substantial distribution coefficient differences were observed among the four coral species and the magnitude of inter-species variation in D was also species-dependent. Theoretical calculations imply that pH variation could cause variations in D large enough to account for the small differences between the two areas. 相似文献
5.
Journal of Seismology - In the Kanto Basin, Japan, it has been reported that the dominant periods of long-period ground motions vary depending on the areas where earthquakes occurred. This suggests... 相似文献
6.
David C. Rubie Daniel J. Frost Ute Mann Yuki Asahara Francis Nimmo Kyusei Tsuno Philip Kegler Astrid Holzheid Herbert Palme 《Earth and Planetary Science Letters》2011,301(1-2):31-42
A model of core formation is presented that involves the Earth accreting heterogeneously through a series of impacts with smaller differentiated bodies. Each collision results in the impactor's metallic core reacting with a magma ocean before merging with the Earth's proto-core. The bulk compositions of accreting planetesimals are represented by average solar system abundances of non-volatile elements (i.e. CI-chondritic), with 22% enhancement of refractory elements and oxygen contents that are defined mainly by the Fe metal/FeO silicate ratio. Based on an anhydrous bulk chemistry, the compositions of coexisting core-forming metallic liquid and peridotitic silicate liquid are calculated by mass balance using experimentally-determined metal/silicate partition coefficients for the elements Fe, Si, O, Ni, Co, W, Nb, V, Ta and Cr. Oxygen fugacity is fixed by the partitioning of Fe between metal and silicate and depends on temperature, pressure and the oxygen content of the starting composition. Model parameters are determined by fitting the calculated mantle composition to the primitive mantle composition using least squares minimization. Models that involve homogeneous accretion or single-stage core formation do not provide acceptable fits. In the most successful models, involving 24 impacting bodies, the initial 60–70% (by mass) of the Earth accretes from highly-reduced material with the final 30–40% of accreted mass being more oxidised, which is consistent with results of dynamical accretion simulations. In order to obtain satisfactory fits for Ni, Co and W, it is required that the larger (and later) impactor cores fail to equilibrate completely before merging with the Earth's proto-core, as proposed previously on the basis of Hf-W isotopic studies. Estimated equilibration conditions may be consistent with magma oceans extending to the core–mantle boundary, thus making core formation extremely efficient. The model enables the compositional evolution of the Earth's mantle and core to be predicted throughout the course of accretion. The results are consistent with the late accretion of the Earth's water inventory, possibly with a late veneer after core formation was complete. Finally, the core is predicted to contain ~ 5 wt.% Ni, ~ 8 wt.% Si, ~ 2 wt.% S and ~ 0.5 wt.% O. 相似文献
7.
Kyusei Tsuno Eiji Ohtani Hidenori Terasaki 《Physics of the Earth and Planetary Interiors》2007,160(1):75-85
We have determined phase relations in the Fe-O and Fe-O-S systems in the range of 15-21 GPa and 1825-2300 °C. Below the liquidus temperatures, solid FeO and metallic liquids are observed in both the Fe-O and the Fe-O-S systems. An immiscible two-liquid region exists in the Fe-O binary system in the pressure range investigated, and the immiscibility gap between Fe-rich metallic liquid and FeO-rich ionic liquid does not greatly change with either pressure or temperature. On the other hand, an immiscible two-liquid region in the Fe-O-S ternary system narrows significantly with increasing pressure at constant temperature and vice versa, and it almost disappears at 21 GPa, and 2300 °C. Immiscible two-liquid regions are thus not expected to exist in the Fe-O-S system in the Earth's core, suggesting that both oxygen and sulfur can be incorporated into the core. Our results are consistent with a geochemical model for the core containing 5.8 wt.% oxygen and 1.9 wt.% sulfur as proposed by McDonough and Sun [McDonough, W.F., Sun, S.-S., 1995. The composition of the Earth. Chem. Geol. 120, 223-253]. 相似文献
1